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Volume 100
Main Index

Issue 1


Qualitative potential energy surfaces. 1. Theory
N. D. Epiotis and S. Shaik
pp 1 - 8; DOI:
10.1021/ja00469a001
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Qualitative potential energy surfaces. 2. Cycloadditions
N. D. Epiotis and S. Shaik
pp 9 - 17; DOI:
10.1021/ja00469a002
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Qualitative potential energy surfaces. 3. Stereoselection rules for spin inversion in triplet photochemical reactions
S. Shaik and N. D. Epiotis
pp 18 - 29; DOI:
10.1021/ja00469a003
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Qualitative potential energy surfaces. 4. Aromatic substitution
N. D. Epiotis and S. Shaik
pp 29 - 33; DOI:
10.1021/ja00469a004
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The electronic structure of the low-lying excited states of glyoxal
Warren B. Mueller, James F. Harrison, and Peter J. Wagner
pp 33 - 37; DOI:
10.1021/ja00469a005
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Constitutional symmetry and unique descriptors of molecules
Wolfgang Schubert and Ivar Ugi
pp 37 - 41; DOI:
10.1021/ja00469a006
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Optimized geometries of the saddle-point rotamers of formamide
Roman F. Nalewajski
pp 41 - 46; DOI:
10.1021/ja00469a007
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The conformation of echinomycin in solution
H. T. Cheung, J. Feeney, G. C. K. Roberts, D. H. Williams, G. Ughetto, and M. J. Waring
pp 46 - 54; DOI:
10.1021/ja00469a008
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Heteronuclear vicinal coupling constants and site-specific isotopic substitution in the investigation of rotational isomerism in leucine
Alan J. Fischman, Herman R. Wyssbrod, William C. Agosta, and David Cowburn
pp 54 - 58; DOI:
10.1021/ja00469a009
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Ground states of molecules. 40. MNDO results for molecules containing fluorine
Michael J. S. Dewar and Henry S. Rzepa
pp 58 - 67; DOI:
10.1021/ja00469a010
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Molecular orbital studies of the radicals of hydroxybenzenes and epinephrine
Yasuko Shinagawa and Yoshiya Shinagawa
pp 67 - 72; DOI:
10.1021/ja00469a011
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Molecular orbital studies of organic substituent effects. Semiempirical calculations on charge and energy perturbation through the benzene nucleus in a model SN2 reaction
Robert B. Davidson and C. Richard Williams
pp 73 - 79; DOI:
10.1021/ja00469a012
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Studies of hydrogen bonding in the vapor phase by measurement of thermal conductivity and molecular orbital calculations. 2,2,2-Trifluoroethanol
L. A. Curtiss, D. J. Frurip, and M. Blander
pp 79 - 86; DOI:
10.1021/ja00469a013
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Reactions involving hydrogen peroxide, iodine, and iodate ion. 6. Oxidation of iodine by hydrogen peroxide at 50.degree.C
Herman A. Liebhafsky, William C. McGavock, Robert J. Reyes, Glenn M. Roe, and Lawrence S. Wu
pp 87 - 91; DOI:
10.1021/ja00469a014
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Hyperconjugation and through-space and through-bond interactions in bridgehead alkyl radicals by electron spin resonance
Takashi Kawamura, Masaji Matsunaga, and Teijiro Yonezawa
pp 92 - 97; DOI:
10.1021/ja00469a015
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Carbon-13 spin-lattice relaxation and molecular motion of diphenyl dichalcogenides
Marcello Baldo, Alain Forchioni, Kurt J. Irgolic, and Giuseppe C. Pappalardo
pp 97 - 100; DOI:
10.1021/ja00469a016
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Photoelectron spectra and orbital interactions in methylenenortriquinacenes
L. N. Domelsmith, K. N. Houk, C. R. Degenhardt, and L. A. Paquette
pp 100 - 105; DOI:
10.1021/ja00469a017
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Photoelectron spectra of 3-substituted cyclopentenes. Correlations between ionization potentials and cycloaddition regioselectivity
E. J. McAlduff, Pierluigi Caramella, and K. N. Houk
pp 105 - 110; DOI:
10.1021/ja00469a018
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Transits across a cyclopentadienyl: organic and organometallic haptotropic shifts
Nguyen Trong Anh, Mihai Elian, and Roald Hoffmann
pp 110 - 116; DOI:
10.1021/ja00469a019
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Photolytic and radiolytic studies of tris(2,2'-bipyridine)ruthenium(2+) in micellar solutions
Dan Meisel, Max S. Matheson, and Joseph Rabani
pp 117 - 122; DOI:
10.1021/ja00469a020
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The photochemistry of organocobalt complexes containing tetraaza macrocyclic ligands. Cobalt-methyl homolysis and the nature of the cobalt-carbon bond
Chup Y. Mok and John F. Endicott
pp 123 - 129; DOI:
10.1021/ja00469a021
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Mechanism of hydrogen evolution from hydridocobaloxime
Tai-Hsiang Chao and James H. Espenson
pp 129 - 133; DOI:
10.1021/ja00469a022
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Interactions of divalent metal ions with inorganic and nucleoside phosphates. 5. Kinetics of nickel(II) with HP3O104-, cytidine 5'-triphosphate, HP2O73-, and cytidine 5'-diphosphate
Cheryl Miller Frey and John E. Stuehr
pp 134 - 139; DOI:
10.1021/ja00469a023
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Interactions of divalent metal ions with inorganic and nucleoside phosphates. 6. A thermodynamic and kinetic study of the nickel(II)-adenosine 5'-triphosphate and -adenosine 5'-diphosphate systems
Cheryl Miller Frey and John E. Stuehr
pp 139 - 145; DOI:
10.1021/ja00469a024
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A stable chromium(V) compound. Synthesis, properties, and crystal structure of potassium bis(2-hydroxy-2-methylbutyrato)oxochromate(V) monohydrate
Miroslav Krumpolc, Barry G. DeBoer, and Jan Rocek
pp 145 - 153; DOI:
10.1021/ja00469a025
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The molybdenum-molybdenum triple bond. 3. A triple bond between two four-coordinated molybdenum(III) atoms. Structural characterization of the bis(dimethylamine) adduct of dimolybdenum hexatrimethylsiloxide
Malcolm H. Chisholm, F. Albert Cotton, Michael W. Extine, and William W. Reichert
pp 153 - 157; DOI:
10.1021/ja00469a026
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Diastereotopic groups in silyllithium and germyllithium compounds. Slow inversion about silicon and germanium
Joseph B. Lambert and Migdalia Urdaneta-Perez
pp 157 - 162; DOI:
10.1021/ja00469a027
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The gas-phase chemistry of chlorotitanium ions with oxygen-containing organic compounds
J. Allison and D. P. Ridge
pp 163 - 169; DOI:
10.1021/ja00469a028
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Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
S. J. Tauster, S. C. Fung, and R. L. Garten
pp 170 - 175; DOI:
10.1021/ja00469a029
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The hexasilver molecule stabilized by coordination to six silver ions. The structure of (Ag.+-.)6(Ag6). The crystal structure of an ethylene sorption complex of partially decomposed fully Ag.+-.-exchanged zeolite A
Yang Kim and Karl Seff
pp 175 - 180; DOI:
10.1021/ja00469a030
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Mercury in organic chemistry. 14. A convenient regiospecific synthesis of .pi.-allylpalladium compounds via vinylmercurials
Richard C. Larock and Mark A. Mitchell
pp 180 - 188; DOI:
10.1021/ja00469a031
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Organometallic reaction mechanisms. 15. Factors influencing the nature of Grignard reactions with ketones
E. C. Ashby and T. L. Wiesemann
pp 189 - 199; DOI:
10.1021/ja00469a032
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Kinetic acidity of diastereotopic protons in sulfonium ions. A transition state conformational effect
G. Barbarella, P. Dembech, A. Garbesi, F. Bernardi, A. Bottoni, and A. Fava
pp 200 - 202; DOI:
10.1021/ja00469a033
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Electronic structure of the .pi. donor naphthalene 1,8-disulfide
D. J. Sandman, G. P. Ceasar, P. Nielsen, A. J. Epstein, and T. J. Holmes
pp 202 - 206; DOI:
10.1021/ja00469a034
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Flavin model systems. 1. The electrochemistry of 1-hydroxyphenazine and pyocyanine in aprotic solvents
Mark M. Morrison, Eddie T. Seo, John K. Howie, and Donald T. Sawyer
pp 207 - 211; DOI:
10.1021/ja00469a035
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Flavin model systems. 2. Pyocyanine complexes of divalent manganese, iron, nickel, copper, and zinc in dimethyl sulfoxide
Mark M. Morrison and Donald T. Sawyer
pp 211 - 213; DOI:
10.1021/ja00469a036
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Hydrogen bonding spectra of pyridinium hydrochlorides in dimethyl sulfoxide solution and as mulls
Edward M. Arnett and B. Chawla
pp 214 - 216; DOI:
10.1021/ja00469a037
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Thermometric titrations of substituted pyridines with trifluoroacetic acid in carbon tetrachloride. Hydrogen bonded ion pair systems
Edward M. Arnett and B. Chawla
pp 217 - 221; DOI:
10.1021/ja00469a038
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Hydrogen bond strengths from solvent-dependent lifetimes of Rose Bengal dye
Laurence E. Cramer and Kenneth G. Spears
pp 221 - 227; DOI:
10.1021/ja00469a039
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Effect of solvent on .beta.-arylalkyl solvolysis
Frank L. Schadt, C. J. Lancelot, and Paul v. R. Schleyer
pp 228 - 246; DOI:
10.1021/ja00469a040
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The solution conformation of nicotine. A 1H and 2H nuclear magnetic resonance investigation
T. Phil Pitner, William B. Edwards, Ronald L. Bassfield, and Jerry F. Whidby
pp 246 - 251; DOI:
10.1021/ja00469a041
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An electron spin resonance investigation on intermediates and products in the basic oxidation of nitrodiphenylethylenes
M. Barzaghi, P. L. Beltrame, A. Gamba, and M. Simonetta
pp 251 - 259; DOI:
10.1021/ja00469a042
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Camphene. 5. Torsion factors influencing exo/endo Nametkin rearrangement. The structure of (-)-camphene-8-carboxylic acid
Paul C. Moews, James R. Knox, and Wyman R. Vaughan
pp 260 - 264; DOI:
10.1021/ja00469a043
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Transition metal catalyzed asymmetric organic syntheses via polymer-attached optically active phosphine ligands. Synthesis of R amino acids and hydratropic acid by hydrogenation
Naotake Takaishi, Hirosuke Imai, Christopher A. Bertelo, and J. K. Stille
pp 264 - 268; DOI:
10.1021/ja00469a044
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Transition metal catalyzed asymmetric organic syntheses via polymer-attached optically active phosphine ligands. Synthesis of R amino acids by hydrogenation with a polymer catalyst containing optically active alcohol sites
T. Masuda and J. K. Stille
pp 268 - 272; DOI:
10.1021/ja00469a045
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Measurement of hydrogen exchange at the tryptophan residues of a protein by stopped-flow and ultraviolet spectroscopy
Mamoru Nakanishi, Hitomi Nakamura, Akiko Y. Hirakawa, Masamichi Tsuboi, Toshihiko Nagamura, and Yutaka Saijo
pp 272 - 276; DOI:
10.1021/ja00469a046
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Role of 1,2-dehydroreticulinium ion in the biosynthetic conversion of reticuline to thebaine
Paul R. Borkowski, Jerold S. Horn, and Henry Rapoport
pp 276 - 281; DOI:
10.1021/ja00469a047
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Conjugative effects on the enol-enethiol tautomerism of .beta.-thioxoketones
Lars Carlsen and Fritz Duus
pp 281 - 282; DOI:
10.1021/ja00469a048
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1-Aza-1,2,4,6-cycloheptatetraene
Orville L. Chapman and Jean Pierre Le Roux
pp 282 - 285; DOI:
10.1021/ja00469a049
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Synthesis and thermolysis of 7,8-diazabicyclo[4.2.2]deca-2,4,7-triene
Henrik Olsen and James P. Snyder
pp 285 - 287; DOI:
10.1021/ja00469a050
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Regiospecific reaction of enol ethers with an organopalladium salt. Stereochemical and conformational effects on product formation
Isamu Arai and G. Doyle Daves
pp 287 - 288; DOI:
10.1021/ja00469a051
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Direct two-step conversion of penicillins to 3-acetoxymethylcephems
G. A. Koppel and L. J. McShane
pp 288 - 289; DOI:
10.1021/ja00469a052
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Replacement of the nitro group by hydrogen
Nathan Kornblum, Stephen C. Carlson, and Ronald G. Smith
pp 289 - 290; DOI:
10.1021/ja00469a053
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Organofluorosilicates in organic synthesis. 1. A novel general and practical method for anti-Markownikoff hydrohalogenation of olefins via organopentafluorosilicates derived from hydrosilylation products
Kohei Tamao, Junichi Yoshida, Masatada Takahashi, Hiraku Yamamoto, Toshio Kakui, Hiroshi Matsumoto, Atsushi Kurita, and Makoto Kumada
pp 290 - 292; DOI:
10.1021/ja00469a054
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Regiospecific generation of lithioenamines from .alpha.,.beta.-unsaturated imines. An alternative method for reduction-alkylation of enones
Paul A. Wender and Michael A. Eissenstat
pp 292 - 294; DOI:
10.1021/ja00469a055
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Ozonolysis of vinylsilanes
George Buechi and Hans Wuest
pp 294 - 295; DOI:
10.1021/ja00469a056
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Characterization of a dioxetane deriving from norbornene and evidence for its zwitterionic peroxide precursor
Charles W. Jefford and Christian G. Rimbault
pp 295 - 296; DOI:
10.1021/ja00469a057
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Absolute rates of hydrogen abstraction by tert-butoxy radicals
R. D. Small and J. C. Scaiano
pp 296 - 298; DOI:
10.1021/ja00469a058
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Metal-carbene complexes and the possible role of hydroxycarbene in formaldehyde laser photochemistry
Robert R. Lucchese and Henry F. Schaefer
pp 298 - 299; DOI:
10.1021/ja00469a059
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An alkoxyaryltrifluoroperiodinane. A stable heterocyclic derivative of pentacoordinated organoiodine(V)
Ronald L. Amey and J. C. Martin
pp 300 - 301; DOI:
10.1021/ja00469a060
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Triplet carbonyl-olefin charge-transfer complexes. A CNDO treatment
R. Marshall Wilson, Russell Outcalt, and H. H. Jaffe
pp 301 - 302; DOI:
10.1021/ja00469a061
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Immobilization of synthetically useful enzymes by condensation polymerization
Alfred Pollak, Richard L. Baughn, Orn Adalsteinsson, and George M. Whitesides
pp 302 - 304; DOI:
10.1021/ja00469a062
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Large-scale enzyme-catalyzed synthesis of ATP from adenosine and acetyl phosphate. Regeneration of ATP from AMP
Richard L. Baughn, Orn Adalsteinsson, and George M. Whitesides
pp 304 - 306; DOI:
10.1021/ja00469a063
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Conversion of a protein to a homogeneous asymmetric hydrogenation catalyst by site-specific modification with a diphosphinerhodium(I) moiety
Michael E. Wilson and George M. Whitesides
pp 306 - 307; DOI:
10.1021/ja00469a064
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Mokupalides, three novel hexaprenoids from a marine sponge
Mark B. Yunker and Paul J. Scheuer
pp 307 - 309; DOI:
10.1021/ja00469a065
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p-Toluenesulfonyldiazoacetates as photoaffinity labeling reagents
Vinay Chowdhry and F. H. Westheimer
pp 309 - 310; DOI:
10.1021/ja00469a066
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Photochemistry of iron(II) diimine complexes in a room temperature molten salt
Helena Li Chum, D. Koran, and R. A. Osteryoung
pp 310 - 312; DOI:
10.1021/ja00469a067
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Near-ultraviolet photooxidation of tryptophan. Proof of formation of superoxide ion
J. P. McCormick and Thomas Thomason
pp 312 - 313; DOI:
10.1021/ja00469a068
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Total synthesis of (.+-.)-thienamycin
David B. R. Johnston, Susan M. Schmitt, F. Aileen Bouffard, and B. G. Christensen
pp 313 - 315; DOI:
10.1021/ja00469a069
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Internal photocycloaddition between chromophores separated by 17 bonds
J. A. Ors and R. Srinivasan
pp 315 - 316; DOI:
10.1021/ja00469a070
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Sirohydrochlorin. Prosthetic group of a sulfite reductase enzyme and its role in the biosynthesis of vitamin B12
A. I. Scott, A. J. Irwin, L. M. Siegel, and J. N. Shoolery
pp 316 - 318; DOI:
10.1021/ja00469a071
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Enhanced chemiluminescence from the silica gel catalyzed decomposition of a 1,2-dioxetane
K. A. Zaklika, Paul A. Burns, and A. Paul Schaap
pp 318 - 320; DOI:
10.1021/ja00469a072
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Correlation of chemical shifts of protons and carbon-13
Geoffrey Bodenhausen and Ray Freeman
pp 320 - 321; DOI:
10.1021/ja00469a073
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Interaction of acetylene and ethylene with nickel atom
Thomas H. Upton and William A. Goddard
pp 321 - 323; DOI:
10.1021/ja00469a074
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Stereochemistry in the di-.pi.-methane rearrangement: aryl migration. Exploratory and mechanistic organic photochemistry
Howard E. Zimmerman, Thomas P. Gannett, and Gary E. Keck
pp 323 - 324; DOI:
10.1021/ja00469a075
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Reversible binding of dioxygen to ruthenium(II) porphyrins
N. Farrell, D. H. Dolphin, and B. R. James
pp 324 - 326; DOI:
10.1021/ja00469a076
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Tetrakis[methylaminobis(difluorophosphine)]carbonyldiiron: unsymmetrical bonding of methylaminobis(difluorophosphine) to a pair of transition metals involving phosphorus-nitrogen bond cleavage
M. G. Newton, R. B. King, M. Chang, and J. Gimeno
pp 326 - 327; DOI:
10.1021/ja00469a077
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Bridging the gap between the gas phase and solution: transition in the relative acidity of water and methanol at 296 .+-. 2 K
Gervase I. Mackay and Diethard K. Bohme
pp 327 - 329; DOI:
10.1021/ja00469a078
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Base-induced generation of superoxide ion and hydroxyl radical from hydrogen peroxide
Julian L. Roberts, Mark M. Morrison, and Donald T. Sawyer
pp 329 - 330; DOI:
10.1021/ja00469a079
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Relationship between charge delocalization and stability of some oxocarbenium ions
John W. Larsen
pp 330 - 331; DOI:
10.1021/ja00469a080
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Nonaqueous reductive lanthanide chemistry. 1. Reaction of lanthanide atoms with 1,3-butadienes
William J. Evans, Steven C. Engerer, and Anne C. Neville
pp 331 - 333; DOI:
10.1021/ja00469a081
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Nonaqueous reductive lanthanide chemistry. 2. Conversion of cis,cis-1,5-cyclooctadiene to cyclooctatetraenyl dianion by reduced praseodymium and potassium
William J. Evans, Andrea L. Wayda, Chia-Wun Chang, and William M. Cwirla
pp 333 - 334; DOI:
10.1021/ja00469a082
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Resonance Raman spectra of copper(III) peptide complexes
James R. Kincaid, James A. Larrabee, and Thomas G. Spiro
pp 334 - 336; DOI:
10.1021/ja00469a083
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Trimethylsulfonium ion as a ligand: synthesis and characterizaton of pentaamminetrimethylsulfoniumruthenium tris(hexafluorophosphate)
C. A. Stein and Henry Taube
pp 336 - 337; DOI:
10.1021/ja00469a084
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1,9-Dimethyldibenzo[b,f]pentalene dication and dianion. New 14.pi. and 18.pi. aromatic systems
Itamar Willner and Mordecai Rabinovitz
pp 337 - 338; DOI:
10.1021/ja00469a085
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Phase-transfer catalyzed oxygen-18 labeling studies of carbonyl ligands in neutral metal carbonyl derivatives
Donald J. Darensbourg and Joseph A. Froelich
pp 338 - 340; DOI:
10.1021/ja00469a086
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Chlorine(I) derivatives of trifluoromethanesulfonic acid and trifluoroacetic acid
Darryl D. DesMarteau
pp 340 - 341; DOI:
10.1021/ja00469a087
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A direct, selective, and general method for reductive deamination of primary amines
G. A. Doldouras and J. Kollonitsch
pp 341 - 342; DOI:
10.1021/ja00469a088
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Reduction of nitric oxide by carbon monoxide in the presence of aqueous palladium(II) and copper(II)
Mitsuru Kubota, Kent J. Evans, Catherine A. Koerntgen, and James C. Marsters
pp 342 - 343; DOI:
10.1021/ja00469a089
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Nitroxide. 84. Copper(II)-bisnitroxide complex as evidence for strong electron-exchange six-spin system
R. Briere, A. Rassat, and P. Rey
pp 343 - 344; DOI:
10.1021/ja00469a090
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Experimental observation of the effect of an oriented positive monopole on carbon-13 chemical shifts of a naphthalene derivative. Crown ether conformational changes and their effect on an attached naphthalene system
Lynn R. Sousa and Mark R. Johnson
pp 344 - 346; DOI:
10.1021/ja00469a091
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A versatile and expedient synthesis of .alpha.,.beta.-unsaturated ketones. Utilization of the .beta.-epoxy sulfone functional group as the enone progenitor
P. C. Conrad and P. L. Fuchs
pp 346 - 348; DOI:
10.1021/ja00469a092
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Palladium catalyzed amine exchange reaction of tertiary amines. Insertion of palladium(0) into carbon-hydrogen bonds
Shunichi Murahashi, Tsumoru Hirano, and Tsuneo Yano
pp 348 - 350; DOI:
10.1021/ja00469a093
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Cyclopropene, alkene, alkyne, and carbonyl complexes of cyclopentadienylniobium species and reduction of cyclopropene
Susan Fredericks and J. L. Thomas
pp 350 - 351; DOI:
10.1021/ja00469a094
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Shikimate-derived metabolites. 2. Synthesis of a bacterial natural product illustrating a concerted syn-SN2' reaction
Nobuo Ikota and Bruce Ganem
pp 351 - 352; DOI:
10.1021/ja00469a095
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Shikimate-derived metabolites. 3. Total synthesis of senepoxide and seneol according to a biogenetic proposal
Gene W. Holbert and Bruce Ganem
pp 352 - 353; DOI:
10.1021/ja00469a096
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Production of hydrogen from interaction of an anion radical and water
Gerald R. Stevenson, Jose Valentin, Craig Meverden, Luis Echegoyen, and Rene Maldonado
pp 353 - 354; DOI:
10.1021/ja00469a097
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A self-consistency criterion for two-structure theories
Kenneth S. Pitzer
pp 354 - 354; DOI:
10.1021/ja00469a098
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Nitroxide radical as a nuclear spin decoupling reagent. Application to carbon-13 nuclear magnetic resonance studies of organothallium compounds
Isao Morishima, Toshiro Inubushi, Sakae Uemura, and Haruo Miyoshi
pp 354 - 356; DOI:
10.1021/ja00469a099
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Book Reviews

pp 357 - 358; DOI:
10.1021/ja00469a600
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Issue 2


.sigma. Participation in electrocyclic reactions. A consequence of symmetry
E. A. Halevi, J. Katriel, R. Pauncz, F. A. Matsen, and T. L. Welsher
pp 359 - 365; DOI:
10.1021/ja00470a001
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Cis labilization of ligand dissociation. 5. A molecular orbital investigation
Dennis L. Lichtenberger and Theodore L. Brown
pp 366 - 373; DOI:
10.1021/ja00470a002
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Application of ab initio molecular orbital calculations to the structural moieties of carbohydrates. 3
G. A. Jeffrey, J. A. Pople, J. S. Binkley, and S. Vishveshwara
pp 373 - 379; DOI:
10.1021/ja00470a003
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Molecular structures and potential functions for the deformation of cyclopropane, cyclopropene, cyclobutane, and cyclopentadiene
James Kao and Leo Radom
pp 379 - 385; DOI:
10.1021/ja00470a004
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Raman spectrum and torsional potential function for vinylcyclopropane
L. A. Carreira, Theodore G. Towns, and Thomas B. Malloy
pp 385 - 388; DOI:
10.1021/ja00470a005
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The potential surfaces for the lowest singlet and triplet states of cyclobutadiene
Weston Thatcher Borden, Ernest R. Davidson, and Paul Hart
pp 388 - 392; DOI:
10.1021/ja00470a006
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The lowest energy excited singlet states and the cis-trans photoisomerization of styrene
G. L. Bendazzoli, G. Orlandi, P. Palmieri, and G. Poggi
pp 392 - 395; DOI:
10.1021/ja00470a007
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Sudden polarization in zwitterionic excited states of organic intermediates in photochemical reactions. On a possible mechanism for bicyclo[3.1.0]hex-2-ene formation
Vlasta Bonacic-Koutecky
pp 396 - 402; DOI:
10.1021/ja00470a008
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Comparison of molecular geometries determined by paramagnetic nuclear magnetic resonance relaxation and shift reagents in solution
D. H. Welti, M. Linder, and R. R. Ernst
pp 403 - 410; DOI:
10.1021/ja00470a009
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Interpretation of complex molecular motions in solution. A variable frequency carbon-13 relaxation study of chain segmental motions in poly(n-alkyl methacrylates)
George C. Levy, David E. Axelson, Robert Schwartz, and Jiri Hochmann
pp 410 - 424; DOI:
10.1021/ja00470a010
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Cluster model of lipid phase transitions with application to passive permeation of molecules and structure relaxations in lipid bilayers
Minoru I. Kanehisa and Tian Yow Tsong
pp 424 - 432; DOI:
10.1021/ja00470a011
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A model for calculating conformational energies in pentacoordinate phosphorus compounds
Robert R. Holmes
pp 433 - 446; DOI:
10.1021/ja00470a012
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FC.tplbond.P,C-fluorophosphaethyne: preparation and detection by photoelectron and microwave spectroscopy
H. W. Kroto, J. F. Nixon, N. P. C. Simmons, and N. P. C. Westwood
pp 446 - 448; DOI:
10.1021/ja00470a013
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Ultraviolet photoelectron spectroscopy of boranes and carboranes. Five-, six-, and seven-atom frameworks
J. A. Ulman and T. P. Fehlner
pp 449 - 456; DOI:
10.1021/ja00470a014
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Characterization of ferraboranes by ultraviolet photoelectron spectroscopy
J. A. Ulman, E. L. Andersen, and T. P. Fehlner
pp 456 - 463; DOI:
10.1021/ja00470a015
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The solution photosubstitution chemistry of triphenylphosphine derivatives of molybdenum hexacarbonyl
Donald J. Darensbourg and Mark A. Murphy
pp 463 - 468; DOI:
10.1021/ja00470a016
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Coupled pairs of chromium(III) ions in crystals of cesium trichloromagnesate, cesium tribromomagnesate, and cesium tribromocadmate. A case of charge compensation induced pair formation
Gary L. McPherson, Wai-Ming Heung, and Jaime J. Barraza
pp 469 - 475; DOI:
10.1021/ja00470a017
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Electronic selection rules in the photochemical substitution reactions of chromium(III) complexes
L. G. Vanquickenborne and A. Ceulemans
pp 475 - 483; DOI:
10.1021/ja00470a018
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Charge-transfer interactions between transition metal hexafluorides and xenon
J. D. Webb and E. R. Bernstein
pp 483 - 485; DOI:
10.1021/ja00470a019
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Flash kinetic spectroscopic studies of dinuclear rhodium(I) complexes
Vincent M. Miskowski, Glenn L. Nobinger, David S. Kliger, George S. Hammond, Nathan S. Lewis, Kent R. Mann, and Harry B. Gray
pp 485 - 488; DOI:
10.1021/ja00470a020
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Crystal and molecular structure of bis[ethylenediamine(barbiturato)palladium(II)]-4-water
Ekk Sinn, Charles M. Flynn, and R. Bruce Martin
pp 489 - 492; DOI:
10.1021/ja00470a021
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Some chemistry of fluorinated octahedral sulfur compounds
Tomoya Kitazume and Jean'ne M. Shreeve
pp 492 - 496; DOI:
10.1021/ja00470a022
PDF
Proton affinities of some sulfur-oxygen compounds
Danne E. Smith and Burnaby Munson
pp 497 - 500; DOI:
10.1021/ja00470a023
PDF
Binding of lithium(1+) ion to Lewis bases in the gas phase. Reversals in methyl substituent effects for different reference acids
R. L. Woodin and J. L. Beauchamp
pp 501 - 508; DOI:
10.1021/ja00470a024
PDF
Synthesis of fulvenes by reaction of thiobenzophenones with cyclopentadienylmetal carbonyl anions under anhydrous or phase transfer catalyzed conditions
Howard Alper and Hang-Nam Paik
pp 508 - 512; DOI:
10.1021/ja00470a025
PDF
A comparison of the photoaddition reactions of nucleic acid nitrogen bases and cyclohexenones with isobutylene. The role of rigidity in product formation
Allan J. Wexler, John A. Hyatt, Peter W. Raynolds, Charles Cottrell, and John S. Swenton
pp 512 - 520; DOI:
10.1021/ja00470a026
PDF
Copper(I) catalysis of olefin photoreactions. Photorearrangement and photofragmentation of methylenecyclopropanes
Robert G. Salomon, Amitabha Sinha, and Mary F. Salomon
pp 520 - 526; DOI:
10.1021/ja00470a027
PDF
Metal-catalyzed autoxidation. The unrecognized consequences of metal-hydroperoxide complex formation
J. F. Black
pp 527 - 535; DOI:
10.1021/ja00470a028
PDF
Radical ions in photochemistry. 5. Photosensitized (electron transfer) cyanation of olefins
A. J. Maroulis, Y. Shigemitsu, and D. R. Arnold
pp 535 - 541; DOI:
10.1021/ja00470a029
PDF
The loss of C2H2O and of C3H4O from the molecular ions of 3-phenylpropanal as studied by field ionization kinetics. Isomerization of the molecular ions of 3-phenyl-2-propen-1-ol
Peder Wolkoff, Jan Van der Greef, and Nico M. M. Nibbering
pp 541 - 545; DOI:
10.1021/ja00470a030
PDF
Electroorganic chemistry. 31. Reductive cyclization of nonconjugated olefinic ketones to cyclic tertiary alcohols
Tatsuya Shono, Ikuzo Nishiguchi, Hiroshi Ohmizu, and Michiharu Mitani
pp 545 - 550; DOI:
10.1021/ja00470a031
PDF
Ring-closure reactions. 11. The activation parameters for the formation of four- to six-membered lactones from .omega.-bromoalkanoate ions. The role of the entropy factor in small- and common-ring formation
Luigi Mandolini
pp 550 - 554; DOI:
10.1021/ja00470a032
PDF
Convenient and stereoselective route to basic frameworks for synthesis of unsymmetrical pentacyclic triterpenes
Tetsuji Kametani, Yoshiro Hirai, Yuichi Shiratori, Keiichiro Fukumoto, and Fumio Satoh
pp 554 - 560; DOI:
10.1021/ja00470a033
PDF
Peripheral metal complexes: chlorophyll "isomers" with magnesium bound to the ring E .beta.-keto ester system
Hugo Scheer and Joseph J. Katz
pp 561 - 571; DOI:
10.1021/ja00470a034
PDF
Total synthesis of Cinchona alkaloids. 1. Synthesis of meroquinene
Milan R. Uskokovic, Thomas Henderson, Charles Reese, Hsi Lin Lee, Guenter Grethe, and Juerg Gutzwiller
pp 571 - 576; DOI:
10.1021/ja00470a035
PDF
Total synthesis of Cinchona alkaloids. 2. Stereoselective total syntheses of quinine and quinidine
Juerg Gutzwiller and Milan R. Uskokovic
pp 576 - 581; DOI:
10.1021/ja00470a036
PDF
Total synthesis of Cinchona alkaloids. 3. Syntheses of quinuclidine intermediates
Guenter Grethe, Hsi Lin Lee, Toomas Mitt, and Milan R. Uskokovic
pp 581 - 588; DOI:
10.1021/ja00470a037
PDF
Total synthesis of Cinchona alkaloids. 4. Syntheses via quinuclidine precursors
Guenter Grethe, Hsi Lin Lee, Toomas Mitt, and Milan R. Uskokovic
pp 589 - 593; DOI:
10.1021/ja00470a038
PDF
Heavy metal nucleotide interactions. 11. Stereochemical and electronic effects in the electrophilic attack of cis- and trans-diammineplatinum(II) on 5'-guanosine monophosphate and polyguanylate in aqueous solution
Grace Y. H. Chu, Samir Mansy, Robert E. Duncan, and R. Stuart Tobias
pp 593 - 606; DOI:
10.1021/ja00470a039
PDF
Heavy metal nucleotide interactions. 12. Competitive reactions in systems of four nucleotides with cis- or trans-diammineplatinum(II). Raman difference spectrophotometry of the relative nucleophilicity of guanosine, cytidine, adenosine, and uridine monophosphates and analogous DNA bases
Samir Mansy, Grace Y. H. Chu, Robert E. Duncan, and R. Stuart Tobias
pp 607 - 616; DOI:
10.1021/ja00470a040
PDF
Preparation and crystal structure of Ir7(CO)12(C8H12)(C8H11)(C8H10), a heptanuclear iridium cluster showing three stages of cyclooctadiene coordination and dehydrogenation
Cortlandt G. Pierpont, Gordon F. Stuntz, and John R. Shapley
pp 616 - 618; DOI:
10.1021/ja00470a041
PDF
Magnetic exchange interactions in copper(II) dimers bridged by aromatic diamines. Crystal and molecular structure of .mu.-benzidine-bis(2,2',2''-triaminotriethylamine)dicopper(II) nitrate
Timothy R. Felthouse, Eileen N. Duesler, and David N. Hendrickson
pp 618 - 619; DOI:
10.1021/ja00470a042
PDF
Electron spin resonance observation of the photooxidation of hydrated chlorophyll a dimers by water. In vitro photochemical characterization of reaction centers in photosynthesis
F. K. Fong, A. J. Hoff, and F. A. Brinkman
pp 619 - 621; DOI:
10.1021/ja00470a043
PDF
Determination of local structures of platinum uridine blues and purples by extended x-ray absorption fine structure spectroscopy
Boon-Keng Teo, Keiji Kijima, and Robert Bau
pp 621 - 624; DOI:
10.1021/ja00470a044
PDF
Copper atom-acetylene complexes. Matrix isolation electron spin resonance study
Paul H. Kasai and D. McLeod
pp 625 - 627; DOI:
10.1021/ja00470a045
PDF
On the chemical reactivity of superoxide ion
Donald T. Sawyer, Morton J. Gibian, Mark M. Morrison, and Eddie T. Seo
pp 627 - 628; DOI:
10.1021/ja00470a046
PDF
Structure of shikodonin, a unique anti-tumor spirosecokaurene diterpenoid
Isao Kubo, Michael J. Pettei, Ken Hirotsu, Hideyuki Tsuji, and Takashi Kubota
pp 628 - 630; DOI:
10.1021/ja00470a047
PDF
Copper complex acting as a reversible carbon dioxide carrier
Tetsuo Tsuda, Yoshiki Chujo, and Takeo Saegusa
pp 630 - 632; DOI:
10.1021/ja00470a048
PDF
Specificity in enzymic decarboxylation
Marion H. O'Leary and George J. Piazza
pp 632 - 633; DOI:
10.1021/ja00470a049
PDF
Carbon magnetic resonance spectroscopy on carbon-13-labeled uracil in 5S ribonucleic acid
W. David Hamill, David M. Grant, R. Beth Cooper, and Shirley A. Harmon
pp 633 - 635; DOI:
10.1021/ja00470a050
PDF
Synthesis and characterization of [(.eta.5-C5H5)V(CO)3H]-, a new anionic vanadium carbonyl hydride, and a study of its reduction reaction with organic halides. Observation of a free-radical chain process having an extremely rapid metal-to-carbon hydrogen transfer step
Robert J. Kinney, William D. Jones, and Robert G. Bergman
pp 635 - 637; DOI:
10.1021/ja00470a051
PDF
Stereochemistry of 1,4-conjugate elimination reactions
Richard K. Hill and Mark G. Bock
pp 637 - 639; DOI:
10.1021/ja00470a052
PDF
Electrode surface modification via polymer adsorption
Larry L. Miller and Michael R. Van de Mark
pp 639 - 640; DOI:
10.1021/ja00470a053
PDF
Isolation of a stable acylrhodium(III) hydride intermediate formed during aldehyde decarbonylation. Hydroacylation
J. William Suggs
pp 640 - 641; DOI:
10.1021/ja00470a054
PDF
A priori calculations in isotopic exchange equilibriums
D. J. DeFrees, D. Z. Hassner, W. J. Hehre, E. A. Peter, and M. Wolfsberg
pp 641 - 643; DOI:
10.1021/ja00470a055
PDF
Concerning the chemical identity of 6,9.alpha.-oxido-11.alpha.,15.alpha.-dihydroxyprosta-7(8),(E)13-dienoic acid
Charles J. Sih and Fu-Chih Huang
pp 643 - 645; DOI:
10.1021/ja00470a056
PDF
Metabolic formation of 1,9,10-trihydroxy-9,10-dihydro-3-methylcholanthrene: a potential proximate carcinogen from 3-methylcholanthrene
D. R. Thakker, W. Levin, A. W. Wood, A. H. Conney, T. A. Stoming, and D. M. Jerina
pp 645 - 647; DOI:
10.1021/ja00470a057
PDF
Crystal structure of bis(.eta.5-cyclopentadienyl)chloro(neopentylidene)tantalum, Ta(.eta.5-C5H5)2(CHCMe3)Cl, a molecule containing a twisted neopentylidene ligand with a highly obtuse Ta-C(.alpha.)-C(.beta.) angle
Melvyn Rowen Churchill, Frederick J. Hollander, and Richard R. Schrock
pp 647 - 648; DOI:
10.1021/ja00470a058
PDF
Alkali metal cation catalysis of a photochemical reaction
Richard R. Hautala and Riley H. Hastings
pp 648 - 649; DOI:
10.1021/ja00470a059
PDF
Preparation and rearrangements of some 8,8-dimethylhomotropylium cations
Ronald F. Childs and Carol V. Rogerson
pp 649 - 651; DOI:
10.1021/ja00470a060
PDF
Insertion reactions of 4H-imidazolylidenes into carbon-hydrogen bonds of alcohols
Uan G. Kang and Harold Shechter
pp 651 - 652; DOI:
10.1021/ja00470a061
PDF
Metal-metal bonded clusters in transition metal Groups 3 and 4. Synthesis and structure of three M6X12-type clusters for scandium and zirconium
John D. Corbett, Richard L. Daake, Kenneth R. Poeppelmeier, and Dennis H. Guthrie
pp 652 - 654; DOI:
10.1021/ja00470a062
PDF
Diastereomeric transition states. High and low energy reaction pathways in the Cope rearrangement
Kenneth J. Shea and Richard B. Phillips
pp 654 - 655; DOI:
10.1021/ja00470a063
PDF
Photochemistry of alkyl halides. 6. gem-Diiodides. A convenient method for the cyclopropanation of olefins
Norbert J. Pienta and Paul J. Kropp
pp 655 - 657; DOI:
10.1021/ja00470a064
PDF
Stereoelectronic control in the base-catalyzed hydrogen-deuterium exchange reaction of twistan-4-one
R. R. Fraser and Philippe J. Champagne
pp 657 - 658; DOI:
10.1021/ja00470a065
PDF
Continuous wave carbon dioxide laser induced chemistry of diborane. A thermal reaction
C. Riley, S. Shatas, and Valerie Arkle
pp 658 - 660; DOI:
10.1021/ja00470a066
PDF
Prostaglandin endoperoxides. 6. A polar transition state in the thermal rearrangement of 2,3-dioxabicyclo[2.2.1]heptane
Robert G. Salomon, Mary F. Salomon, and Daniel J. Coughlin
pp 660 - 662; DOI:
10.1021/ja00470a067
PDF
X-ray crystal structure of norrufescine
Michael D. Klein, K. T. Buck, Michael P. Cava, and Donald Voet
pp 662 - 663; DOI:
10.1021/ja00470a068
PDF
Megalomicins. 6. Tertiary glycosidic macrolide antibiotics. A structural revision by carbon-13 nuclear magnetic resonance and x-ray crystallography
Ton That Thang, Gabor Lukacs, Satoshi Omura, Peter Bartner, Dena L. Boxler, Raymond Brambilla, Alan K. Mallams, James B. Morton, Paul Reichert, and et al.
pp 663 - 666; DOI:
10.1021/ja00470a069
PDF
Molecular structure of diaquo-.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinatoiron(III) perchlorate and perchlorato-.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinatoiron(III). Two new structural types for iron(III) porphyrins
M. E. Kastner, W. Robert Scheidt, Toshio Mashiko, and Christopher A. Reed
pp 666 - 667; DOI:
10.1021/ja00470a070
PDF
Book Reviews

pp 668 - 672; DOI:
10.1021/ja00470a600
PDF

Issue 3


Conformational polymorphism. The influence of crystal structure on molecular conformation
J. Bernstein and A. T. Hagler
pp 673 - 681; DOI:
10.1021/ja00471a001
PDF
Partial molar volumes of some aqueous electrolytes and a transition model
Prem P. Singh
pp 681 - 684; DOI:
10.1021/ja00471a002
PDF
Photocurrent spectroscopy of semiconductor electrodes in liquid junction solar cells
A. Heller, K. C. Chang, and B. Miller
pp 684 - 688; DOI:
10.1021/ja00471a003
PDF
Anisotropic motion inside a micelle
F. M. Menger and J. M. Jerkunica
pp 688 - 691; DOI:
10.1021/ja00471a004
PDF
The photoelectron and ultraviolet spectra of octamethylcyclododeca-1,3,7,9-tetrayne: a weakly antiaromatic molecule
Cielo Santiago, K. N. Houk, Gary J. DeCicco, and Lawrence T. Scott
pp 692 - 696; DOI:
10.1021/ja00471a005
PDF
Proton magnetic resonance and conformational energy calculations of repeat peptides of tropoelastin. The hexapeptide
Dan W. Urry, M. Abu-Khaled, V. Renugopalakrishnan, and Rao S. Rapaka
pp 696 - 705; DOI:
10.1021/ja00471a006
PDF
Determination of structures of molecular complex in solution using unpaired electron-induced nuclear magnetic relaxation. Application to adenosine 5'-monophosphate and N-methylphenazinium cation radical
Yoshio Nosaka, Kazuyuki Akasaka, and Hiroyuki Hatano
pp 706 - 713; DOI:
10.1021/ja00471a007
PDF
A stopped-flow pulse Fourier transform nuclear magnetic resonance investigation of the rates of chlorination of metal acetylacetonates by N-chlorosuccinimide
Alan J. Brown, Oliver W. Howarth, and Peter Moore
pp 713 - 718; DOI:
10.1021/ja00471a008
PDF
An analysis of the effects of alkyl substituents on the ionization potentials of n-alkenes
David A. Krause, James W. Taylor, and Richard F. Fenske
pp 718 - 723; DOI:
10.1021/ja00471a009
PDF
Electronic states of organic molecules. 6. Analysis of infrared intensities. The hybrid orbital rehybridization model. Charge distribution in molecules
Kenneth B. Wiberg and John J. Wendoloski
pp 723 - 732; DOI:
10.1021/ja00471a010
PDF
Basis set and electron correlation effects on the total electron density in water, hydrogen sulfide, and borane(1)
Jozef Bicerano, Dennis S. Marynick, and William N. Lipscomb
pp 732 - 739; DOI:
10.1021/ja00471a011
PDF
Accurate ab initio calculations on the singlet-triplet separation in methylene
Charles W. Bauschlicher and Isaiah Shavitt
pp 739 - 743; DOI:
10.1021/ja00471a012
PDF
The transition state for the epoxidation of ethylene with peroxyformic acid. An ab initio molecular orbital study
Bozo Plesnicar, Milan Tasevski, and Andrej Azman
pp 743 - 746; DOI:
10.1021/ja00471a013
PDF
A theoretical study of the reaction of methane with methyl radical using several different ab initio and semiempirical methods
M. T. Rayez-Meaume, J. J. Dannenberg, and J. L. Whitten
pp 747 - 749; DOI:
10.1021/ja00471a014
PDF
Ab initio SCF treatment of allyl anion and distorted propenyl anions
Donald W. Boerth and Andrew Streitwieser
pp 750 - 754; DOI:
10.1021/ja00471a015
PDF
Carbon acidity. 54. Kinetic acidities of cycloalkenes with lithium cyclohexylamide
Andrew Streitwieser and Donald W. Boerth
pp 755 - 759; DOI:
10.1021/ja00471a016
PDF
An ab initio molecular orbital study of structures and energies of spiro compounds: spiropentane, spiropentene, spiropentadiene, spiro[2.4]hepta-4,6-diene, spiro[2.4]heptatriene, and spiro[4.4]nonatetraene
James Kao and Leo Radom
pp 760 - 767; DOI:
10.1021/ja00471a017
PDF
An INDO MO study of substituent effects upon 3JCC
Victor Wray
pp 768 - 770; DOI:
10.1021/ja00471a018
PDF
Molecular orbital constraint of interaction coordinates. An approximate quadratic potential function
B. I. Swanson, T. H. Arnold, M. J. S. Dewar, J. J. Rafalko, H. S. Rzepa, and Y. Yamaguchi
pp 771 - 777; DOI:
10.1021/ja00471a019
PDF
Ground states of molecules. 45. MNDO results for molecules containing beryllium
Michael J. S. Dewar and Henry S. Rzepa
pp 777 - 784; DOI:
10.1021/ja00471a020
PDF
Calculations of electron affinities using the MNDO semiempirical SCF-MO method
Michael J. S. Dewar and Henry S. Rzepa
pp 784 - 790; DOI:
10.1021/ja00471a021
PDF
Strength and trans influence of the rhodium-rhodium bond in rhodium(II) carboxylate dimers
Joe G. Norman and Harold J. Kolari
pp 791 - 799; DOI:
10.1021/ja00471a022
PDF
Crystal and molecular structure of a covalent perchloric acid ester: p-tolylsulfonylmethyl perchlorate
Jan B. F. N. Engberts, Hans Morssink, and Aafje Vos
pp 799 - 802; DOI:
10.1021/ja00471a023
PDF
Reactions of metal-to-metal multiple bonds. 1. .mu.-Allene-bis(cyclopentadienyl)tetracarbonyldimolybdenum and -ditungsten compounds. Preparation, properties, and structural characterization
W. I. Bailey, M. H. Chisholm, F. A. Cotton, C. A. Murillo, and L. A. Rankel
pp 802 - 807; DOI:
10.1021/ja00471a024
PDF
Reactions of metal-to-metal multiple bonds. 2. Reactions of bis(cyclopentadienyl)tetracarbonyldimolybdenum with small unsaturated molecules. Structural characterization of .mu.-dimethylaminocyanamide-bis(cyclopentadienyl)tetracarbonyldimolybdenum
M. H. Chisholm, F. A. Cotton, M. W. Extine, and L. A. Rankel
pp 807 - 811; DOI:
10.1021/ja00471a025
PDF
Positively charged ligands. The coordination behavior of sulfonium cations
Richard D. Adams and Daniel F. Chodosh
pp 812 - 817; DOI:
10.1021/ja00471a026
PDF
A mechanistic investigation of cobaloxime complexes containing good trans labilizing ligands, including spectroscopic and rate comparisons
Robert Charles Stewart and Luigi G. Marzilli
pp 817 - 822; DOI:
10.1021/ja00471a027
PDF
Carboxyalkyl- and carboxyphenylcobaloximes. Substituent effect of chelated cobalt
Kenneth L. Brown, Allan W. Awtrey, and Ronald LeGates
pp 823 - 828; DOI:
10.1021/ja00471a028
PDF
Metallocyclobutanes. Preparation and structural characterization of the products of insertion of (ethylene)bis(triphenylphosphine)platinum into 1,1,2,2,-tetracyano-3-phenylcyclopropane and 1-carboethoxy-1,2,2-tricyano-trans-3-phenylcyclopropane
Jayaraman Rajaram and James A. Ibers
pp 829 - 838; DOI:
10.1021/ja00471a029
PDF
Stereochemistry of oxidative addition of benzyl-.alpha.-d chloride and bromide to tris(triethylphosphine)palladium(0). Direct observation of optical activity in a carbon-palladium .sigma.-bonded complex
Y. Becker and J. K. Stille
pp 838 - 844; DOI:
10.1021/ja00471a030
PDF
The dynamic .eta.1- and .eta.3-benzylbis(triethylphosphine)palladium(II) cations. Mechanisms of interconversion
Y. Becker and J. K. Stille
pp 845 - 850; DOI:
10.1021/ja00471a031
PDF
Photochemical transformations. 20. Intermediates in the sensitized photorearrangements of the .alpha.- and .gamma.-methylallyl chlorides
Stanley J. Cristol and Roger P. Micheli
pp 850 - 855; DOI:
10.1021/ja00471a032
PDF
Acyl migration in the acid-catalyzed decomposition of .alpha.-hydroperoxy ketones
Yasuhiko Sawaki and Yoshiro Ogata
pp 856 - 860; DOI:
10.1021/ja00471a033
PDF
Diels-Alder cycloadditions of a bicyclobutane bridged diene. Acid and thermal stability of benzvalene derivatives as a function of substituents
H. Hogeveen and W. F. J. Huurdeman
pp 860 - 871; DOI:
10.1021/ja00471a034
PDF
Comparison of Diels-Alder reactivity of a bicyclobutane and of a cyclobutane bridged diene
H. Hogeveen, W. F. J. Huurdeman, and D. M. Kok
pp 871 - 877; DOI:
10.1021/ja00471a035
PDF
The aromatic Cope rearrangement. Thermal reactions of cis-1-aryl-2-vinylcyclopropanes
Elliot N. Marvell and Crystal Lin
pp 877 - 883; DOI:
10.1021/ja00471a036
PDF
Rates of the Cope rearrangement of some 2-aryl-1,5-hexadienes
Elliot N. Marvell and Thomas H. C. Li
pp 883 - 888; DOI:
10.1021/ja00471a037
PDF
Absolute rate constants for reactions of phenyl radicals
V. Madhavan, Robert H. Schuler, and Richard W. Fessenden
pp 888 - 893; DOI:
10.1021/ja00471a038
PDF
Stereochemistry of ozonide formation. Effects of complexing agents and rate of warm-up
Philip S. Bailey, Thomas M. Ferrell, A. Rustaiyan, Selim Seyhan, and Leonard E. Unruh
pp 894 - 898; DOI:
10.1021/ja00471a039
PDF
Mechanism of ozonolysis. A more flexible stereochemical concept
Philip S. Bailey and Thomas M. Ferrell
pp 899 - 905; DOI:
10.1021/ja00471a040
PDF
A new approach to the construction of diamondoid hydrocarbons. Synthesis of anti-tetramantane
William Burns, M. Anthony McKervey, Thomas R. B. Mitchell, and John J. Rooney
pp 906 - 911; DOI:
10.1021/ja00471a041
PDF
Intrinsic asymmetry and diastereotopism
J. Reisse, R. Ottinger, P. Bickart, and K. Mislow
pp 911 - 915; DOI:
10.1021/ja00471a042
PDF
Approach to the aspects of driving force of inclusion by .alpha.-cyclodextrin
Iwao Tabushi, Yoichi Kiyosuke, Takuji Sugimoto, and Kazuo Yamamura
pp 916 - 919; DOI:
10.1021/ja00471a043
PDF
Diazenyl radicals: a nitrogen-15 CIDNP and radical trapping study of unsymmetric diazenes
Ned A. Porter, George R. Dubay, and John G. Green
pp 920 - 925; DOI:
10.1021/ja00471a044
PDF
The evidence for generation of dimethylaminocyanocarbene in the thermolysis of dimethylaminomalononitrile. The dimethylamino(dicyano- and cyano)methyl radicals, carbon analogs of the nitroxides
Louis De Vries
pp 926 - 933; DOI:
10.1021/ja00471a045
PDF
Mononitroxides and proximate dinitroxides derived by oxidation of 2,2,4,4,5,5-hexasubstituted imidazolidines. A new series of nitroxide and dinitroxide spin labels
John F. W. Keana, Robert S. Norton, Michael Morello, Donna Van Engen, and Jon Clardy
pp 934 - 937; DOI:
10.1021/ja00471a046
PDF
Total synthesis of dregamine and epidregamine. A general route to 2-acylindole alkaloids
James P. Kutney, Gunter K. Eigendorf, Hajime Matsue, Akio Murai, Kiyoshi Tanaka, Wing L. Sung, Kojiro Wada, and Brian R. Worth
pp 938 - 943; DOI:
10.1021/ja00471a047
PDF
Conformational preferences of the bridging groups of cyclo-L-cystine and the active fragments of epipolythiodiketopiperazine antibiotics
Allan R. Gregory and Maria Przybylska
pp 943 - 949; DOI:
10.1021/ja00471a048
PDF
Crystal structure and conformation of the cyclic dipeptide cyclo-(L-histidyl-L-aspartyl) trihydrate
R. Ramani, K. Venkatesan, and R. E. Marsh
pp 949 - 953; DOI:
10.1021/ja00471a049
PDF
Sulfuranes. 35. Synthesis, reactions, and crystal and molecular structure of a sulfurane with two apical nitrogen-centered ligands: a spirodiazasulfurane
L. J. Adzima, Chian C. Chiang, Iain C. Paul, and J. C. Martin
pp 953 - 962; DOI:
10.1021/ja00471a050
PDF
Kinetics of chlorpromazine cation radical decomposition in aqueous buffers
Hung Yuan Cheng, Patricia Holt Sackett, and Richard L. McCreery
pp 962 - 967; DOI:
10.1021/ja00471a051
PDF
Study of the kinetics of reduction of an iron(III) porphyrin by hexaammineruthenium(II). Estimate of the self-exchange rate for a high-spin iron porphyrin complex
Robert F. Pasternack and Esther G. Spiro
pp 968 - 972; DOI:
10.1021/ja00471a052
PDF
[5-Aspartic acid]-oxytocin: first 5-position neurohypophyseal hormone analog possessing significant biological activity
Roderich Walter, Gerald Skala, and Clark W. Smith
pp 972 - 973; DOI:
10.1021/ja00471a053
PDF
Ipso nitration. Characterization of nitro group shifts in 4-methyl-4-nitrocyclohexa-2,5-dienones
Craig E. Barnes and Philip C. Myhre
pp 973 - 975; DOI:
10.1021/ja00471a054
PDF
Ipso nitration. A study of the migratory aptitude of the nitro group in the 1,2-dimethyl-1-nitrocyclohexadienyl cation
Craig E. Barnes and Philip C. Myhre
pp 975 - 976; DOI:
10.1021/ja00471a055
PDF
Europium(IV), a new oxidation state for europium. Crystal structure of dehydrated europium(II)-exchanged sodium zeolite A, Eu4.5Na3-A, partially oxidized by oxygen
R. L. Firor and K. Seff
pp 976 - 978; DOI:
10.1021/ja00471a056
PDF
Five-coordinate europium(IV) and zero-coordinate europium(II). Crystal structure of dehydrated near-fully europium(II)-exchanged zeolite A, Eu5.5Na-A, partially oxidized by chlorine
R. L. Firor and K. Seff
pp 978 - 980; DOI:
10.1021/ja00471a057
PDF
Cyclopropa[3,4]benzocyclobutene
Dariush Davalian, Peter J. Garratt, and Muzammil M. Mansuri
pp 980 - 981; DOI:
10.1021/ja00471a058
PDF
On the nature of tris(2,2'-bipyridine)ruthenium(1+) ion in aqueous solution
Q. G. Mulazzani, S. Emmi, P. G. Fuochi, M. Z. Hoffman, and M. Venturi
pp 981 - 983; DOI:
10.1021/ja00471a059
PDF
Divergent cycloaddition pathways for reaction of singlet stilbene and stilbene excimer with dimethyl fumarate
Frederick D. Lewis and Douglas E. Johnson
pp 983 - 984; DOI:
10.1021/ja00471a060
PDF
Determination of critical micelle concentrations in micellar and reversed micellar systems by positron annihilation techniques
Yan-Ching Jean and Hans J. Ache
pp 984 - 985; DOI:
10.1021/ja00471a061
PDF
A cyclic disulfurane with sulfur-oxygen, sulfur-carbon, and/or sulfur-nitrogen bonds. 3. Some new cyclic S,S-bis(trifluoromethyl)catecholatosulfur(IV) compounds
Tomoya Kitazume and Jean'ne M. Shreeve
pp 985 - 987; DOI:
10.1021/ja00471a062
PDF
Spectroscopic and magnetic properties of an exchange coupled copper(II)-manganese(II) dimer
David A. Krost and Gary L. McPherson
pp 987 - 989; DOI:
10.1021/ja00471a063
PDF
Reversible binding of dioxygen by tris(3,5-di-tert-butylcatecholato)manganese(III) in dimethyl sulfoxide
Keith D. Magers, Cecil G. Smith, and Donald T. Sawyer
pp 989 - 991; DOI:
10.1021/ja00471a064
PDF
Novel electrochemical reactions of compounds containing strong metal-metal bonds. Oxidation of rhenium(II) dimers, Re2X4(PR3)4, by both EECC and ECEC pathways
D. J. Salmon and R. A. Walton
pp 991 - 993; DOI:
10.1021/ja00471a065
PDF
Cationic cyclization of allenes. Preferential cyclization via vinyl cations
Kenn E. Harding, James L. Cooper, and Paul M. Puckett
pp 993 - 994; DOI:
10.1021/ja00471a066
PDF
Gas-phase reactions of phenyltrimethylgermylcarbene. Evidence for transient formation of 1,1-dimethyl-2-phenylgermirane
Ellis B. Norsoph, Brian Coleman, and Maitland Jones
pp 994 - 995; DOI:
10.1021/ja00471a067
PDF
Hypovalent radicals. 2. Fluorenylidene anion radical - possible redox potentials for the fluorenylidene/fluorenylidene anion radical couple
Richard N. McDonald, K. J. Borhani, and M. Dale Hawley
pp 995 - 996; DOI:
10.1021/ja00471a068
PDF
Transition metal initiated cationic photopolymerization
Michael E. Woodhouse, Frederick D. Lewis, and Tobin J. Marks
pp 996 - 998; DOI:
10.1021/ja00471a069
PDF
Novel iron complexes from concondensations of iron vapor with aminodifluorophosphines
M. Chang, R. B. King, and M. G. Newton
pp 998 - 999; DOI:
10.1021/ja00471a070
PDF
Triple decker sandwich compounds: paramagnetic tris(cyclooctatetraene)dititanium and its dianion
Stanislav P. Kolesnikov, Jerry E. Dobson, and Philip S. Skell
pp 999 - 999; DOI:
10.1021/ja00471a071
PDF
Conformational equilibrium of the 17(20) rotamers of (E)-20(22)-dehydrocholesterol
William R. Nes
pp 999 - 1000; DOI:
10.1021/ja00471a072
PDF
Silyl phosphites. 6. Reactions of tris(trimethylsilyl) phosphite with .alpha.-halocarbonyl compounds
Mitsuo Sekine, Kiyomi Okimoto, and Tsujiaki Hata
pp 1001 - 1002; DOI:
10.1021/ja00471a073
PDF
Tridachione, a propionate-derived metabolite of the opisthobranch mollusc Tridachiella diomedea
Chris Ireland, D. John Faulkner, Barbara A. Solheim, and Jon Clardy
pp 1002 - 1003; DOI:
10.1021/ja00471a074
PDF
Metal-metal interactions in binuclear rhodium(I) complexes derived from the 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato macrocyclic ligand
Guy C. Gordon, Patrick W. DeHaven, Marvin C. Weiss, and Virgil L. Goedken
pp 1003 - 1005; DOI:
10.1021/ja00471a075
PDF
Unusual reactivity of trifluoroacetyl peptide chloromethyl ketones with pancreatic elastase
A. Renaud, J. L. Dimicoli, P. Lestienne, and J. Bieth
pp 1005 - 1007; DOI:
10.1021/ja00471a076
PDF
Benzannelated annulenes. 3. A clear demonstration of importance of symmetrical Kekule structures to diatropicity (aromaticity). Synthesis of a stable, highly diatropic, dibenzannulene
Reginald H. Mitchell, Robert J. Carruthers, and Ludvik Mazuch
pp 1007 - 1008; DOI:
10.1021/ja00471a077
PDF
Organic thermal reactions. 39. Deep-seated rearrangement in the anionic oxy-Cope system. Extremely facile epimerically unfavorable anionic oxy-Cope rearrangement of anti-bisallylic 1,5,7-triene alkoxides
Tsutomu Miyashi, Atsuo Hazato, and Toshio Mukai
pp 1008 - 1010; DOI:
10.1021/ja00471a078
PDF
A mechanism for the biomethylation of tin by reductive cobalt-carbon bond cleavage of alkylcobalamins
L. J. Dizikes, W. P. Ridley, and J. M. Wood
pp 1010 - 1012; DOI:
10.1021/ja00471a079
PDF
Anodic oxidation of uranocene. Evidence for new organouranium cations in solution
Jared A. Butcher, James Q. Chambers, and Richard M. Pagni
pp 1012 - 1013; DOI:
10.1021/ja00471a080
PDF
Synthesis of highly conducting films of derivatives of polyacetylene, (CH)x
C. K. Chiang, M. A. Druy, S. C. Gau, A. J. Heeger, E. J. Louis, A. G. MacDiarmid, Y. W. Park, and H. Shirakawa
pp 1013 - 1015; DOI:
10.1021/ja00471a081
PDF
Protonation and ionization of 4-chlorocyclohexene in superacid. A fast 1,2-hydride shift in the 4-cyclohexenyl cation
Dan Farcasiu
pp 1015 - 1016; DOI:
10.1021/ja00471a082
PDF
Book Reviews

pp 1017 - 1018; DOI:
10.1021/ja00471a600
PDF

Issue 4


Mechanisms of the reaction of positive atomic oxygen ions with nitrogen
Darrel G. Hopper
pp 1019 - 1029; DOI:
10.1021/ja00472a001
PDF
Force and density study on the chemical reaction process NH2 + H .fwdarw. NH3
H. Nakatsuji, T. Koga, K. Kondo, and T. Yonezawa
pp 1029 - 1036; DOI:
10.1021/ja00472a002
PDF
Through-bond interaction of two mutually perpendicular .pi. systems. A comparison with spiroconjugation
Peter Bischof, Rolf Gleiter, and Rudolf Haider
pp 1036 - 1042; DOI:
10.1021/ja00472a003
PDF
Oscillations in chemical systems. 24. Oscillatory decomposition of formic acid in sulfuric acid
Kenneth Showalter and Richard M. Noyes
pp 1042 - 1049; DOI:
10.1021/ja00472a004
PDF
Electronic structure and protonation of alkyl chlorides
William L. Jorgensen
pp 1049 - 1056; DOI:
10.1021/ja00472a005
PDF
Chemical consequences of orbital interactions. 13. Ab initio molecular orbital study of the geometries, properties, and protonation of alkyl chlorides
William L. Jorgensen
pp 1057 - 1061; DOI:
10.1021/ja00472a006
PDF
Vibrational energy distributions of reacting CH2(1A1) from the 4358, 3660, and 2537 .ANG. photolyses of CH2N2 and upon reaction with cyclobutane. A chemical activation study
T. H. Richardson and J. W. Simons
pp 1062 - 1068; DOI:
10.1021/ja00472a007
PDF
Conformational analysis. 128. The Woodward-Fieser rules and .alpha.,.beta.-unsaturated ketones
Tommy Liljefors and Norman L. Allinger
pp 1068 - 1073; DOI:
10.1021/ja00472a008
PDF
Must a molecule have a shape?
R. G. Woolley
pp 1073 - 1078; DOI:
10.1021/ja00472a009
PDF
Induced equilibrium shifts in labile racemates. The nature of the discriminatory interactions in the Pfeiffer effect
Pieter E. Schipper
pp 1079 - 1084; DOI:
10.1021/ja00472a010
PDF
Base-catalyzed isotopic exchange of molecular hydrogen. 4. Hydrogen isotope effects in the dimethyl sulfoxide-water system
E. Buncel, E. A. Symons, and Rory A. More O'Ferrall
pp 1084 - 1092; DOI:
10.1021/ja00472a011
PDF
Theoretical studies of the kinetics of planar-tetrahedral equilibration in nickel(II) complexes. 1. Reaction coordinates and potential energy surfaces
Lawrence L. Lohr
pp 1093 - 1099; DOI:
10.1021/ja00472a012
PDF
Theoretical studies of the kinetics of planar-tetrahedral equilibration in nickel(II) complexes. 2. Reaction probabilities and rate constants
Lawrence L. Lohr and Erik K. Grimmelmann
pp 1100 - 1105; DOI:
10.1021/ja00472a013
PDF
Resonance Raman spectra of cobalt(II)-imidazole complexes: analogs of the binding site of cobalt-substituted zinc proteins
Simon Salama and Thomas G. Spiro
pp 1105 - 1111; DOI:
10.1021/ja00472a014
PDF
Magnetic resonance investigation of the autoreduction of tetraphenylporphinatoiron(III) chloride in the presence of piperidine
John Del Gaudio and Gerd N. La Mar
pp 1112 - 1119; DOI:
10.1021/ja00472a015
PDF
Synthetic and mechanistic studies of the reduction of .alpha.,.beta.-unsaturated carbonyl compounds by the binuclear cluster, sodium hydrogen octacarbonyldiferrate
James P. Collman, Richard G. Finke, Paul L. Matlock, Robert Wahren, Robert G. Komoto, and John I. Brauman
pp 1119 - 1140; DOI:
10.1021/ja00472a016
PDF
Dynamics of intersystem crossing processes in solution for six-coordinate d5, d6, and d7 spin-equilibrium metal complexes of iron(III), iron(II), and cobalt(II)
Eric V. Dose, Mitchell A. Hoselton, Norman Sutin, Michael F. Tweedle, and Lon J. Wilson
pp 1141 - 1147; DOI:
10.1021/ja00472a017
PDF
A kinetic and mechanistic study of the formation of iridium(III) ozonide complexes by the insertion of hexafluoroacetone into complexes IrX(CO)L2O2 (X = halogen, L = substituted phosphine or arsine)
William B. Beaulieu, Gary D. Mercer, and D. Max Roundhill
pp 1147 - 1152; DOI:
10.1021/ja00472a018
PDF
Molecular orbital theory for catalysis. Structures, energy levels, and reactions of acetylene with Ni2(COD)2(RC.tplbond.CR), Ni2(C5H5)2(RC.tplbond.CR), and the nickel(111) surface
Alfred B. Anderson
pp 1153 - 1159; DOI:
10.1021/ja00472a019
PDF
Production of hydrogen by ultraviolet irradiation of binuclear molybdenum(II) complexes in acidic aqueous solutions. Observation of molybdenum hydride intermediates in octahalodimolybdate(II) photoreactions
William C. Trogler, David K. Erwin, Gregory L. Geoffroy, and Harry B. Gray
pp 1160 - 1163; DOI:
10.1021/ja00472a020
PDF
Chemistry and molecular structure of a product formed through enamine-ketimine tautomerism in a Pd-C(CH3):NR fragment
H. C. Clark, C. R. C. Milne, and N. C. Payne
pp 1164 - 1169; DOI:
10.1021/ja00472a021
PDF
Specific sequestering agents for the actinides. 1. N,N',N'',N'''-Tetra(2,3-dihydroxybenzoyl)tetraazacyclotetra- and -hexadecanes
Frederick L. Weitl, Kenneth N. Raymond, William L. Smith, and Thomas R. Howard
pp 1170 - 1172; DOI:
10.1021/ja00472a022
PDF
Mechanisms of photochemical reactions in solution. 77. The effect of configuration in some bicyclic di-.pi.-methanes with simple chromophores
Richard G. Weiss and George S. Hammond
pp 1172 - 1182; DOI:
10.1021/ja00472a023
PDF
Stable free radicals. 8. Photochemical decomposition of 1,8-biphenylenediyl bismethyl and o-xylenyl pyridinyl diradicals
Edward M. Kosower and Avraham Teuerstein
pp 1182 - 1185; DOI:
10.1021/ja00472a024
PDF
Stable free radicals. 9. Magnesium and other metal halide complexes of pyridinyl diradicals
Edward M. Kosower, Joseph Hajdu, and Janos B. Nagy
pp 1186 - 1193; DOI:
10.1021/ja00472a025
PDF
Aluminum trichloride .sigma. complexes of cyclobutadienes
P. B. J. Driessen and H. Hogeveen
pp 1193 - 1200; DOI:
10.1021/ja00472a026
PDF
Radical brominations of some chloroalkanes. Evidence for anchimeric assistance by neighboring chlorine
Charles R. Everly, Fritz Schweinsberg, and James G. Traynham
pp 1200 - 1205; DOI:
10.1021/ja00472a027
PDF
Cyclohexadienyl cations. 7. Kinetics and mechanism of the acid-catalyzed dienol-benzene rearrangement
V. P. Vitullo, M. J. Cashen, J. N. Marx, L. J. Caudle, and J. R. Fritz
pp 1205 - 1210; DOI:
10.1021/ja00472a028
PDF
Molecular orbital theory of the electronic structure of molecules. 38. Flexible olefins preferring nonplanar puckered structures
Hans Ulrich Wagner, Guenter Szeimies, Jayaraman Chandrasekhar, Paul V. R. Schleyer, John A. Pople, and J. Stephen Binkley
pp 1210 - 1213; DOI:
10.1021/ja00472a029
PDF
Remote functionalization reactions as conformational probes for flexible alkyl chains
Ronald Breslow, Jonathan Rothbard, Frederick Herman, and Matias L. Rodriguez
pp 1213 - 1218; DOI:
10.1021/ja00472a030
PDF
Structural effects in solvolytic reactions. 24. Solvolysis of 1-cycloalkyl-1-aryl-1-ethyl p-nitrobenzoates. Effect of .alpha.-cycloalkyl groups in stabilizing an electron-deficient center as revealed by the tool of increasing electron demand
Herbert C. Brown, M. Ravindranathan, and C. Gundu Rao
pp 1218 - 1222; DOI:
10.1021/ja00472a031
PDF
Organic sulfur chemistry. 26. Synthesis and reactions of some new sulfur transfer reagents
David N. Harpp, Kosta Steliou, and T. H. Chan
pp 1222 - 1228; DOI:
10.1021/ja00472a032
PDF
General acid catalyzed breakdown of ketone bisulfites
P. R. Young and W. P. Jencks
pp 1228 - 1235; DOI:
10.1021/ja00472a033
PDF
Naphtho[1,8-cd:4,5-c'd']bis[1,2,6]thiadiazine. A compound of ambiguous aromatic character
R. C. Haddon, M. L. Kaplan, and J. H. Marshall
pp 1235 - 1239; DOI:
10.1021/ja00472a034
PDF
Solvent effects of water and fluorosulfuric acid on proton transfer equilibriums and the energies of solvation of gaseous onium ions
R. W. Taft, J. F. Wolf, J. L. Beauchamp, G. Scorrano, and E. M. Arnett
pp 1240 - 1249; DOI:
10.1021/ja00472a035
PDF
Vinyl ether hydrolysis. 10. Methyl .alpha.-cyclopropylvinyl ether. A search for a change in reaction mechanism
A. J. Kresge and W. K. Chwang
pp 1249 - 1253; DOI:
10.1021/ja00472a036
PDF
Fluorescence probes in reversed micelles. Luminescence intensities, lifetimes, quenching, energy transfer, and depolarization of pyrene derivatives in cyclohexane in the presence of dodecylammonium propionate aggregates
Glenn D. Correll, Raymond N. Cheser, Faruk Nome, and Janos H. Fendler
pp 1254 - 1262; DOI:
10.1021/ja00472a037
PDF
Oxycyclopropanes in organochemical synthesis. Total syntheses of (-)-valeranone and (.+-.)-grandisol
Ernest Wenkert, David A. Berges, and Norman F. Golob
pp 1263 - 1267; DOI:
10.1021/ja00472a038
PDF
Oxycyclopropanes in organochemical synthesis. Total syntheses of (.+-.)-.alpha.-cuparenone and (.+-.)-.beta.-vetivone
Ernest Wenkert, Brian L. Buckwalter, Afranio A. Craveiro, Eduardo L. Sanchez, and Sharatchandra S. Sathe
pp 1267 - 1273; DOI:
10.1021/ja00472a039
PDF
Measurement of hydrogen exchange at the tyrosine residues in ribonuclease A by stopped-flow and ultraviolet spectroscopy
Mamoru Nakanishi and Masamichi Tsuboi
pp 1273 - 1275; DOI:
10.1021/ja00472a040
PDF
Electronic structure of sulfur compounds. 23. Photoelectron spectra of some pyrazolinethiones, 1,2,3-triazolinethiones, and 4-(1,2,3-triazolium) sulfides. Evidence of an abnormal effect of methylation
C. Guimon, G. Pfister-Guillouzo, and M. Begtrup
pp 1275 - 1278; DOI:
10.1021/ja00472a041
PDF
Conformational and ion binding studies of a cyclic pentapeptide. Evidence for .beta. and .gamma. turns in solution
Lila G. Pease and Christopher Watson
pp 1279 - 1286; DOI:
10.1021/ja00472a042
PDF
Crystal structure and conformation of cyclo-(glycylprolylglycyl-D-alanylprolyl) containing 4 .fwdarw. 1 and 3 .fwdarw. 1 intramolecular hydrogen bonds
Isabella L. Karle
pp 1286 - 1289; DOI:
10.1021/ja00472a043
PDF
Enzymic hydroxylation of ferrocene
Robert P. Hanzlik and William H. Soine
pp 1290 - 1291; DOI:
10.1021/ja00472a044
PDF
Hemiacetal buildup during acetal hydrolysis
James L. Jensen and Paul A. Lenz
pp 1291 - 1293; DOI:
10.1021/ja00472a045
PDF
Photochemical reactions in organized monolayer assemblies. 8. Environmental effects on photochemical reactions: contrasts in the photooxidation behavior of protoporphyrin IX in solution, monolayer films, organized monolayer assemblies, and micelles
Barbara E. Horsey and David G. Whitten
pp 1293 - 1295; DOI:
10.1021/ja00472a046
PDF
Radical-induced pseudocontact shifts
John C. Waterton and Jeremy K. M. Sanders
pp 1295 - 1296; DOI:
10.1021/ja00472a047
PDF
High resolution phosphorus-31 and carbon-13 nuclear magnetic resonance spectra of unsonicated model membranes
R. A. Haberkorn, J. Herzfeld, and R. G. Griffin
pp 1296 - 1298; DOI:
10.1021/ja00472a048
PDF
Photocalorimetry. Enthalpies of photolysis of trans-azobenzene, ferrioxalate and cobaltioxalate ions, chromium hexacarbonyl, and dirhenium decarbonyl
Arthur W. Adamson, Arnd Vogler, Horst Kunkely, and Rudolf Wachter
pp 1298 - 1300; DOI:
10.1021/ja00472a049
PDF
The relationship between metallacyclopentanes and bis(olefin)-metal complexes
R. H. Grubbs and A. Miyashita
pp 1300 - 1302; DOI:
10.1021/ja00472a050
PDF
.alpha.-Diketone sensitized photooxidation of pyrimidines
Hong-Son Ryang and Shih Yi Wang
pp 1302 - 1303; DOI:
10.1021/ja00472a051
PDF
Stereochemistry of the hydroxypalladation of ethylene. Evidence for trans addition in the wacker process
J. K. Stille and R. Divakaruni
pp 1303 - 1304; DOI:
10.1021/ja00472a052
PDF
Specific catalysis of ester hydrolysis by a new water-soluble heterocyclophane
Iwao Tabushi, Yoshio Kimura, and Kazuo Yamamura
pp 1304 - 1306; DOI:
10.1021/ja00472a053
PDF
Photochemical formation of methylenecyclopropane analogs. 2. Tris(imino)methanes. An electron spin resonance identification of nitrogen analogs of trimethylenemethane
Helmut Quast, Lothar Bieber, and Wayne C. Danen
pp 1306 - 1307; DOI:
10.1021/ja00472a054
PDF
Energetics of the thermal polymerization of a diacetylene crystal
R. R. Chance, G. N. Patel, E. A. Turi, and Y. P. Khanna
pp 1307 - 1309; DOI:
10.1021/ja00472a055
PDF
Formose reactions. 5. A selective formose reaction
Yoshihiro Shigemasa, Osamu Nagae, Chikahiro Sakazawa, Ruka Nakashima, and Teruo Matsuura
pp 1309 - 1310; DOI:
10.1021/ja00472a056
PDF
Correlation of electronic spectra of metalloporphyrins and metalloproteins
James C. W. Chien
pp 1310 - 1312; DOI:
10.1021/ja00472a057
PDF
.pi.-arene complexes of nickel(II) stabilized by .sigma.-bonded pentafluorophenyl ligands. Homogeneous arene hydrogenation catalysis and unusually labile .pi.-arene ligands
Kenneth J. Klabunde, Bruce B. Anderson, Michael Bader, and Lewis J. Radonovich
pp 1313 - 1314; DOI:
10.1021/ja00472a058
PDF
Reactions of carbenes at low temperatures. Diphenylcarbene and isobutene
Robert A. Moss and John K. Huselton
pp 1314 - 1315; DOI:
10.1021/ja00472a059
PDF
Selective olefin dimerization via tantallocyclopentane complexes
S. J. McLain and R. R. Schrock
pp 1315 - 1317; DOI:
10.1021/ja00472a060
PDF
A novel 16-electron cyclooctenyliron(II) cation
S. D. Ittel, F. A. Van-Catledge, C. A. Tolman, and J. P. Jesson
pp 1317 - 1318; DOI:
10.1021/ja00472a061
PDF
Binding and activation of enzymic substrates by metal complexes. 4. Structural evidence for acetylene as a four-electron donor in carbonylacetylenebis(diethyldithiocarbamate)tungsten
Louis Ricard, Raymond Weiss, W. E. Newton, Grace J. J. Chen, and John W. McDonald
pp 1318 - 1320; DOI:
10.1021/ja00472a062
PDF
Reversible binding of acetylene by oxobis(diethyldithiocarbamate)molybdenum
E. A. Maatta, R. A. D. Wentworth, W. E. Newton, John W. McDonald, and Gerald D. Watt
pp 1320 - 1321; DOI:
10.1021/ja00472a063
PDF
On the mechanism of the thermal Cope rearrangement of allyl-substituted cyclopropenes
Albert Padwa and Thomas J. Blacklock
pp 1321 - 1323; DOI:
10.1021/ja00472a064
PDF
Laser-induced chemiluminescence: variation of reaction rates with reagent approach geometry
Ron C. Estler and Richard N. Zare
pp 1323 - 1324; DOI:
10.1021/ja00472a065
PDF
Carbanions from deprotonation of .alpha.-(phenylthio)alkaneboronic esters
Donald S. Matteson and Karl Arne
pp 1325 - 1326; DOI:
10.1021/ja00472a066
PDF
Additions and Corrections - Flash Photolysis of Na+, C-(Ph)2CH2CH2C-(Ph)2,Na+. Redox Potential of 1,1-Diphenylethylene and Rate Constant of Dimerization of Its Radical Anion
H. C. Wang, E. D. Lillie, S. Slomkowski, G. Levin, and M. Szwarc
pp 1326 - 1326; DOI:
10.1021/ja00472a600
PDF
Additions and Corrections - Cyclic Peptides. 17. Metal and Amino Acid Complexes of cyclo(Pro-Gly)4 and Analogues Studies by Nuclear Magnetic Resonance and Circular Dichroism
Vincent Madison, Charles M. Deber, and Elkan R. Blout
pp 1326 - 1326; DOI:
10.1021/ja00472a601
PDF
Additions and Corrections - Application of Linear Dichroism to the Analysis of Electronic Absorption Spectra of Biphenyl, Fluorene, 9,9'-Spirobifluorene, and [6.6]Vespirene. Interpretation of the Circular Dichroism Spectrum of [6.6]Vespirene.
Jacob Sagiv, Amnon Yogev, and Yehuda Mazur
pp 1326 - 1327; DOI:
10.1021/ja00472a602
PDF
Additions and Corrections - Crystal and Molecular Structure of perfluorobenzo[1,2:3,4:5,6]tricyclobutene
Randolph P. Thummel, James D. Korp, Ivan Bernal, Richard L. Harlow, and R. L. Soulen
pp 1327 - 1327; DOI:
10.1021/ja00472a603
PDF
Additions and Corrections - New Synthetic Reactions. Stereoreversed Cyclobutanone Formation Utilizing Selenoxide as a Leaving Group
Barry M. Trost, and Paul H. Scudder
pp 1327 - 1327; DOI:
10.1021/ja00472a604
PDF
Additions and Corrections - On the Regioselectivity of the Catalyzed and Uncatalyzed Diels-Alder Reaction
Barry M. Trost, Joachim Ippen, and William C. Vladuchick
pp 1327 - 1327; DOI:
10.1021/ja00472a605
PDF
Book Reviews

pp 1327 - 1332; DOI:
10.1021/ja00472a606
PDF

Issue 5


Multiplicity of the ground state and magnitude of the T1-S0 gap in substituted carbenes
N. Colin Baird and Kathleen F. Taylor
pp 1333 - 1338; DOI:
10.1021/ja00473a001
PDF
Electronic states of the nickel oxide molecule
Stephen P. Walch and W. A. Goddard
pp 1338 - 1348; DOI:
10.1021/ja00473a002
PDF
Dissociation energies, electron affinities, and electronegativities of diatomic molecules. An empirical correlation with predictions for XY, XY+, and XY-
William F. Sheehan
pp 1348 - 1352; DOI:
10.1021/ja00473a003
PDF
Structure of fluoromethyl radicals. Conjugative and inductive effects
Fernando Bernardi, William Cherry, Sason Shaik, and Nicolaos D. Epiotis
pp 1352 - 1356; DOI:
10.1021/ja00473a004
PDF
Correlation between exothermicity, rate, and negative temperature dependence in slow ion-molecule reactions
M. Meot-Ner and F. H. Field
pp 1356 - 1359; DOI:
10.1021/ja00473a005
PDF
Theoretical studies of thermal rearrangements. Methylenecyclopropane and barriers to internal rotation in biradicals
D. A. Dixon, R. Foster, T. A. Halgren, and W. N. Lipscomb
pp 1359 - 1365; DOI:
10.1021/ja00473a006
PDF
Localized molecular orbitals for dinitrogen dioxide, dinitrogen trioxide, and dinitrogen tetroxide
S. Kishner, M. A. Whitehead, and M. S. Gopinathan
pp 1365 - 1371; DOI:
10.1021/ja00473a007
PDF
Ab initio calculations on large molecules using molecular fragments. Configuration interaction studies on the ground and lower excited states of N-methylcarbazole
Deni Murk, Larry E. Nitzsche, and Ralph E. Christoffersen
pp 1371 - 1378; DOI:
10.1021/ja00473a008
PDF
The vinylidene-acetylene rearrangement. A self-consistent electron pairs study of a model unimolecular reaction
Clifford E. Dykstra and Henry F. Schaefer
pp 1378 - 1382; DOI:
10.1021/ja00473a009
PDF
CNDO/2 localized molecular orbital studies on disulfur dinitride and tetrasulfur dinitride
R. R. Adkins and A. G. Turner
pp 1383 - 1387; DOI:
10.1021/ja00473a010
PDF
Molecular orbital theory of the hydrogen bond. 18. Methyl substituent effects on amide hydrogen bonding
Janet E. Del Bene
pp 1387 - 1394; DOI:
10.1021/ja00473a011
PDF
Molecular orbital theory of the hydrogen bond. 19. Amide hydrogen bonding in excited n .fwdarw. .pi.* states
Janet E. Del Bene
pp 1395 - 1398; DOI:
10.1021/ja00473a012
PDF
A theoretical study of proton addition to oxirane, aziridine, and 2-azirene
J. Catalan and M. Yanez
pp 1398 - 1401; DOI:
10.1021/ja00473a013
PDF
Sources of line width in boron-11 nuclear magnetic resonance spectra. Scalar relaxation and boron-boron coupling in tetraborane(10) and pentaborane(9)
Richard Weiss and Russell N. Grimes
pp 1401 - 1405; DOI:
10.1021/ja00473a014
PDF
Studies of solution character by molecular spectroscopy. 7. Ion sites for sodium tetracarbonylcobaltate in oxetane, 1,2-dimethoxyethane, and tetrahydrofuran from 300 to 150 K
Walter F. Edgell, Shankar Hegde, and Angelo Barbetta
pp 1406 - 1417; DOI:
10.1021/ja00473a015
PDF
Hydrogen bond cooperativity in suprabinary complexes. Vapor pressure data for the methanol-n-hexadecane-N,N-dimethyltetradecylamine system
Edwin E. Tucker and Sherril D. Christian
pp 1418 - 1426; DOI:
10.1021/ja00473a016
PDF
Poly(crown ether) catalyzed decarboxylation of 6-nitrobenzisoxazole-3-carboxylate
Shailesh C. Shah and Johannes Smid
pp 1426 - 1432; DOI:
10.1021/ja00473a017
PDF
A theory of the circular dichroism of the d-d transitions of chiral complexes
Pieter E. Schipper
pp 1433 - 1441; DOI:
10.1021/ja00473a018
PDF
Stereodynamics of enantiomerization in bis(diisopropylamino)aminoboranes
Kay K. Curry and John W. Gilje
pp 1442 - 1449; DOI:
10.1021/ja00473a019
PDF
Reaction of eaq- into excited states of tris(2,2'-bipyridine)ruthenium(2+)
Charles D. Jonah, Max S. Matheson, and Dan Meisel
pp 1449 - 1456; DOI:
10.1021/ja00473a020
PDF
Photoanation of the tris(2,2'-bipyridine)ruthenium(II) cation by thiocyanate
Patrick E. Hoggard and Gerald B. Porter
pp 1457 - 1463; DOI:
10.1021/ja00473a021
PDF
Photochemical and photophysical behavior of trans-diisothiocyanatobis(ethylenediamine)chromium(III)
D. Sandrini, M. T. Gandolfi, L. Moggi, and V. Balzani
pp 1463 - 1468; DOI:
10.1021/ja00473a022
PDF
Stereoselectivity and mechanisms of acid-catalyzed additions of acetic acid to (E)- and (Z)-2-butene in acetic acid
Daniel J. Pasto and James F. Gadberry
pp 1469 - 1473; DOI:
10.1021/ja00473a023
PDF
Mechanistic studies on the catalysis of isomerization of olefins by (Ph3P)3NiX
M. J. D'Aniello and E. Kent Barefield
pp 1474 - 1481; DOI:
10.1021/ja00473a024
PDF
Stannylation/destannylation. Preparation of .alpha.-alkoxy organolithium reagents and synthesis of dendrolasin via a carbinyl carbanion equivalent
W. Clark Still
pp 1481 - 1487; DOI:
10.1021/ja00473a025
PDF
Conformational analysis of tertiary cycloalkyl (C6, C7, C8) carbocations. Unexpected preference for the twist-boat conformation in the cyclohexyl case
Roger P. Kirchen and Ted S. Sorensen
pp 1487 - 1494; DOI:
10.1021/ja00473a026
PDF
Stable carbocations. 212. On the structure of cyclopropylcarbinyl and cyclobutyl cations. 8,9-Dehydro-2-adamantyl and 2,5-dehydro-4-protoadamantyl cations
George A. Olah, Gao Liang, Kevin A. Babiak, Thomas M. Ford, David L. Goff, Thomas K. Morgan, and Roger K. Murray
pp 1494 - 1500; DOI:
10.1021/ja00473a027
PDF
The effect of carbonyl substituents on the barriers to rotation in N,N-dimethylamides
Myra D. Wunderlich, Lilian K. Leung, James A. Sandberg, Keith D. Meyer, and Claude H. Yoder
pp 1500 - 1503; DOI:
10.1021/ja00473a028
PDF
Exo-endo vs. equatorial-axial equilibriums Assessment of steric crowding in the endo cavity
F. M. Menger, M. Perinis, J. M. Jerkunica, and L. E. Glass
pp 1503 - 1505; DOI:
10.1021/ja00473a029
PDF
Electrochemically induced aromatic nucleophilic substitution
Jean Pinson and Jean Michel Saveant
pp 1506 - 1510; DOI:
10.1021/ja00473a030
PDF
Chemical consequences of orbital interactions. 12. Stereoelectronic effects of the protonation and properties of 2-norbornyl chlorides
William L. Jorgensen and John E. Munroe
pp 1511 - 1516; DOI:
10.1021/ja00473a031
PDF
Molecular asymmetry in trans-thiacycloalkenes. 1. Interconversion of diastereomeric trans-2-methylthiacyclooct-4-enes
V. Cere, S. Pollicino, E. Sandri, and A. Fava
pp 1516 - 1520; DOI:
10.1021/ja00473a032
PDF
Preparation and chemistry of vinyl triflates. 16. Mechanism of alkylation of aromatic substrates
Peter J. Stang and Albert G. Anderson
pp 1520 - 1525; DOI:
10.1021/ja00473a033
PDF
Kinetics of halogenation of olefins and acetylenes. 5. Bromination of phenylpropiolic acid and its ethyl ester
Susan J. Ehrlich and Ernst Berliner
pp 1525 - 1533; DOI:
10.1021/ja00473a034
PDF
Two-photon spectroscopy of the visual chromophores. Evidence for a lowest excited 1Ag--like .pi..pi.* state in all-trans-retinol (vitamin A)
Robert R. Birge, James A. Bennett, Brian M. Pierce, and Terry M. Thomas
pp 1533 - 1539; DOI:
10.1021/ja00473a035
PDF
Nuclear magnetic resonance studies of catecholamines. Complex formation with adenosine 5'-triphosphate in aqueous solution. Stoichiometry and molecular conformations
Joseph Granot
pp 1539 - 1548; DOI:
10.1021/ja00473a036
PDF
Approaches to the synthesis of masked p-quinone methides. Applications to the total synthesis of (.+-.)-cherylline
David J. Hart, Paul A. Cain, and David A. Evans
pp 1548 - 1557; DOI:
10.1021/ja00473a037
PDF
A total synthesis of biotin based on the stereoselective alkylation of sulfoxides
Solange Lavielle, Sonia Bory, Bernard Moreau, M. Jacqueline Luche, and Andree Marquet
pp 1558 - 1563; DOI:
10.1021/ja00473a038
PDF
Ternary complexes in solution. 28. Enhanced stability of ternary metal ion/adenosine 5'-triphosphate complexes. Cooperative effects caused by stacking interactions in complexes containing adenosine triphosphate, phenanthroline, and magnesium, calcium, or zinc ions
Paul R. Mitchell and Helmut Sigel
pp 1564 - 1570; DOI:
10.1021/ja00473a039
PDF
Spatial configuration of the bizarre 5' terminus of mammalian mRNA
Chong H. Kim and Ramaswamy H. Sarma
pp 1571 - 1590; DOI:
10.1021/ja00473a040
PDF
Proton inventories of a serine protease charge-relay model in an aprotic solvent
John L. Hogg, Ray Morris, and Noel A. Durrant
pp 1590 - 1594; DOI:
10.1021/ja00473a041
PDF
syn-Tricyclo[4.2.1.12,5]decane. Comparison with anti-tricyclo[4.2.1.12,5]decane
Leo A. Paquette, Gerhard Klein, and Christopher W. Doecke
pp 1595 - 1596; DOI:
10.1021/ja00473a042
PDF
syn-Tricyclo[4.2.1.12,5]deca-3,7-diene, the head-to-head [4 + 4] dimer of cyclopentadiene
Christopher W. Doecke, Gerhard Klein, and Leo A. Paquette
pp 1596 - 1597; DOI:
10.1021/ja00473a043
PDF
Use of phenyl vinyl sulfoxide as an acetylene equivalent in Diels-Alder cycloadditions
Leo A. Paquette, Rudi E. Moerck, Bijan Harirchian, and Philip D. Magnus
pp 1597 - 1599; DOI:
10.1021/ja00473a044
PDF
Reversible charge control of nortriquinacenyl-tetracyclo[4.2.1.03,5.04,9]nonenyl isomerizations
Leo A. Paquette, Charles R. Degenhardt, and Howard C. Berk
pp 1599 - 1600; DOI:
10.1021/ja00473a045
PDF
Domino Diels-Alder reactions. 4. C16-Hexaquinacene
Leo A. Paquette, Robert A. Snow, Jean L. Muthard, and Tadeusz Cynkowski
pp 1600 - 1602; DOI:
10.1021/ja00473a046
PDF
Design and study of a photosensitive interface: a derivatized n-type silicon photoelectrode
Mark S. Wrighton, Richard G. Austin, Andrew B. Bocarsly, Jeffrey M. Bolts, Otto Haas, Kenneth D. Legg, Louis Nadjo, and Michael C. Palazzoto
pp 1602 - 1603; DOI:
10.1021/ja00473a047
PDF
Regarding the mechanism of carbon-hydrogen bond acidification by sulfur
Weston Thatcher Borden, Ernest R. Davidson, Niels H. Andersen, Alan D. Denniston, and Nicholaos D. Epiotis
pp 1604 - 1605; DOI:
10.1021/ja00473a048
PDF
Lewis acid catalyzed acyl migration with optically active (Z)- and (E)-1,3-diphenyl-2-buten-1-one oxide. Evidence of a concerted pathway
John M. Domagala and Robert D. Bach
pp 1605 - 1607; DOI:
10.1021/ja00473a049
PDF
The 1,3-dimethyltriazaallyl radical
F. Bernardi, M. Guerra, L. Lunazzi, G. Panciera, and G. Placucci
pp 1607 - 1608; DOI:
10.1021/ja00473a050
PDF
Synthesis and direct spectroscopic observation of a 1,1-dialkyldiazene. Infrared and electronic spectrum of N-(2,2,6,6-tetramethylpiperidyl)nitrene
William D. Hinsberg and Peter B Dervan
pp 1608 - 1610; DOI:
10.1021/ja00473a051
PDF
A structural model for type 3 copper in multicopper oxidases
Robert H. Lane, Nantelle S. Pantaleo, James K. Farr, William M. Coney, and M. Gary Newton
pp 1610 - 1611; DOI:
10.1021/ja00473a052
PDF
Gas phase basicity of silanamines
K. J. Shea, R. Gobeille, J. Bramblett, and E. Thompson
pp 1611 - 1613; DOI:
10.1021/ja00473a053
PDF
Thermal characteristics of a refolding transition. The alkaline transition of .alpha.-chymotrypsin
James D. Stoesz and Rufus W. Lumry
pp 1613 - 1614; DOI:
10.1021/ja00473a054
PDF
A virtually completely asymmetric synthesis
Ernest L. Eliel, Jorma K. Koskimies, and Bruno Lohri
pp 1614 - 1616; DOI:
10.1021/ja00473a055
PDF
Total synthesis of (.+-.)-eriolanin
Paul A. Grieco, Tomei Oguri, S. Gilman, and George T. DeTitta
pp 1616 - 1618; DOI:
10.1021/ja00473a056
PDF
A new series of minimum steric perturbation nitroxide lipid spin labels
Terry D. Lee, G. Bruce Birrell, and John F. W. Keana
pp 1618 - 1619; DOI:
10.1021/ja00473a057
PDF
Detection and measurement of the rate of 1,3-iron shift in cycloheptatrieneiron tricarbonyl
Karin J. Karel and Maurice Brookhart
pp 1619 - 1621; DOI:
10.1021/ja00473a058
PDF
Design of an ion-molecule reaction specific for neutral nitriles
Kenneth L. Busch, Willard B. Nixon, and Maurice M. Bursey
pp 1621 - 1622; DOI:
10.1021/ja00473a059
PDF
Characterization of surfactant vesicles as potential membrane models. Effect of electrolytes, substrates, and fluorescence probes
Chieu D. Tran, Patricia L. Klahn, Alejandro Romero, and Janos H. Fendler
pp 1622 - 1624; DOI:
10.1021/ja00473a060
PDF
Studies of nitrogen metabolism using carbon-13 NMR spectroscopy. 1. Streptonigrin biosynthesis
Steven J. Gould and Chiu Chin Chang
pp 1624 - 1626; DOI:
10.1021/ja00473a061
PDF
Reactions of 1,1-dimethyl-2,3-bis(trimethylsilyl)-1-silirene and hexamethylsilirane with dimethyl sulfoxide. Insertion of dimethylsilanone into the silirene and silirane rings
Dietmar Seyferth, Thomas F. O. Lim, and Don P. Duncan
pp 1626 - 1627; DOI:
10.1021/ja00473a062
PDF
Stereorational total synthesis of the marine diterpene dictyolene and its C-11 epimer
James A. Marshall and Peter G. M. Wuts
pp 1627 - 1629; DOI:
10.1021/ja00473a063
PDF
.pi.,.pi.-Biradicaloid hydrocarbons: spectral characterization of singlet and triplet 1,3-perinaphthadiyl and observation of thermal and photochemical 2,3-hydrogen shifts
Jean Francois Muller, Danielle Muller, Harry J. Dewey, and Josef Michl
pp 1629 - 1630; DOI:
10.1021/ja00473a064
PDF
Silacyclobutenes: a simple synthesis
Eric Block and Larry K. Revelle
pp 1630 - 1632; DOI:
10.1021/ja00473a065
PDF
Complete substitution of carbonyl groups in cyclopentadienyliron dicarbonyl dimer by methylaminobis(difluorophosphine). A novel bridging CH3NPF2 ligand bonded to metals through both phosphorus and nitrogen
M. G. Newton, R. B. King, M. Chang, and J. Gimeno
pp 1632 - 1634; DOI:
10.1021/ja00473a066
PDF
Reductive coupling of organometals induced by oxidation. Detection of metastable paramagnetic intermediates
T. T. Tsou and J. K. Kochi
pp 1634 - 1635; DOI:
10.1021/ja00473a067
PDF
Manifestations of sulfur to sulfur through-space interactions in complex ion spectra
C. A. Stein and Henry Taube
pp 1635 - 1637; DOI:
10.1021/ja00473a068
PDF
Preparative nucleophilic substitution with "betylates". Substrate phase transfer and substrate-reagent ion-pair reactions
J. F. King, S. M. Loosmore, J. D. Lock, and M. Aslam
pp 1637 - 1639; DOI:
10.1021/ja00473a069
PDF
Mixed phenazine-N-methylphenazinium 7,7,8,8-tetracyano-p-quinodimethanide. A quasi-one-dimensional "metal-like" system with variable band filling
Joel S. Miller and Arthur J. Epstein
pp 1639 - 1641; DOI:
10.1021/ja00473a070
PDF
Book Reviews

pp 1641 - 1646; DOI:
10.1021/ja00473a600
PDF

Issue 6


Ab initio SCF computations on toluene and the toluenium ion using a large contracted Gaussian basis set
Walter C. Ermler and Robert S. Mulliken
pp 1647 - 1653; DOI:
10.1021/ja00474a001
PDF
A theoretical study concerning mechanisms of the molecular rearrangement of carbonyl compounds to oxacarbenes in the lowest triplet state
Julianna A. Altmann, I. G. Csizmadia, Michael A. Robb, Keith Yates, and Peter Yates
pp 1653 - 1657; DOI:
10.1021/ja00474a002
PDF
Ab initio molecular orbital calculations on the water-carbon dioxide system. The reaction hydroxide(1-) ion + carbon dioxide .fwdarw. bicarbonate(1-) ion
B. Jonsson, G. Karlstrom, and H. Wennerstrom
pp 1658 - 1661; DOI:
10.1021/ja00474a003
PDF
Relative stability of planar and perpendicular olefins
Shigeru Nagase and Keiji Morokuma
pp 1661 - 1666; DOI:
10.1021/ja00474a004
PDF
An ab initio molecular orbital study of organic reactions. The energy, charge, and spin decomposition analyses at the transition state and along the reaction pathway
Shigeru Nagase and Keiji Morokuma
pp 1666 - 1672; DOI:
10.1021/ja00474a005
PDF
A molecular orbital study of protonation. 3. Equilibrium structures and energies of ions RCHOH+
Janet E. Del Bene
pp 1673 - 1679; DOI:
10.1021/ja00474a006
PDF
The effect of micellar phase on the state and dynamics of some excited state charge transfer complexes
B. Katusin-Razem, M. Wong, and J. K. Thomas
pp 1679 - 1686; DOI:
10.1021/ja00474a007
PDF
Transition metal alkyl chemistry at elevated carbon monoxide pressures. An infrared spectroscopic study of systems related to catalytic intermediates in homogeneous hydroformylation reactions
R. B. King, A. D. King, M. Z. Iqbal, and C. C. Frazier
pp 1687 - 1694; DOI:
10.1021/ja00474a008
PDF
Large metal ion-centered template reactions. Chemical and spectral studies of the "superphthalocyanine" dioxocyclopentakis(1-iminoisoindolinato)uranium(VI) and its derivatives
Tobin J. Marks and Djordje R. Stojakovic
pp 1695 - 1705; DOI:
10.1021/ja00474a009
PDF
Nitric oxide reactivity with manganese complexes containing linear pentadentate ligands
W. M. Coleman and L. T. Taylor
pp 1705 - 1710; DOI:
10.1021/ja00474a010
PDF
Moessbauer-Zeeman spectra of some octaethylporphyrinato- and tetraphenylporphinatoiron(III) complexes
David H. Dolphin, John R. Sams, Tsang Bik Tsin, and Kit L. Wong
pp 1711 - 1718; DOI:
10.1021/ja00474a011
PDF
The effect of energy gaps on multiple emissions in heterotrischelated rhodium(III) complexes
Richard J. Watts and J. Van Houten
pp 1718 - 1721; DOI:
10.1021/ja00474a012
PDF
Reaction of bis(trifluoromethyl)mercury with group 4A tetrahalides. Preparation and stabilities of (trifluoromethyl)germanium and (trifluoromethyl)tin compounds
R. J. Lagow, R. Eujen, L. L. Gerchman, and J. A. Morrison
pp 1722 - 1726; DOI:
10.1021/ja00474a013
PDF
The molybdenum-molybdenum triple bond. 4. Insertion reactions of hexakis(alkoxy)dimolybdenum compounds with carbon dioxide and single-crystal x-ray structural characterization of bis(tert-butylcarbonato)tetrakis(tert-butoxy)dimolybdenum
Malcolm H. Chisholm, F. Albert Cotton, Michael W. Extine, and William W. Reichert
pp 1727 - 1734; DOI:
10.1021/ja00474a014
PDF
Stereochemical systematics of metal clusters. Structural characterization of a genuine one-electron metal-metal bonded cobalt dimer bis[(.eta.5-cyclopentadienyl)diphenylphosphidocobalt](1+) and related compounds by extended x-ray absorption fine structure spectroscopy
Boon-Keng Teo, P. Eisenberger, and B. M. Kincaid
pp 1735 - 1744; DOI:
10.1021/ja00474a015
PDF
Activation of epoxides as electrophiles by transition metal ions in dilute aqueous solution
Robert P. Hanzlik and Arlene Hamburg
pp 1745 - 1749; DOI:
10.1021/ja00474a016
PDF
Synthesis and reactivity of zerovalent platinum complexes of short-lived cyclic alkynes. Formation of monomeric platinum(II) hydroxo-, methoxo-, and .sigma.-carbon-bonded complexes by oxidative addition reactions with water, methanol, and activated hydrocarbons and catalysis of nitrile to amide hydration
Martin A. Bennett and Toshikatsu Yoshida
pp 1750 - 1759; DOI:
10.1021/ja00474a017
PDF
Carbon-carbon bond formation promoted by transition metal carbonyls. 16. Reaction of .alpha.,.alpha.'-dibromo ketones and iron carbonyls. Mechanistic aspects
R. Noyori, Y. Hayakawa, H. Takaya, S. Murai, R. Kobayashi, and N. Sonoda
pp 1759 - 1765; DOI:
10.1021/ja00474a018
PDF
Carbon-carbon bond formation promoted by transition metal carbonyls. 17. Reactions of polybromo ketones with 1,3-dienes in the presence of iron carbonyls. New 3 + 4 .fwdarw. 7 cyclocoupling reaction forming 4-cycloheptenones
H. Takaya, S. Makino, Y. Hayakawa, and R. Noyori
pp 1765 - 1777; DOI:
10.1021/ja00474a019
PDF
Carbon-carbon bond formation promoted by transition metal carbonyls. 18. New synthesis of troponoid compounds via the iron carbonyl promoted cyclocoupling between polybromo ketones and 1,3-dienes
H. Takaya, Y. Hayakawa, S. Makino, and R. Noyori
pp 1778 - 1785; DOI:
10.1021/ja00474a020
PDF
Carbon-carbon bond formation promoted by transition metal carbonyls. 19. General synthesis of tropane alkaloids via the polybromo ketone-iron carbonyl reaction
Y. Hayakawa, Y. Baba, S. Makino, and R. Noyori
pp 1786 - 1791; DOI:
10.1021/ja00474a021
PDF
Carbon-carbon bond formation promoted by transition metal carbonyls. 20. Iron carbonyl promoted reaction of .alpha.,.alpha.'-dibromo ketones and aromatic olefins leading to 3-arylcyclopentanones. The [3 + 2] cycloaddition involving an allylic cation
Y. Hayakawa, K. Yokoyama, and R. Noyori
pp 1791 - 1799; DOI:
10.1021/ja00474a022
PDF
Novel cyclopentenone synthesis via the iron carbonyl aided cyclocoupling between .alpha.,.alpha.'-dibromo ketones and enamines
Y. Hayakawa, K. Yokoyama, and R. Noyori
pp 1799 - 1806; DOI:
10.1021/ja00474a023
PDF
Synthesis, properties, and reactions of dispiro[2.2.2.2]deca-4,9-diene
Takashi Tsuji, Tohru Shibata, Yutaka Hienuki, and Shinya Nishida
pp 1806 - 1814; DOI:
10.1021/ja00474a024
PDF
A pulse radiolysis study of the quenching of aromatic carbonyl triplets by norbornadienes and quadricyclenes. The mechanism of interconversion
A. J. G. Barwise, A. A. Gorman, R. L. Leyland, P. G. Smith, and M. A. J. Rodgers
pp 1814 - 1820; DOI:
10.1021/ja00474a025
PDF
Base-catalyzed oxygenation of tert-butylated phenols. 1. Regioselectivity in the base-catalyzed oxygenation of tert-butylphenols
Akira Nishinaga, Toshio Itahara, Tadashi Shimizu, and Teruo Matsuura
pp 1820 - 1825; DOI:
10.1021/ja00474a026
PDF
Base-catalyzed oxygenation of tert-butylated phenols. 2. Formation of 3-aryl-2,5-di-tert-butyl-2,4-cyclopentadienones by base-catalyzed oxygenation of 4-aryl-2,6-di-tert-butylphenols: x-ray structure determination of 2,5-di-tert-butyl-3-(4-chlorophenyl)cyclopentadienone
Akira Nishinaga, Toshio Itahara, Teruo Matsuura, Anton Rieker, Dieter Koch, Klaus Albert, and Peter B. Hitchcock
pp 1826 - 1834; DOI:
10.1021/ja00474a027
PDF
Intrinsic acidities of carbon acids. Sulfones and sulfoxides
J. B. Cumming and P. Kebarle
pp 1835 - 1838; DOI:
10.1021/ja00474a028
PDF
Strong acid chemistry. 5. Reactions of cycloalkanes in hydrogen fluoride-tantalum pentafluoride with hydrogen
M. Siskin
pp 1838 - 1841; DOI:
10.1021/ja00474a029
PDF
Strong acid chemistry. 6. Direct reduction of benzyl chlorides in strong acids
M. Siskin and R. H. Schlosberg
pp 1842 - 1843; DOI:
10.1021/ja00474a030
PDF
Kinetics and mechanism of amide acetal hydrolysis. Carbon-oxygen vs. carbon-nitrogen bond cleavage in acid solutions
Robert A. McClelland
pp 1844 - 1849; DOI:
10.1021/ja00474a031
PDF
Association phenomena. 2. Catalysis of the decomposition of acetyl phosphate by chelate micelles and by amine-ammonium micelles
L. Lee Melhado and C. David Gutsche
pp 1850 - 1856; DOI:
10.1021/ja00474a032
PDF
Association phenomena. 3. Polyfunctional catalysis of acetyl phosphate decomposition
Hon-Peng Lau and C. David Gutsche
pp 1857 - 1865; DOI:
10.1021/ja00474a033
PDF
Chemical effects of steric strains. 22. Rates of solvolysis of dimethyl(2-norbornyl)carbinyl p-nitrobenzoates and of the quaternization of 2-dimethylaminonorbornanes. A critical examination of the significance of steric factors in the chemistry of exo- and endo-norbornyl derivatives
Herbert C. Brown and M. Ravindranathan
pp 1865 - 1869; DOI:
10.1021/ja00474a034
PDF
.sigma. Ground state of the benzoyloxy radical
Moon B. Yim, Osamu Kikuchi, and David E. Wood
pp 1869 - 1872; DOI:
10.1021/ja00474a035
PDF
Pull-push mechanism for the 1,2-hydrogen rearrangement of carbenes. Substituent and deuterium isotope effects for thermal decomposition of 1-phenyl-2-diazopropanes
Dean T. T. Su and Edward R. Thornton
pp 1872 - 1875; DOI:
10.1021/ja00474a036
PDF
Extrusion of nitrogen from cyclic and bicyclic azo compounds
Paul S. Engel, Richard A. Hayes, Leonard Keifer, Sandor Szilagyi, and J. W. Timberlake
pp 1876 - 1882; DOI:
10.1021/ja00474a037
PDF
Synthesis and stereochemistry of chrysomelidial and plagiolactone
Jerrold Meinwald and Tappey H. Jones
pp 1883 - 1886; DOI:
10.1021/ja00474a038
PDF
Synthesis of mercury mercaptide azetidinones via 2- and 4-methylthio-substituted cephalosporins
W. A. Slusarchyk, H. E. Applegate, C. M. Cimarusti, J. E. Dolfini, P. Funke, and M. Puar
pp 1886 - 1891; DOI:
10.1021/ja00474a039
PDF
Kinetics of epimerization of 15(R)-methylprostaglandin E2 and of 15(S)-methylprostaglandin E2 as a function of pH and temperature in aqueous solution
Margaret V. Merritt and George E. Bronson
pp 1891 - 1895; DOI:
10.1021/ja00474a040
PDF
Biosynthetic conversion of thebaine to codeinone. Mechanism of ketone formation from enol ether in vivo
Jerold S. Horn, Ara G. Paul, and Henry Rapoport
pp 1895 - 1898; DOI:
10.1021/ja00474a041
PDF
Trivalent copper, superoxide, and galactose oxidase
Gordon A. Hamilton, Paul K. Adolf, John De Jersey, Garrett C. DuBois, Gary R. Dyrkacz, and R. Daniel Libby
pp 1899 - 1912; DOI:
10.1021/ja00474a042
PDF
Conformations of polypeptide hormones by optically detected magnetic resonance and a Zimm-Bragg analysis of helical folding in glucagon
David A. Deranleau, J. B. Alexander Ross, Kenneth W. Rousslang, and Alvin L. Kwiram
pp 1913 - 1917; DOI:
10.1021/ja00474a043
PDF
Optical and paramagnetic identification of a primary electron acceptor in bacterial photosynthesis
J. Fajer, M. S. Davis, D. C. Brune, A. Forman, and J. P. Thornber
pp 1918 - 1920; DOI:
10.1021/ja00474a044
PDF
Products of reaction of superoxide and hydroxyl radicals with manganese(2+) cation
Benon H. J. Bielski and Phillip C. Chan
pp 1920 - 1921; DOI:
10.1021/ja00474a045
PDF
Novel bonding mode of diphenylketene to a transition metal: a metal anchored olefin system
Giuseppe Fachinetti, Claude Biran, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 1921 - 1922; DOI:
10.1021/ja00474a046
PDF
Stereoselective coupling reaction of thioamides via a dithia-Cope rearrangement
Yoshinao Tamaru, Toshira Harada, and Zenichi Yoshida
pp 1923 - 1925; DOI:
10.1021/ja00474a047
PDF
Conformational study of eight-membered-ring organophosphorus heterocycles
J. P. Dutasta and J. B. Robert
pp 1925 - 1927; DOI:
10.1021/ja00474a048
PDF
A highly stereoselective synthesis of Z-trisubstituted olefins via [2,3]-sigmatropic rearrangement. Preference for a pseudoaxially substituted transition state
W. Clark Still and Abhijit Mitra
pp 1927 - 1928; DOI:
10.1021/ja00474a049
PDF
Concerning CH2:C-.cntdot.and its reaction with 14N15NO
J. H. J. Dawson and N. M. M. Nibbering
pp 1928 - 1929; DOI:
10.1021/ja00474a050
PDF
Solid-state high resolution NMR spectroscopy of spin 1/2 nuclei (carbon-13, silicon-29, tin-119) in organic compounds
Endel T. Lippmaa, Madis A. Alla, Tonis J. Pehk, and Guenter Engelhardt
pp 1929 - 1931; DOI:
10.1021/ja00474a051
PDF
A unique two-electron, reversible reduction of a binuclear copper(II) complex. Observation of the electrochemical behavior predicted by Polcyn and Shain for the sequential transfer of two electrons at the same potential
D. Earl Fenton, R. R. Schroeder, and R. L. Lintvedt
pp 1931 - 1932; DOI:
10.1021/ja00474a052
PDF
Tetrahedral mercaptide complexes. Crystal and molecular structures of [(C6H5)4P]2M(SC6H5)4 complexes (M = cadmium(II), zinc(II), nickel(II), cobalt(II), and manganese(II))
D. Swenson, N. C. Baenziger, and D. Coucouvanis
pp 1932 - 1934; DOI:
10.1021/ja00474a053
PDF
Nitroxide spin labels as surface and structural probes for wood and cellulose and its derivatives
Laurance D. Hall and J. D. Aplin
pp 1934 - 1936; DOI:
10.1021/ja00474a054
PDF
Molecular orbitals from group orbitals. 5. Role of steric effects in the perturbational molecular orbital method of conformational analysis
Saul Wolfe, David J. Mitchell, and Myung-Hwan Whangbo
pp 1936 - 1938; DOI:
10.1021/ja00474a055
PDF
Total synthesis of (.+-.)-vernolepin
G. R. Kieczykowski and R. H. Schlessinger
pp 1938 - 1940; DOI:
10.1021/ja00474a056
PDF
Synthesis of sesquiterpene antitumor lactones. 2. A new stereocontrolled total synthesis of (.+-.)-vernolepin
Minoru Isobe, Hideo Iio, Tatsuhiko Kawai, and Toshio Goto
pp 1940 - 1942; DOI:
10.1021/ja00474a057
PDF
Total synthesis of (S)-12-hydroxy-5,8,14-cis,-10-trans-eicosatetraenoic acid (Samuelsson's HETE)
E. J. Corey, Haruki Niwa, and Jochen Knolle
pp 1942 - 1943; DOI:
10.1021/ja00474a058
PDF
Crown ether model systems for the study of photoexcited-state response to oriented perturbers. How does a naphthalene derivative respond to an alkali metal cation in its .pi. face?
James M. Larson and Lynn R. Sousa
pp 1943 - 1944; DOI:
10.1021/ja00474a059
PDF
Structural diversity in iron porphyrins: solution characterization of a high-spin six-coordinate ferric complex
Markus Zobrist and Gerd N. La Mar
pp 1944 - 1946; DOI:
10.1021/ja00474a060
PDF
Novel temperature-dependent photochemical rearrangement of citral
Francis Barany, Steven Wolff, and William C. Agosta
pp 1946 - 1948; DOI:
10.1021/ja00474a061
PDF
Simultaneous fluorination and functionalization of hydrocarbon polymers
J. L. Adcock, Shoji Inoue, and R. J. Lagow
pp 1948 - 1950; DOI:
10.1021/ja00474a062
PDF
Addition reactions of imidyl radicals with olefins and arenes
J. C. Day, M. G. Katsaros, W. D. Kocher, A. E. Scott, and P. S. Skell
pp 1950 - 1951; DOI:
10.1021/ja00474a063
PDF
Excited-state succinimidyl radical in thermal chain reactions
P. S. Skell and J. C. Day
pp 1951 - 1953; DOI:
10.1021/ja00474a064
PDF
Entropy changes for the protonation of alkenes
Pierre Ausloos and Sharon G. Lias
pp 1953 - 1954; DOI:
10.1021/ja00474a065
PDF
N-Cycloheptatrienylidenemethylamine oxide: synthesis, electronic spectra, and cycloadditions of a fulvenoid dipole
Debabrata Mukherjee, L. N. Domelsmith, and K. N. Houk
pp 1954 - 1957; DOI:
10.1021/ja00474a066
PDF
Preparation and properties of the actinide borohydrides: protactinium(IV), neptunium(IV), and plutonium(IV) borohydrides
R. H. Banks, N. M. Edelstein, R. R. Rietz, David H. Templeton, and Allan Zalkin
pp 1957 - 1958; DOI:
10.1021/ja00474a067
PDF
Synthesis, structure, and spectral properties of tetrathiafulvalene trichloromercurate(II), an unusual metallotetrathiaethylene
T. J. Kistenmacher, M. Rossi, C. C. Chiang, R. P. Van Duyne, T. Cape, and Allen R. Siedle
pp 1958 - 1959; DOI:
10.1021/ja00474a068
PDF
Powerful anchimeric effect of the N-nitroso group
C. J. Michejda and S. R. Koepke
pp 1959 - 1960; DOI:
10.1021/ja00474a069
PDF
Bis(chlorophyll)cyclophanes. New models of special pair chlorophyll
Michael R. Wasielewski, Walter A. Svec, and Benjamin T. Cope
pp 1961 - 1962; DOI:
10.1021/ja00474a070
PDF
Thermolysis of 2-acetoxy-.DELTA.3-1,3,4-oxadiazolines. Evidence for stepwise homolysis of cyclic diazenes
Dominic W. K. Yeung, Gerald A. MacAlpine, and John Warkentin
pp 1962 - 1964; DOI:
10.1021/ja00474a071
PDF
Electron spin resonance of methoxy radicals trapped in methanol x-irradiated at 4.2 K
Machio Iwasaki and Kazumi Toriyama
pp 1964 - 1965; DOI:
10.1021/ja00474a072
PDF
Magnesium-25 hyperfine coupling in the bacteriochlorophyll radical cation
M. C. Thurnauer, M. K. Bowman, B. T. Cope, and J. R. Norris
pp 1965 - 1966; DOI:
10.1021/ja00474a073
PDF
Dioxetanone chemiluminescence by the chemically initiated electron exchange pathway. Efficient generation of excited singlet states
Steven P. Schmidt and Gary B. Schuster
pp 1966 - 1968; DOI:
10.1021/ja00474a074
PDF
Molecular recognition of DNA by small molecules. Synthesis of bis(methidium)spermine, a DNA polyintercalating molecule
Peter B. Dervan and Michael M. Becker
pp 1968 - 1970; DOI:
10.1021/ja00474a075
PDF
Influence of alkyl substitution on the trans .fwdarw. cis photoisomerization of all-trans-retinal and related polyenes
Walter H. Waddell, Daniel L. Hopkins, Motokazu Uemura, and John L. West
pp 1970 - 1972; DOI:
10.1021/ja00474a076
PDF
Polarized single-crystal spectroscopic studies of oxyhemerythrin
Robert R. Gay and Edward I. Solomon
pp 1972 - 1973; DOI:
10.1021/ja00474a077
PDF
A direct technique for obtaining electron-impact mass spectra of polar, involatile compounds. Application to underivatized disaccharides
William R. Anderson, Willi Frick, and G. Doyle Daves
pp 1974 - 1975; DOI:
10.1021/ja00474a078
PDF
Book Reviews

pp 1975 - 1978; DOI:
10.1021/ja00474a600
PDF

Issue 7


Molecular orbital model studies of the effect of strain on hyperconjugation in carbonium ions
Andrew Streitwieser and Spiro Alexandratos
pp 1979 - 1984; DOI:
10.1021/ja00475a001
PDF
A theoretical relation for the position of the energy barrier between initial and final states of chemical reactions
Arnold R. Miller
pp 1984 - 1992; DOI:
10.1021/ja00475a002
PDF
Reactive complex theory of photochemical reactions. A nonequilibrium approach to chemical rate processes in condensed media
Dennis J. Diestler and Francis K. Fong
pp 1992 - 1996; DOI:
10.1021/ja00475a003
PDF
Strengths of A-A single bonds in symmetric A2B2n molecules and ions
Benjamin M. Gimarc, Shakil A. Khan, and Michael C. Kohn
pp 1996 - 2003; DOI:
10.1021/ja00475a004
PDF
Quantum mechanical studies of the .alpha. effect
M. M. Heaton
pp 2004 - 2008; DOI:
10.1021/ja00475a005
PDF
Avoided crossings in excited states potential energy surfaces
A. Devaquet, A. Sevin, and B. Bigot
pp 2009 - 2011; DOI:
10.1021/ja00475a006
PDF
Expansion of molecular orbital wave functions into valence bond wave functions. A simplified procedure
P. C. Hiberty and C. Leforestier
pp 2012 - 2017; DOI:
10.1021/ja00475a007
PDF
Molecular orbital studies of organic substituent effects. Transmission of charge and energy perturbations through rigid bicyclic skeletons in a model SN2 reaction
Robert B. Davidson and C. Richard Williams
pp 2017 - 2021; DOI:
10.1021/ja00475a008
PDF
Bonding in acyclic hydrocarbons. An FSGO analysis and computational procedure
John J. Woods and Gary Simons
pp 2021 - 2029; DOI:
10.1021/ja00475a009
PDF
Substituent effects on spin delocalization in triplet phenylnitrenes. 1. Para-substituted phenylnitrenes
J. Herbert Hall, James M. Fargher, and Matthias R. Gisler
pp 2029 - 2034; DOI:
10.1021/ja00475a010
PDF
Theoretical elucidation of Faraday B terms in the magnetic circular dichroism of monosubstituted benzenes. Use of the CNDO/S-CI approximation
Akira Kaito and Masahiro Hatano
pp 2034 - 2040; DOI:
10.1021/ja00475a011
PDF
Excitation functions of slow proton transfer reactions involving negative ions
C. Lifshitz, R. L. C. Wu, and T. O. Tiernan
pp 2040 - 2048; DOI:
10.1021/ja00475a012
PDF
Crystal structure of .eta.5-pentamethylcyclopentadienyltriphenylphosphineethylenerhodium(I). A case of important .pi. component in a metal-olefin bond
W. Porzio and M. Zocchi
pp 2048 - 2052; DOI:
10.1021/ja00475a013
PDF
Molecular structure and magnetic properties of .mu.-dihydroxo-bis[4-dimethylamino-2,6-pyridinedicarboxylatoaquoiron(III)]dihydrate, [(CH3)2NC7H2NO4(H2O)FeOH]2.2H2O
Chia-Chih Ou, Roger A. Lalancette, Joseph A. Potenza, and Harvey J. Schugar
pp 2053 - 2057; DOI:
10.1021/ja00475a014
PDF
Crystal and molecular structure of the tetrameric cadmium(II) complex (Cd[SC(CH3)2CH2NH2]2CdCl2)2.2H2O
Timothy G. Fawcett, Chia-Chih Ou, Joseph A. Potenza, and Harvey J. Schugar
pp 2058 - 2062; DOI:
10.1021/ja00475a015
PDF
Cis dihydride diphosphine complexes of platium(II) and their dehydrogenation to form dimeric platinum(0) complexes. The structure of [Pt(tert-Bu)2P(CH2)3P(tert-Bu)2]2
T. Yoshida, T. Yamagata, T. H. Tulip, James A. Ibers, and Sei Otsuka
pp 2063 - 2073; DOI:
10.1021/ja00475a016
PDF
Platinum(0)-platinum(0) dimers. Bonding relationships in a d10-d10 system
Alain Dedieu and Roald Hoffmann
pp 2074 - 2079; DOI:
10.1021/ja00475a017
PDF
The olefin insertion reaction
David L. Thorn and Roald Hoffmann
pp 2079 - 2090; DOI:
10.1021/ja00475a018
PDF
Metal clusters in catalysis. 14. The chemistry of dinuclear metal-acetylene complexes
E. L. Muetterties, W. R. Pretzer, M. G. Thomas, B. F. Beier, D. L. Thorn, V. W. Day, and A. B. Anderson
pp 2090 - 2096; DOI:
10.1021/ja00475a019
PDF
Thermal and light-induced electron transfer between iron(II) and cobalt(III) mediated by bridging pyrazines
John M. Malin, Debra A. Ryan, and Thomas V. O'Halloran
pp 2097 - 2102; DOI:
10.1021/ja00475a020
PDF
Matrix photoionization studies of trifluoromethyl halide systems. Infrared spectra of the CF3+, CF2X+, and CF3X+ cations in solid argon
Frank T. Prochaska and Lester Andrews
pp 2102 - 2108; DOI:
10.1021/ja00475a021
PDF
Electron spin resonance studies of the reaction of lithium atoms with Lewis bases in argon matrices: formation of reactive intermediates. 1. Water and ammonia
Paul F. Meier, Robert H. Hauge, and John L. Margrave
pp 2108 - 2112; DOI:
10.1021/ja00475a022
PDF
Hydrogen evolving systems. 3. Further observations on the reduction of molecular nitrogen and of other substrates in the vanadium(II) hydroxide-magnesium hydroxide system
Stacey I. Zones, Miles R. Palmer, John G. Palmer, John M. Doemeny, and Gerhard N. Schrauzer
pp 2113 - 2121; DOI:
10.1021/ja00475a023
PDF
Molecules with T symmetry. Conformational analysis of systems of type M[C(CH3)3]4 and M[Si(CH3)3]4 by the empirical force field method
Linda D. Iroff and Kurt Mislow
pp 2121 - 2126; DOI:
10.1021/ja00475a024
PDF
Reactions of potassium-graphite
David E. Bergbreiter and James M. Killough
pp 2126 - 2134; DOI:
10.1021/ja00475a025
PDF
Reversible Grignard and organolithium reactions
Robert A. Benkeser, Michael P. Siklosi, and Edward C. Mozdzen
pp 2134 - 2139; DOI:
10.1021/ja00475a026
PDF
Heteroatom directed photoarylation. Synthetic potential of the heteroatom sulfur
Arthur G. Schultz, Wallace Y. Fu, Robert D. Lucci, B. Gail Kurr, Kin Ming Lo, and Matthew Boxer
pp 2140 - 2149; DOI:
10.1021/ja00475a027
PDF
Heteroatom directed photoarylation. Synthetic potential of the heteroatom oxygen
Arthur G. Schultz, Robert D. Lucci, Wallace Y. Fu, Mitchell H. Berger, Jeanette Erhardt, and William K. Hagmann
pp 2150 - 2162; DOI:
10.1021/ja00475a028
PDF
Organic photochemistry in the solid state. The distance and geometric requirements for intramolecular hydrogen abstraction reactions. Structure-reactivity relationships based on x-ray crystallographic data
John R. Scheffer and Alice A. Dzakpasu
pp 2163 - 2173; DOI:
10.1021/ja00475a029
PDF
Synthesis and crystal structure of 2,3,4,5,6,7,8,9-octahydro-2,2,5,5,8,8-hexamethyl-1H-benzo[1,2-c:3,4-c':5,6-c"]tripyrrolium tribromide dihydrate, C18H30N33+.cntdot.3Br-.2H2O
Julius Ciric, Stephen L. Lawton, George T. Kokotailo, and Gary W. Griffin
pp 2173 - 2175; DOI:
10.1021/ja00475a030
PDF
Geometry of norbornane. X-ray crystal structure of exo-N-(2-norbornyl)benzamide
M. Gary Newton, Nantelle S. Pantaleo, S. Kirbawy, and Norman L. Allinger
pp 2176 - 2180; DOI:
10.1021/ja00475a031
PDF
Photochemical transformations of small ring heterocyclic compounds. 93. Spatial requirements associated with the intramolecular 1,1-cycloaddition reactions of nitrile ylides
Albert Padwa and Audrey Ku
pp 2181 - 2190; DOI:
10.1021/ja00475a032
PDF
Carboxylic acid participation in amide hydrolysis. External general base catalysis and general acid catalysis in reactions of norbornenylanilic acids
Ronald Kluger and C. H. Lam
pp 2191 - 2197; DOI:
10.1021/ja00475a033
PDF
Ozonolysis of trans-di-tert-butylethylene. Mechanistic considerations
V. Ramachandran and R. W. Murray
pp 2197 - 2201; DOI:
10.1021/ja00475a034
PDF
Calorimetric determination of the conformational enthalpy and entropy of 2-phenyl-1,3-dioxane. Effectively free rotation of an equatorial 2-phenyl group. Conformational equilibriums in 2,2-disubstituted 1,3-dioxanes
William F. Bailey, Helen Connon, Ernest L. Eliel, and Kenneth B. Wiberg
pp 2202 - 2209; DOI:
10.1021/ja00475a035
PDF
Solvent participation in reactions. 2. Reactions of the cystamine anion radical
O. I. Micic, M. T. Nenadovic, and P. A. Carapellucci
pp 2209 - 2212; DOI:
10.1021/ja00475a036
PDF
Conformational studies of tentoxin by nuclear magnetic resonance spectroscopy. Evidence for a new conformation for a cyclic tetrapeptide
Daniel H. Rich and Pradip K. Bhatnagar
pp 2212 - 2218; DOI:
10.1021/ja00475a037
PDF
Isolation and conformational analysis of two conformers of D-methylalanine1-tentoxin
Daniel H. Rich and Pradip K. Bhatnagar
pp 2218 - 2224; DOI:
10.1021/ja00475a038
PDF
Biradical trapping: the formation of bicyclic peroxides via the thermal and photodecomposition of azo compounds in the presence of oxygen
R. Marshall Wilson and Fiona Geiser
pp 2225 - 2226; DOI:
10.1021/ja00475a039
PDF
Lanthanides in organic chemistry. 1. Selective 1,2 reductions of conjugated ketones
Jean Louis Luche
pp 2226 - 2227; DOI:
10.1021/ja00475a040
PDF
Equilibrium geometry of trimethylenemethane and the absence of an adjacent secondary minimum on the triplet potential energy surface
Diane M. Hood, Russell M. Pitzer, and Henry F. Schaefer
pp 2227 - 2228; DOI:
10.1021/ja00475a041
PDF
A simple method for obtaining x-ray photoelectron spectra of species in liquid solution
Steven C. Avanzino and William L. Jolly
pp 2228 - 2230; DOI:
10.1021/ja00475a042
PDF
Interaction of the dicoordinate phosphorus cation 1,3-dimethyl-1,3,2-diazaphospholidide with transition metal nucleophiles
R. W. Light and R. T. Paine
pp 2230 - 2231; DOI:
10.1021/ja00475a043
PDF
Iron carbonyl complexes containing positively charged phosphorus ligands
R. G. Montemayor, Dennis T. Sauer, Suzanne Fleming, Dennis W. Bennett, Michael G. Thomas, and Robert W. Parry
pp 2231 - 2233; DOI:
10.1021/ja00475a044
PDF
A donor-acceptor structure for the acetyl chloride-aluminum chloride complex in methylene chloride from aluminum-27 nuclear magnetic resonance
John Wilinski and R. J. Kurland
pp 2233 - 2234; DOI:
10.1021/ja00475a045
PDF
Ultrafast excited-state proton transfer in reversed micelles
Jose R. Escabi-Perez and Janos H. Fendler
pp 2234 - 2236; DOI:
10.1021/ja00475a046
PDF
Steric effect on fluorescence quenching of 1,1'-binaphthyl by chiral amines
Masahiro Irie, Takehiko Yorozu, and Koichiro Hayashi
pp 2236 - 2237; DOI:
10.1021/ja00475a047
PDF
Trisection of reaction pathways in automerization of 6-methylenebicyclo[3.2.1]oct-2-ene
John M. Janusz and Jerome A. Berson
pp 2237 - 2239; DOI:
10.1021/ja00475a048
PDF
Heterogeneous photocatalytic synthesis of methane from acetic acid - new Kolbe reaction pathway
Bernhard Kraeutler and Allen J. Bard
pp 2239 - 2240; DOI:
10.1021/ja00475a049
PDF
Helium(I) photoelectron spectrum of tropyl radical
T. Koenig and J. C. Chang
pp 2240 - 2242; DOI:
10.1021/ja00475a050
PDF
A general approach to the synthesis of 1,6-dicarbonyl substrates. New applications of base-accelerated oxy-Cope rearrangements
David A. Evans, David J. Baillargeon, and John V. Nelson
pp 2242 - 2244; DOI:
10.1021/ja00475a051
PDF
Nickel-catalyzed conjugate addition of organoaluminum acetylides to .alpha.,.beta.-enones
Robert T. Hansen, Denise B. Carr, and Jeffrey Schwartz
pp 2244 - 2245; DOI:
10.1021/ja00475a052
PDF
Cyanoketenes. Mechanism of cycloaddition of chlorocyanoketene to imidates
Harold W. Moore, Louis Hernandez, and Richard Chambers
pp 2245 - 2247; DOI:
10.1021/ja00475a053
PDF
Preparation of dicarbonyl(.eta.5-cyclopentadienyl)thionitrosylchromium(I). The first organometallic thionitrosyl complex
Brian W. S. Kolthammer and Peter Legzdins
pp 2247 - 2248; DOI:
10.1021/ja00475a054
PDF
An intramolecular model of 1,3-dipolar cycloaddition to the 5,6 double bond of a pyrimidine nucleoside. A new route to the regiospecific synthesis of 4-substituted triazole reversed nucleosides
Tadashi Sasaki, Katsumaro Minamoto, Toshimichi Suzuki, and Toyoyuki Sugiura
pp 2248 - 2250; DOI:
10.1021/ja00475a055
PDF
Abstraction of NH from HN3 by MoO[S2P(OC2H5)2]2. Structure of Mo2O3(NH)[S2P(OC2H5)2]2.THF
A. W. Edelblut, Barry L. Haymore, and R. A. D. Wentworth
pp 2250 - 2251; DOI:
10.1021/ja00475a056
PDF
Structure and absolute configuration of tris(N-methylthioformohydroxamato)iron(III), an antibacterial metal chelate and potential iron siderochrome
Keith S. Murray, Peter J. Newman, and Donald Taylor
pp 2251 - 2252; DOI:
10.1021/ja00475a057
PDF
Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins
David E. Van Horn and Eiichi Negishi
pp 2252 - 2254; DOI:
10.1021/ja00475a058
PDF
Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins
Eiichi Negishi, Nobuhisa Okukado, Anthony O. King, David E. Van Horn, and Barry I. Spiegel
pp 2254 - 2256; DOI:
10.1021/ja00475a059
PDF
Reactions of triply bonded dimetal compounds. Reversible addition of carbon monoxide to a hexakis(alkoxy)dimolybdenum compound. A molecule with a carbonyl-bridged metal-metal double bond
Malcolm H. Chisholm, Raymond L. Kelly, F. Albert Cotton, and Michael W. Extine
pp 2256 - 2257; DOI:
10.1021/ja00475a060
PDF
Simultaneous multiple emissions from fac-XRe(CO)3(3-benzoylpyridine)2:n-.pi.* intraligand and charge-transfer emission at low temperature
Paul J. Giordano, Susan M. Fredericks, Mark S. Wrighton, and David L. Morse
pp 2257 - 2259; DOI:
10.1021/ja00475a061
PDF
Importance of apolar binding in complex formation of cyclodextrins with adamantanecarboxylate
Makoto Komiyama and Myron L. Bender
pp 2259 - 2260; DOI:
10.1021/ja00475a062
PDF
Synthesis of pentaammineruthenium-histidine complexes in ribonuclease A
C. R. Matthews, P. M. Erickson, D. L. Van Vliet, and M. Petersheim
pp 2260 - 2262; DOI:
10.1021/ja00475a063
PDF
Selective photoaggregation of metal atoms to small bimetallic clusters of known size. The chromium-molybdenum system CrnMom
Werner E. Klotzbuecher and Geoffrey A. Ozin
pp 2262 - 2264; DOI:
10.1021/ja00475a064
PDF
Preparation and isolation of .DELTA.1,4-bicyclo[2.2.0]hexene
J. Casanova, J. Bragin, and F. D. Cottrell
pp 2264 - 2265; DOI:
10.1021/ja00475a065
PDF
Enthalpy limit in the laser-induced reaction of 1-chloro-1,1-difluoroethane
R. N. Zitter and D. F. Koster
pp 2265 - 2266; DOI:
10.1021/ja00475a066
PDF
Product control by light intensity. The photoaddition of aldehydes to .alpha.-diketones
Mordecai B. Rubin and Shai Inbar
pp 2266 - 2268; DOI:
10.1021/ja00475a067
PDF
Organofluorosilicates in organic synthesis. 2. A convenient procedure for preparing primary alcohols from olefins. A novel facile oxidative cleavage of carbon-silicon bonds by m-chloroperoxybenzoic acid
Kohei Tamao, Toshio Kakui, and Makoto Kumada
pp 2268 - 2269; DOI:
10.1021/ja00475a068
PDF
Bis(2-diphenylphosphinoethyl)amine. A flexible synthesis of functionalized chelating diphosphines
Michael E. Wilson, Ralph G. Nuzzo, and George M. Whitesides
pp 2269 - 2270; DOI:
10.1021/ja00475a069
PDF
Stereochemistry of the degenerate metathesis of terminal alkenes - the nature of the chain-carrying metal-carbene complex
Charles P. Casey and Hendrik E. Tuinstra
pp 2270 - 2272; DOI:
10.1021/ja00475a070
PDF
Total synthesis of adriamycinone. Regiospecific synthesis of anthracyclinones via base-catalyzed cyclizations
Fumio Suzuki, Steven Trenbeath, Robert D. Gleim, and Charles J. Sih
pp 2272 - 2273; DOI:
10.1021/ja00475a071
PDF
Selected ion fragmentation with a tandem quadrupole mass spectrometer
R. A. Yost and C. G. Enke
pp 2274 - 2275; DOI:
10.1021/ja00475a072
PDF
Book Reviews

pp 2275 - 2278; DOI:
10.1021/ja00475a600
PDF

Issue 8


Photodissociation spectroscopy of hexatriene cations
Robert C. Dunbar and Harry Ho-I Teng
pp 2279 - 2283; DOI:
10.1021/ja00476a001
PDF
Photodissociation spectroscopy and structural rearrangements in ions of cyclooctatetraene, styrene, and related molecules
Emil W. Fu and Robert C. Dunbar
pp 2283 - 2288; DOI:
10.1021/ja00476a002
PDF
Spin-lattice relaxation in triphenylphosphine, triphenylarsine, and triphenylstibine
Charles A. Wilkie
pp 2288 - 2291; DOI:
10.1021/ja00476a003
PDF
Carbon-13 ENDOR studies of organic doublet and triplet state molecules
B. Kirste, H. Kurreck, W. Lubitz, and K. Schubert
pp 2292 - 2299; DOI:
10.1021/ja00476a004
PDF
Ion binding studied using quadrupole splittings of sodium-23(1+) ions in lyotropic liquid crystals. The dependence on surfactant type
G. Lindblom, B. Lindman, and G. J. T. Tiddy
pp 2299 - 2303; DOI:
10.1021/ja00476a005
PDF
Ultraviolet photoelectron studies of biological pyrimidines. The valence electronic structure of cytosine
C. Yu, S. Peng, I. Akiyama, J. Lin, and P. R. LeBreton
pp 2303 - 2307; DOI:
10.1021/ja00476a006
PDF
The effect of paramagnetic relaxation reagents on nitrogen-15 spin relaxation and the use of Gd(dpm)3 as a nitrogen-15 nuclear magnetic resonance spin label
George C. Levy, James J. Dechter, and Jozef Kowalewski
pp 2308 - 2314; DOI:
10.1021/ja00476a007
PDF
Banana and nonbanana bonds of the carbonyl group
Keith F. Purcell and J. Zapata
pp 2314 - 2319; DOI:
10.1021/ja00476a008
PDF
A tandem ion cyclotron resonance study of the reactions of allyl ions with benzene and substituted benzene
Raymond Houriet, Thomas A. Elwood, and Jean H. Futrell
pp 2320 - 2324; DOI:
10.1021/ja00476a009
PDF
Quantitative comparison of theoretical calculations with the experimentally determined electron density distribution of formamide
E. D. Stevens, J. Rys, and P. Coppens
pp 2324 - 2328; DOI:
10.1021/ja00476a010
PDF
Pseudopotential calculations. 5. Results for Group 2A and 2B dimethyls and chlorides
Mark A. Ratner, J. W. Moskowitz, and Sid Topiol
pp 2329 - 2334; DOI:
10.1021/ja00476a011
PDF
The shapes and other properties of non-transition element complexes. 1. AB6
Benjamin M. Gimarc, Joel F. Liebman, and Michael Kohn
pp 2334 - 2339; DOI:
10.1021/ja00476a012
PDF
The shapes and other properties of non-transition element complexes. 2. AB4
Benjamin M. Gimarc and Shakil A. Khan
pp 2340 - 2345; DOI:
10.1021/ja00476a013
PDF
The shapes and other properties of non-transition element complexes. 3. AB5
Benjamin M. Gimarc
pp 2346 - 2353; DOI:
10.1021/ja00476a014
PDF
A theoretical study of the metal-metal interaction in binuclear complexes of transition groups 6 and 7
Marc Benard
pp 2354 - 2362; DOI:
10.1021/ja00476a015
PDF
Electronic structures of azolium ions and their ylides. The imidazolium, oxazolium, and thiazolium ions
Haven S. Aldrich, William L. Alworth, and Nancy R. Clement
pp 2362 - 2366; DOI:
10.1021/ja00476a016
PDF
Stereochemistry of trans-MoX4(C2H4)2 and MoX4(O2)2 complexes
C. Bachmann, J. Demuynck, and A. Veillard
pp 2366 - 2369; DOI:
10.1021/ja00476a017
PDF
Sulfur chelates. 31. Synthesis and characterization of aryl xanthogens, xanthate esters, and esters of O-aryl S-alkyl thiocarbonates. Synthesis and single-crystal x-ray structure of a polymeric xanthogen complex of copper(I), [CuCl(S2COC6H4-4-CH3)2]n
H. W. Chen, J. P. Fackler, D. P. Schussler, and L. D. Thompson
pp 2370 - 2375; DOI:
10.1021/ja00476a018
PDF
Structural effects of cross-linking in polymer-bound bromotris(triphenylphosphine)rhodium(I) catalyst by x-ray absorption studies
Joseph Reed, P. Eisenberger, Boon-Keng Teo, and B. M. Kincaid
pp 2375 - 2378; DOI:
10.1021/ja00476a019
PDF
Mono- and biscarbonyl complexes of iron(II) tetraphenylporphyrin
B. B. Wayland, L. F. Mehne, and J. Swartz
pp 2379 - 2383; DOI:
10.1021/ja00476a020
PDF
Kinetics and mechanism of the quenching of the emission of substituted polypyridineruthenium(II) complexes. Reactions of RuL3+, *RuL32+, and RuL33+ with the copper(I)-copper(II) couple
M. A. Hoselton, C. T. Lin, H. A. Schwarz, and N. Sutin
pp 2383 - 2388; DOI:
10.1021/ja00476a021
PDF
Multiple metal-carbon bonds. 7. Preparation and characterization of Ta(.eta.5-C5H5)2(CH2)(CH3), a study of its decomposition, and some simple reactions
R. R. Schrock and P. R. Sharp
pp 2389 - 2399; DOI:
10.1021/ja00476a022
PDF
Proton nuclear magnetic resonance study of equilibriums and paramagnetisms of ferriprotoporphyrin IX-ligand complexations
Jin-Tsai Wang, Herman J. C. Yeh, and David F. Johnson
pp 2400 - 2405; DOI:
10.1021/ja00476a023
PDF
Catalytic homogeneous hydrogenation of arenes. 6. Reaction scope for the (.eta.3-2-propenyl)tris(trimethyl phosphite-P)cobalt catalyst
L. S. Stuhl, M. Rakowski DuBois, F. J. Hirsekorn, J. R. Bleeke, A. E. Stevens, and E. L. Muetterties
pp 2405 - 2410; DOI:
10.1021/ja00476a024
PDF
Electronic states of pentacarbonylchromium
P. Jeffrey Hay
pp 2411 - 2417; DOI:
10.1021/ja00476a025
PDF
Preparation and reactions of phosphine nickelocyclopentanes
R. H. Grubbs, Akira Miyashita, M. Liu, and P. Burk
pp 2418 - 2425; DOI:
10.1021/ja00476a026
PDF
Infrared spectra of argon matrix-isolated alkali halide salt/water complexes
Bruce S. Ault
pp 2426 - 2433; DOI:
10.1021/ja00476a027
PDF
Reaction of uranocenes with nitro compounds
Charles B. Grant and Andrew Streitwieser
pp 2433 - 2440; DOI:
10.1021/ja00476a028
PDF
Isotopically selective carbon dioxide transverse excitation laser induced chemical reactions of dichlorodifluoromethane and dibromodifluoromethane with olefins
J. J. Ritter
pp 2441 - 2444; DOI:
10.1021/ja00476a029
PDF
Reactivities of amino and aminium radicals: oxidative photoaddition of tetramethyl-2-tetrazene to olefins
Leon J. Magdzinski and Yuan L. Chow
pp 2444 - 2448; DOI:
10.1021/ja00476a030
PDF
Bridged [18]annulenes. 12b,12c,12d,12e,12f,12g-Hexahydrocoronene and its mono- and dibenzo analogs. Ring-current contribution to chemical shifts as a measure of degree of aromaticity
T. Otsubo, R. Gray, and V. Boekelheide
pp 2449 - 2456; DOI:
10.1021/ja00476a031
PDF
Bridged [18]annulenes. A study of the synthesis and properties of 12c,12d,12e,12f-tetrahydrobenzo[g,h,i]perylene and its analogs
R. B. DuVernet, O. Wennerstrom, J. Lawson, T. Otsubo, and V. Boekelheide
pp 2457 - 2464; DOI:
10.1021/ja00476a032
PDF
Synthesis, structure, and acetolysis of some fused cyclobutane derivatives
R. L. Petty, M. Ikeda, G. E. Samuelson, C. J. Boriack, K. D. Onan, A. T. McPhail, and J. Meinwald
pp 2464 - 2474; DOI:
10.1021/ja00476a033
PDF
Proton exchange in gas-phase isopropylation of benzene and toluene
Yukio Yamamoto, Setsuo Takamuku, and Hiroshi Sakurai
pp 2474 - 2478; DOI:
10.1021/ja00476a034
PDF
Concerning the mechanism of dehalogenation of halobenzene derivatives by gaseous Broensted acids
Hei-Wun Leung, Hiroshi Ichikawa, Yip-Hoi Li, and Alex G. Harrison
pp 2479 - 2484; DOI:
10.1021/ja00476a035
PDF
Steric effects in SN2 reactions
DeLos F. DeTar, Donald F. McMullen, and Narender P. Luthra
pp 2484 - 2493; DOI:
10.1021/ja00476a036
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 31. Rate constants for spin trapping. 1. Primary alkyl radicals
P. Schmid and K. U. Ingold
pp 2493 - 2500; DOI:
10.1021/ja00476a037
PDF
Increased electron demand in the solvolysis of secondary 2-norbornyl tosylates
Joseph B. Lambert and H. Wayne Mark
pp 2501 - 2505; DOI:
10.1021/ja00476a038
PDF
Solvolysis of 6,7-dimethoxy-1,2-dimethyl-exo-2-benzonorbornenyl derivatives. Evidence for an unsymmetrical benzonorbornenyl nonclassical intermediate
Harlan L. Goering, Chiu-Shan Chang, and Divakar Masilamani
pp 2506 - 2510; DOI:
10.1021/ja00476a039
PDF
Organosulfur compounds. 13. Optical resolution of chiral sulfinyl compounds via .beta.-cyclodextrin inclusion complexes
Marian Mikolajczyk and Jozef Drabowicz
pp 2510 - 2515; DOI:
10.1021/ja00476a040
PDF
Glycocinnamoylspermidines, a new class of antibiotics. 3. The structures of LL-BM123.beta., .gamma.1, and .gamma.2
G. A. Ellestad, D. B. Cosulich, R. W. Broschard, J. H. Martin, M. P. Kunstmann, G. O. Morton, J. E. Lancaster, W. Fulmor, and F. M. Lovell
pp 2515 - 2524; DOI:
10.1021/ja00476a041
PDF
Reactions of nucleophiles with strained cyclic sulfonate esters. Broensted relationships for rate and equilibrium constants for variation of phenolate anion nucleophile and leaving group
Timothy Deacon, Charles R. Farrar, Bernardus J. Sikkel, and Andrew Williams
pp 2525 - 2534; DOI:
10.1021/ja00476a042
PDF
N1'-Methylthiaminium diiodide. Model study on the effect of a coenzyme bound positive charge on reaction mechanisms requiring thiamin pyrophosphate
Frank Jordan and Yitbarek H. Mariam
pp 2534 - 2541; DOI:
10.1021/ja00476a043
PDF
Reactions in inclusion molecular complexes. 2. A topochemical solid-state photoaddition of acetone to deoxycholic acid
Meir Lahav, Les Leiserowitz, Ronit Popovitz-Biro, and Chia-Pin Tang
pp 2542 - 2544; DOI:
10.1021/ja00476a044
PDF
Hydride donation reactions of transition metal formyl complexes
Charles P. Casey and Stephen M. Neumann
pp 2544 - 2545; DOI:
10.1021/ja00476a045
PDF
Binuclear and mixed metal formyl complexes: isolation, characterization, and chemistry
J. A. Gladysz and Wilson Tam
pp 2545 - 2547; DOI:
10.1021/ja00476a046
PDF
6,9.alpha.-Oxido-11.alpha.,15.alpha.-dihydroxyprosta-6,(E)-13-dienoic acid methyl ester and 6,9.alpha.:6,11.alpha.-dioxido-15.alpha.-hydroxyprost-(E)-13-enoic acid methyl ester. Two isomeric forms of prostacyclin (PGI2)
Katsuichi Shimoji, Yoshitaka Konishi, Yoshinobu Arai, Masaki Hayashi, and Hisashi Yamamoto
pp 2547 - 2548; DOI:
10.1021/ja00476a047
PDF
Conformational equilibrium in the backbone of cyclic tripeptides
H. Kessler, P. Kondor, G. Krack, and P. Kraemer
pp 2548 - 2550; DOI:
10.1021/ja00476a048
PDF
cyclo-Triphosphorus (.delta.-P3) as a ligand in cobalt and nickel complexes with 1,1,1-tris(diphenylphosphinomethyl)ethane. Formation and structures
M. Di Vaira, C. A. Ghilardi, S. Midollini, and L. Sacconi
pp 2550 - 2551; DOI:
10.1021/ja00476a049
PDF
Catalytic irreversible inhibition of mammalian ornithine decarboxylase (E.C.4.1.1.17) by substrate and product analogs
B. W. Metcalf, P. Bey, C. Danzin, M. J. Jung, P. Casara, and J. P. Vevert
pp 2551 - 2553; DOI:
10.1021/ja00476a050
PDF
Existence and stability of a simple sulfide of iron(III)
A. H. Stiller, B. Jack McCormick, P. Russell, and P. A. Montano
pp 2553 - 2554; DOI:
10.1021/ja00476a051
PDF
Carbon-carbon bond formation at C4' of a nucleoside. Synthesis and utilization of a uridine 4',5'-enamine
John A. Secrist and William J. Winter
pp 2554 - 2555; DOI:
10.1021/ja00476a052
PDF
A simplified preparation of decaborane(14) from sodium tetrahydroborate
Gary B. Dunks and Kathy Palmer Ordonez
pp 2555 - 2556; DOI:
10.1021/ja00476a053
PDF
An experimental determination of the geometry and electron affinity of methyl radical
G. Barney Ellison, P. C. Engelking, and W. C. Lineberger
pp 2556 - 2558; DOI:
10.1021/ja00476a054
PDF
Chiral [16O, 17O, 18O]phosphate monoesters. 1. Asymmetric synthesis and stereochemical analysis of [1(R)-16O, 17O, 18O]phospho-(S)-propane-1,2-diol
Steven J. Abbott, Stephen R. Jones, Steven A. Weinman, and Jeremy R. Knowles
pp 2558 - 2560; DOI:
10.1021/ja00476a055
PDF
Cubitene: an irregular twelve-membered-ring diterpene from a termite soldier
Glenn D. Prestwich, David F. Wiemer, Jerrold Meinwald, and Jon Clardy
pp 2560 - 2561; DOI:
10.1021/ja00476a056
PDF
A stereocontrolled general synthesis of C-nucleosides
R. Noyori, T. Sato, and Y. Hayakawa
pp 2561 - 2563; DOI:
10.1021/ja00476a057
PDF
Stabilities of carbonium ions in solution. 6. Heats of formation of simple alkyl carbonium ions in sulfuryl chloride fluoride and their relevance to the nonclassical ion question
Edward M. Arnett and Craig Petro
pp 2563 - 2564; DOI:
10.1021/ja00476a058
PDF
Detection and trapping of a chemiluminescent o-xylylene peroxide. Chemical light formation along two separate paths
Jimmie P. Smith and Gary B. Schuster
pp 2564 - 2566; DOI:
10.1021/ja00476a059
PDF
Bis-pericyclic reactions: retrocycloaddition and the importance of avoiding piecewise analysis
James P. Snyder and Henrik Olsen
pp 2566 - 2567; DOI:
10.1021/ja00476a060
PDF
Organoselenium-induced ring closures. Stereoselective synthesis of cyclic .alpha.,.beta.-unsaturated sulfoxides, sulfones, and sulfides and synthesis of 6,9-sulfoxa-5(E)- and -5(Z)-prostacyclin, 6,9-sulfo-5(E)- and -5(Z)-prostacyclin, 6,9-sulfo-6.alpha.- and -6.beta.-4(E)-isoprostacyclin, and 6,9-thiaprostacyclin
K. C. Nicolaou, W. E. Barnette, and R. L. Magolda
pp 2567 - 2570; DOI:
10.1021/ja00476a061
PDF
Carbon-14 and deuterium isotope effects during the [2 + 2] cycloaddition of diphenylketene to styrene
Clair J. Collins, Ben M. Benjamin, and George W. Kabalka
pp 2570 - 2571; DOI:
10.1021/ja00476a062
PDF
Effects of liquid crystal solvents on the photodimerization of acenaphthylene
Jeanne M. Nerbonne and Richard G. Weiss
pp 2571 - 2573; DOI:
10.1021/ja00476a063
PDF
Long-range steric effects in rhodium(I) cleavages of secopentaprismanes. A reversible rhodium(I)-mediated cyclobutane-diolefin conversion
Philip E. Eaton and Dennis R. Patterson
pp 2573 - 2575; DOI:
10.1021/ja00476a064
PDF
Antineoplastic agents. 57. Isolation and structure of aphanastatin
Judith Polonsky, Zoa Varon, Bernadette Arnoux, Claudine Pascard, George R. Pettit, Jean H. Schmidt, and Linda M. Lange
pp 2575 - 2576; DOI:
10.1021/ja00476a065
PDF
Relative acidity of superacids: hydrofluoric acid:antimony pentafluoride compared with flurorsulfuric acid:antimony pentafluoride
Jean Sommer, Sylvie Schwartz, Paul Rimmelin, and Patrick Canivet
pp 2576 - 2577; DOI:
10.1021/ja00476a066
PDF
Insertion vs. addition of oligomeric difluorosilylenes. Evidence for the attack of oligomeric difluorosilylenes on the carbon-carbon double bond as an initial step in the insertion reactions with trans- and cis-difluoroethylene
Chao-Shiuan Liu and Tsai-Lih Hwang
pp 2577 - 2579; DOI:
10.1021/ja00476a067
PDF
Rates of radical .beta. cleavage in photogenerated diradicals
Peter J. Wagner, James H. Sedon, and Michael J. Lindstrom
pp 2579 - 2580; DOI:
10.1021/ja00476a068
PDF
Synthesis and characterization of the pentamolybdate ion, Mo5O17H3-
M. Filowitz, W. G. Klemperer, and W. Shum
pp 2580 - 2581; DOI:
10.1021/ja00476a069
PDF
Application of a novel double-labeling procedure to measurement of carbonyl oxygen isotope effects on the alkaline hydrolysis and hydrazinolysis of methyl benzoate
Marion H. O'Leary and John F. Marlier
pp 2582 - 2583; DOI:
10.1021/ja00476a070
PDF
A new and efficient total synthesis of (.+-.)-longifolene
Wolfgang Oppolzer and Thierry Godel
pp 2583 - 2584; DOI:
10.1021/ja00476a071
PDF
Metal carbene chemistry. Formation and reactions of (.eta.5-C5H5)Fe(CO)n(CH2)+ (n = 1,2) in the gas phase by ion cyclotron resonance spectroscopy
Amy E. Stevens and J. L. Beauchamp
pp 2584 - 2585; DOI:
10.1021/ja00476a072
PDF
Synthesis of 1,3-(dicyanomethylene)croconate salts. New bond-delocalized dianion, "Croconate Violet"
Alexander J. Fatiadi
pp 2586 - 2587; DOI:
10.1021/ja00476a073
PDF
Cyclic peroxides. 59. On the mechanism of the rubrene-enhanced chemiluminescence of .alpha.-peroxylactones
Waldemar Adam, O. Cueto, and F. Yany
pp 2587 - 2589; DOI:
10.1021/ja00476a074
PDF
Organic photochemistry with high energy (6.7 eV) photons: cis .dblharw. trans isomerism in cyclooctene
R. Srinivasan and K. H. Brown
pp 2589 - 2590; DOI:
10.1021/ja00476a075
PDF
Hydrocarbon formation from metal carbonyl clusters supported on highly divided oxides
A. K. Smith, A. Theolier, J. M. Basset, R. Ugo, D. Commereuc, and Y. Chauvin
pp 2590 - 2591; DOI:
10.1021/ja00476a076
PDF
Book Reviews

pp 2592 - 2592; DOI:
10.1021/ja00476a600
PDF

Issue 9


Permutational isomerism with bidentate ligands and other constraints
D. J. Klein and A. H. Cowley
pp 2593 - 2599; DOI:
10.1021/ja00477a001
PDF
Cyclotetraphosphanes: geometry, 1J(PP) nuclear magnetic resonance coupling constants, and phosphorus chemical shift anisotropy. A nuclear magnetic resonance study in liquid crystals
J. P. Albrand, A. Cogne, and J. B. Robert
pp 2600 - 2604; DOI:
10.1021/ja00477a002
PDF
The molecular structure of beryllocene
Ning-Shih Chiu and Lothar Schaefer
pp 2604 - 2607; DOI:
10.1021/ja00477a003
PDF
Extreme conformational flexibility of the furanose ring in DNA and RNA
Michael Levitt and Arieh Warshel
pp 2607 - 2613; DOI:
10.1021/ja00477a004
PDF
Kinetics and thermodynamics of the reactions of two iron(III) porphyrins with imidazole and 1-methylimidazole in dimethyl sulfoxide
Robert F. Pasternack, Bruce S. Gillies, and James R. Stahlbush
pp 2613 - 2619; DOI:
10.1021/ja00477a005
PDF
Photosensitization of stilbene isomerization by palladium and platinum porphyrins, an intermolecular quantum chain process
Janet A. Mercer-Smith and David G. Whitten
pp 2620 - 2625; DOI:
10.1021/ja00477a006
PDF
Visual pigments. 8. Hydrogen bonding effects on fluorescence properties of retinals
Takeshi Takemura, P. K. Das, Gordon Hug, and Ralph S. Becker
pp 2626 - 2630; DOI:
10.1021/ja00477a007
PDF
Visual pigments. 9. Fluorescence of dimers of retinals
Takeshi Takemura, Gordon Hug, P. K. Das, and Ralph S. Becker
pp 2631 - 2634; DOI:
10.1021/ja00477a008
PDF
Delayed fluorescence efficiencies of anthracene and phenanthrene
Don K. K. Liu and Larry R. Faulkner
pp 2635 - 2639; DOI:
10.1021/ja00477a009
PDF
Photochemical extrusion of nitrogen in azo compounds. An ab initio SCF-CI study
B. Bigot, A. Sevin, and A. Devaquet
pp 2639 - 2642; DOI:
10.1021/ja00477a010
PDF
Activity coefficients of an electrolyte A or B in a ternary mixture (A + B + water) and a transition model
Prem P. Singh
pp 2642 - 2645; DOI:
10.1021/ja00477a011
PDF
Topological orbitals, graph theory, and ionization potentials of saturated hydrocarbons
William C. Herndon, M. Lawrence Ellzey, and Krishnaiyengar S. Raghuveer
pp 2645 - 2650; DOI:
10.1021/ja00477a012
PDF
Ionization potentials of water from valence bond and molecular orbital wave functions
Daniel M. Chipman
pp 2650 - 2654; DOI:
10.1021/ja00477a013
PDF
Ab initio calculation of the reaction path for the addition of singlet (1A1) methylene to ethylene
Bronislaw Zurawski and Werner Kutzelnigg
pp 2654 - 2659; DOI:
10.1021/ja00477a014
PDF
Insertion reaction of a nucleophilic carbene. A molecular orbital theoretical study
Herbert Kollmar
pp 2660 - 2664; DOI:
10.1021/ja00477a015
PDF
The stability of alkyl anions. A molecular orbital theoretical study
H. Kollmar
pp 2665 - 2669; DOI:
10.1021/ja00477a016
PDF
Second-row molecular orbital calculations. 5. A minimal basis INDO for sodium-chlorine
Mark S. Gordon, Mark D. Bjorke, Fred J. Marsh, and Michael S. Korth
pp 2670 - 2678; DOI:
10.1021/ja00477a017
PDF
The interpretation of carbon-13 spin-lattice relaxation resulting from ring puckering in proline
Robert E. London
pp 2678 - 2685; DOI:
10.1021/ja00477a018
PDF
Metal-nitroxyl interactions. 3. Spin-labeled copper salicylaldimines
D. L. DuBois, G. R. Eaton, and S. S. Eaton
pp 2686 - 2689; DOI:
10.1021/ja00477a019
PDF
Copper(II)-histidine stereochemistry. Structure of L-histidinato-D-histidinatodiaquocopper(II) tetrahydrate
N. Camerman, J. K. Fawcett, T. P. A. Kruck, B. Sarkar, and A. Camerman
pp 2690 - 2693; DOI:
10.1021/ja00477a020
PDF
Mechanism of the photochemistry and photophysics of the tris(2,2'-bipyridine)chromium(III) ion in aqueous solution
M. Maestri, F. Bolletta, L. Moggi, V. Balzani, M. S. Henry, and M. Z. Hoffman
pp 2694 - 2701; DOI:
10.1021/ja00477a021
PDF
Photoinduced substitution and oxidative addition reactions of pentacarbonylmanganese(-1) and tetracarbonyl(triphenylphosphine)manganese(-1)
Robert A. Faltynek and Mark S. Wrighton
pp 2701 - 2705; DOI:
10.1021/ja00477a022
PDF
Halogen exchange reactions of methyl fluoride with gaseous Group 4 chlorocations and solid Group 3 chlorides. A study of parallels in the chemistry of isoelectronic species
R. Kinser, J. Allison, T. G. Dietz, M. DeAngelis, and D. P. Ridge
pp 2706 - 2708; DOI:
10.1021/ja00477a023
PDF
A spectroscopic and neutron diffraction investigation of structure, bonding, and molecular dynamics in bis(methylcyclopentadienyl)hafnium bis(tetrahydroborate), (.eta.5-CH3C5H4)2Hf(BH4)2
Paul L. Johnson, Steven A. Cohen, Tobin J. Marks, and Jack M. Williams
pp 2709 - 2716; DOI:
10.1021/ja00477a024
PDF
Reduction of carbon monoxide promoted by alkyl and hydride derivatives of permethylzirconocene
Juan M. Manriquez, Donald R. McAlister, Robert D. Sanner, and John E. Bercaw
pp 2716 - 2724; DOI:
10.1021/ja00477a025
PDF
Electrochemistry of nickel(II) and the behavior of oxide ions in chloroaluminate melts
Bernard Gilbert and R. A. Osteryoung
pp 2725 - 2730; DOI:
10.1021/ja00477a026
PDF
Electrochemical characterization of iron(II) and iron(I) phthalocyanine-amine derivatives
K. M. Kadish, L. A. Bottomley, and J. S. Cheng
pp 2731 - 2737; DOI:
10.1021/ja00477a027
PDF
Alkyl group isomerization in the oxidative addition of acyl chlorides to iridium(I) complexes
M. A. Bennett, R. Charles, and T. R. B. Mitchell
pp 2737 - 2743; DOI:
10.1021/ja00477a028
PDF
Tetrakis(alkoxy) and tetrakis(trialkylsiloxy) compounds of molybdenum(IV)
Malcolm H. Chisholm, William W. Reichert, and Peter Thornton
pp 2744 - 2748; DOI:
10.1021/ja00477a029
PDF
A systematic x-ray absorption study of molybdenum complexes. The accuracy of structural information from extended x-ray absorption fine structure
Stephen P. Cramer, Keith O. Hodgson, Edward I. Stiefel, and William E. Newton
pp 2748 - 2761; DOI:
10.1021/ja00477a030
PDF
Oxygen binding to cobalt porphyrins
James P. Collman, John I. Brauman, Kenneth M. Doxsee, Thomas R. Halbert, Susan E. Hayes, and Kenneth S. Suslick
pp 2761 - 2766; DOI:
10.1021/ja00477a031
PDF
Binding of a tetraammineruthenium complex to imidazole and purine derivatives under equilibrium conditions
Gilbert M. Brown, James E. Sutton, and Henry Taube
pp 2767 - 2774; DOI:
10.1021/ja00477a032
PDF
Reactions of coordinated molecules. 12. Preparation of cis-(OC)4Re[CH3C(O)][CH3CN(C6H5)(H)]: the ketamine tautomer of a metallo-.beta.-ketimine molecule
C. M. Lukehart and Jane V. Zeile
pp 2774 - 2778; DOI:
10.1021/ja00477a033
PDF
Nucleophilic aromatic substitution by organostannylsodiums. A second-order reaction displaying a solvent cage effect
Karl R. Wursthorn, Henry G. Kuivila, and Gary F. Smith
pp 2779 - 2789; DOI:
10.1021/ja00477a034
PDF
Three-electron oxidations. 13. Intramolecular cooxidation of 2,7-dihydroxyheptanoic acid. Structure of the transition state in the chromium(VI) oxidation of alcohols
K. G. Srinivasan and Jan Rocek
pp 2789 - 2795; DOI:
10.1021/ja00477a035
PDF
Phase-transfer catalysis. Nucleophilicity of anions in aqueous organic two-phase reactions catalyzed by onium salts. A comparison with homogeneous organic systems
Dario Landini, Angelamaria Maia, and Fernando Montanari
pp 2796 - 2801; DOI:
10.1021/ja00477a036
PDF
Mechanisms of elimination reactions. 29. Deuterium kinetic isotope effects in eliminations from amine oxides. The consequences of nonlinear proton transfer
Wen-Bin Chiao and William H. Saunders
pp 2802 - 2805; DOI:
10.1021/ja00477a037
PDF
Conformations of four-membered ring hydrazines and hydrazine radical cations
S. F. Nelsen, V. E. Peacock, G. R. Weisman, M. E. Landis, and J. A. Spencer
pp 2806 - 2810; DOI:
10.1021/ja00477a038
PDF
Dediazoniation of arenediazonium ions in homogeneous solution. 10. Solvent effects on the reactions of benzene- and 2,4,6-trimethylbenzenediazonium ion. Evidence for two intermediates
Ivanka Szele and Heinrich Zollinger
pp 2811 - 2815; DOI:
10.1021/ja00477a039
PDF
Dediazoniation of arenediazonium ions in homogeneous solution. 11. Evidence for two intermediates in the reaction of the 2,4,6-trimethylbenzenediazonium ion in 2,2,2-trifluoroethanol
Yoji Hashida, Robin G. M. Landells, Graham E. Lewis, Ivanka Szele, and Heinrich Zollinger
pp 2816 - 2823; DOI:
10.1021/ja00477a040
PDF
Intramolecular proton-transfer mechanism in the uracil monoanions and derivatives. A temperature-jump study
O. Bensaude, J. Aubard, M. Dreyfus, G. Dodin, and J. E. Dubois
pp 2823 - 2827; DOI:
10.1021/ja00477a041
PDF
Host-guest complexation. 10. Designed chiral recognition in solution between carboxyl-containing macrocyclic polyethers and an .alpha.-amino acid
Joseph M. Timko, Roger C. Helgeson, and Donald J. Cram
pp 2828 - 2834; DOI:
10.1021/ja00477a042
PDF
Chemistry of 4,4-dimethoxycyclohexa-2,5-dienone. Unusual formation of bridged polycyclic compounds
C. H. Foster and D. A. Payne
pp 2834 - 2837; DOI:
10.1021/ja00477a043
PDF
Photopolymerization of chiral crystals. 1. The planning and execution of a topochemical solid-state asymmetric synthesis with quantitative asymmetric induction
Lia Addadi and Meir Lahav
pp 2838 - 2844; DOI:
10.1021/ja00477a044
PDF
Chemistry of the sulfur-nitrogen bond. 14. Arenesulfenic acids from N-alkylidenearenesulfinamides (sulfinimines)
Franklin A. Davis, Arthur J. Friedman, and Upender K. Nadir
pp 2844 - 2852; DOI:
10.1021/ja00477a045
PDF
Homolytic displacement at sulfur by the hydrogen atom. Formation of hydrogen sulfide in the liquid-phase photolysis of thiols
William A. Pryor and Eric G. Olsen
pp 2852 - 2856; DOI:
10.1021/ja00477a046
PDF
Photocycloaddition of .beta.-methylstyrenes to some 9-cyanophenanthrenes. Chemical Consequences of exciplex formation
Richard A. Caldwell, Nabih I. Ghali, C. K. Chien, D. DeMarco, and Larry Smith
pp 2857 - 2863; DOI:
10.1021/ja00477a047
PDF
Structural studies of tetracyclines. Crystal and molecular structure of tetracycline methyl betaine pentahydrate
Gus J. Palenik and J. A. Bentley
pp 2863 - 2867; DOI:
10.1021/ja00477a048
PDF
Conformational analysis of 8-azanucleosides. Crystal and molecular structure of 8-azatubercidin monohydrate, a nucleoside analog exhibiting the "high anti" conformation
Stephen Sprang, Richard Scheller, Douglas Rohrer, and M. Sundaralingam
pp 2867 - 2872; DOI:
10.1021/ja00477a049
PDF
Carbon kinetic isotope effects on pyruvate decarboxylation catalyzed by yeast pyruvate decarboxylase and models
Frank Jordan, Donald J. Kuo, and Ernst U. Monse
pp 2872 - 2878; DOI:
10.1021/ja00477a050
PDF
Dependence of cycloamylose-substrate binding on charge
Raymond J. Bergeron, Michael Almy Channing, and Kathy Ann McGovern
pp 2878 - 2883; DOI:
10.1021/ja00477a051
PDF
Bifunctional substrates of erythrocyte carbonic anhydrase. Enzyme-catalyzed hydration and hydrolysis of pyruvate esters
Y. Pocker, J. E. Meany, Brain C. Davis, James Arrigoni, and John E. Stein
pp 2883 - 2885; DOI:
10.1021/ja00477a052
PDF
Nuclear magnetic resonance studies of catecholamines. Ternary complexes with adenosine 5'-triphosphate and divalent metal ions in aqueous solution
Joseph Granot
pp 2886 - 2891; DOI:
10.1021/ja00477a053
PDF
Syntheses of benzo[1,2:4,5]dicyclobutene derivatives
Richard Gray, Lewis G. Harruff, John Krymowski, Jane Peterson, and Virgil Boekelheide
pp 2892 - 2893; DOI:
10.1021/ja00477a054
PDF
Hexaradialene: precursors and structure
Lewis G. Harruff, Mark Brown, and Virgil Boekelheide
pp 2893 - 2894; DOI:
10.1021/ja00477a055
PDF
Carbon alkylation of aliphatic N-sulfinylamines
Fred M. Schell, J. Paul Carter, and Chantal Wiaux-Zamar
pp 2894 - 2896; DOI:
10.1021/ja00477a056
PDF
Adamantene by ring enlargement of 3-noradamantylcarbene
David J. Martella, Maitland Jones, and Paul V. R. Schleyer
pp 2896 - 2897; DOI:
10.1021/ja00477a057
PDF
Ab initio studies of the metal-metal bond in octachlorodirhenate(2-)
P. Jeffrey Hay
pp 2897 - 2898; DOI:
10.1021/ja00477a058
PDF
Synthetic models for bis-metallo active sites. A porphyrin capped by a tetrakis(pyridine) ligand system
David A. Buckingham, Maxwell J. Gunter, and Lewis N. Mander
pp 2899 - 2901; DOI:
10.1021/ja00477a059
PDF
Photoinduced reactions. 101. Photoinduced coupling reaction of 5-bromouridine to tryptophan derivatives
Isao Saito, Satoru Ito, and Teruo Matsuura
pp 2901 - 2902; DOI:
10.1021/ja00477a060
PDF
Gas phase photodissociation of C7H7+
David A. McCrery and Ben S. Freiser
pp 2902 - 2904; DOI:
10.1021/ja00477a061
PDF
Energy partitioning in unimolecular decomposition. Isotope effects on the kinetic energy release in the loss of hydrogen from (CH2:OH)+
Gregory J. Rickard, Neil W. Cole, John R. Christie, and Peter J. Derrick
pp 2904 - 2905; DOI:
10.1021/ja00477a062
PDF
Temperature and substituent dependence of photocycloadditions involving exciplexes
R. A. Caldwell and D. Creed
pp 2905 - 2907; DOI:
10.1021/ja00477a063
PDF
Structures of relative energies of gaseous CSH3+ ions
J. D. Dill and F. W. McLafferty
pp 2907 - 2908; DOI:
10.1021/ja00477a064
PDF
Impact of methyl imidate functionality upon Cope rearrangements. The heteroatomic cis-1,2-divinylcyclopropane example
Leo A. Paquette and Gary D. Ewing
pp 2908 - 2909; DOI:
10.1021/ja00477a065
PDF
Thermal isomerization of homoazocines
Gary D. Ewing, Steven V. Ley, and Leo A. Paquette
pp 2909 - 2911; DOI:
10.1021/ja00477a066
PDF
A molecular chlorine complex of cobalt(II). The crystal structure of a dichlorine sorption complex of dehydrated cobalt(II)-exchanged sodium zeolite A, Co4Na4-A.cntdot.4Cl2
V. Subramanian, Karl Seff, and Tor Ottersen
pp 2911 - 2913; DOI:
10.1021/ja00477a067
PDF
A stereoelectronic effect in hydrogen atom abstraction from a substituted cyclohexyl radical
A. L. J. Beckwith and C. Easton
pp 2913 - 2914; DOI:
10.1021/ja00477a068
PDF
Intramolecular reductive elimination of alkanes from cis-hydridoalkylbis(phosphine)platinum(II) complexes
Luigi Abis, Ayusman Sen, and Jack Halpern
pp 2915 - 2916; DOI:
10.1021/ja00477a069
PDF
Total synthesis of (.+-.)-N-methylmaysenine
E. J. Corey, Leland O. Weigel, David Floyd, and Mark G. Bock
pp 2916 - 2918; DOI:
10.1021/ja00477a070
PDF
The use of trans-methyl .beta.-nitroacrylate in Diels-Alder reactions
Samuel Danishefsky, Michael P. Prisbylla, and Steven Hiner
pp 2918 - 2920; DOI:
10.1021/ja00477a071
PDF
Gas phase oxidation and reduction reactions with C6H7-, HNO-, and HO2-
C. H. DePuy, Veronica M. Bierbaum, Robert J. Schmitt, and R. H. Shapiro
pp 2920 - 2921; DOI:
10.1021/ja00477a072
PDF
Hydrogen-deuterium exchange reactions of carbanions with deuterated alcohols in the gas phase
C. H. DePuy, Veronica M. Bierbaum, Gary K. King, and R. H. Shapiro
pp 2921 - 2922; DOI:
10.1021/ja00477a073
PDF
Reinvestigation and reevaluation of addition and insertion reactions of 9-diazoxanthene and 9-xanthylidene
G. W. Jones, K. T. Chang, R. Munjal, and H. Shechter
pp 2922 - 2923; DOI:
10.1021/ja00477a074
PDF
Spin trapping with .alpha.-pyridyl 1-oxide N-tert-butyl nitrones in aqueous solutions. A unique electron spin resonance spectrum for the hydroxyl radical adduct
Edward G. Janzen, Y. Y. Wang, and Raghav V. Shetty
pp 2923 - 2925; DOI:
10.1021/ja00477a075
PDF
Active homogeneous catalysts for the water gas shift reaction derived from the simple mononuclear carbonyls of iron, chromium, molybdenum, and tungsten
R. B. King, C. C. Frazier, R. M. Hanes, and A. D. King
pp 2925 - 2927; DOI:
10.1021/ja00477a076
PDF
Photoassisted intermolecular charge-transfer processes for organometals: insertion of tetracyanoethylene and spin adducts with quinones
K. Mochida, J. K. Kochi, K. S. Chen, and J. K. S. Wan
pp 2927 - 2929; DOI:
10.1021/ja00477a077
PDF
A terpenic synthon for .DELTA.1-cannabinoids
David B. Uliss, G. Richard Handrick, Haldean C. Dalzell, and Raj K. Razdan
pp 2929 - 2930; DOI:
10.1021/ja00477a078
PDF
A failure of the reactivity-selectivity principle for the quaternization of pyridines
Edward M. Arnett and Ronald Reich
pp 2930 - 2931; DOI:
10.1021/ja00477a079
PDF
Synthesis and reactions of a new neutral diazo complex of iridium(I)
K. Dahl Schramm and James A. Ibers
pp 2932 - 2933; DOI:
10.1021/ja00477a080
PDF
A total synthesis of lasalocid A
T. Nakata, G. Schmid, B. Vranesic, M. Okigawa, T. Smith-Palmer, and Y. Kishi
pp 2933 - 2935; DOI:
10.1021/ja00477a081
PDF
Additions and Corrections - Electrochemical Synthesis and Structural Characterization of the Iron-Sulfur Cluster Cation
P. J. Vergamini, R. R. Ryan, and G. J. Kubas
pp 2935 - 2935; DOI:
10.1021/ja00477a600
PDF
additions and Corrections - Ionization of Group 6 and 7 Protonic Acids in Dimethyl Sulfoxide
Edward M. Arnett, and Leonard E. Small
pp 2935 - 2935; DOI:
10.1021/ja00477a601
PDF
Additions and Corrections - An Anioinc Equivalent of the Friedel-Crafts Cycloacyltion
R. J. Boatman, B. J. Whitlock, and H. W. Whitlock, Jr.
pp 2935 - 2935; DOI:
10.1021/ja00477a602
PDF
Additions and Corrections - Magnesium Bromide-Tetrahydrofuran Complexes: MgBr2(C4H8O)2, MgBr2(C4H8O)3, MgBr2(C4H8O)4, and MgBr2(C4H8O)4(H2O)2. A Reagent for the Preparation of Anhydrous Magnesium Phosphodiester Salts.
Fausto Ramirez, Raghupathy Sarma, Yu Fen Chaw, Terence M. McCaffrey, James F. Marecek, Brian McKeever, and David Nierman
pp 2935 - 2935; DOI:
10.1021/ja00477a603
PDF
Additions and Corrections - Orientation in Nucleophilic Substitution at the Cycloheptatrienone Nucleus: Failure of Predictions from Either Electron Spin Resonance Data or Molecular Orbital Treatments.
Marino Carvazza, M. Perla Colombini, Massimo Martinelli, Lamberto Nucci, Lucio Pardi, Francesco Pietra, and Sergio Santucci
pp 2935 - 2935; DOI:
10.1021/ja00477a604
PDF
Additions and Corrections - Framework Electron Count in Metalloheteroboranes. Platinathiadecaboranes.
D. A. Thompson, T. K. Hilty, and R. W. Rudolph
pp 2936 - 2936; DOI:
10.1021/ja00477a605
PDF
Additions and Corrections - Oxidation and Reduction of Iron Porphyrins and Hemoproteins by Quinones and Hydroquinones.
C. E. Castro, G. M. Hathaway, and R. Havlin
pp 2936 - 2936; DOI:
10.1021/ja00477a606
PDF
Additions and Corrections - Nuclear Magnetic Resonance Investigation of 15N-Labeled Histidine in Aqueous Solutions.
F. Blomberg, W. Maurer, and H. Rüterjans
pp 2936 - 2936; DOI:
10.1021/ja00477a607
PDF
Additions and Corrections - Diastereomeric Transition States. High and Low Energy Reaction Pathways in the Cope Rearrangement.
Kenneth J. Shea, and Richard B. Phillips
pp 2936 - 2936; DOI:
10.1021/ja00477a608
PDF
Additions and Corrections - A Selective Formose Reaction
Yoshihiro Shigemasa, Osamu Nagae, Chikahiro Sakazawa, Ruka Nakashima, and Teruo Matsuura
pp 2936 - 2936; DOI:
10.1021/ja00477a609
PDF
Book Reviews

pp 2936 - 2938; DOI:
10.1021/ja00477a610
PDF

Issue 10


Circular dichroism of l-borneol
Patricia Ann Snyder and W. Curtis Johnson
pp 2939 - 2944; DOI:
10.1021/ja00478a001
PDF
Ab initio theoretical calculations on the circular dichroism spectra of trans-cyclooctene
Dean H. Liskow and Gerald A. Segal
pp 2945 - 2949; DOI:
10.1021/ja00478a002
PDF
Theoretical studies of the cubane molecule
Jerome M. Schulman, C. Rutherford Fischer, Paul Solomon, and Thomas J. Venanzi
pp 2949 - 2953; DOI:
10.1021/ja00478a003
PDF
Orbital interaction and chemical bonds. Exchange repulsion and rehybridization in chemical reactions
Hiroshi Fujimoto, Yoshihiro Osamura, and Tsutomu Minato
pp 2954 - 2959; DOI:
10.1021/ja00478a004
PDF
Photoelectron and charge-transfer spectra of benzobicycloalkenes. Relationships between through-space interactions and reactivity
L. N. Domelsmith, P. D. Mollere, K. N. Houk, Roger C. Hahn, and Richard P. Johnson
pp 2959 - 2965; DOI:
10.1021/ja00478a005
PDF
Laser photoluminescence spectra of diatomic magnesium (24Mg2 and 26Mg2) in solid argon at 12 K
John C. Miller and Lester Andrews
pp 2966 - 2970; DOI:
10.1021/ja00478a006
PDF
Solvent effect on excited state conformational changes in trifluoronitrosomethane
Julie Goodman and L. E. Brus
pp 2971 - 2974; DOI:
10.1021/ja00478a007
PDF
A method of describing the charge distribution in simple molecules
Peter A. Kollman
pp 2974 - 2984; DOI:
10.1021/ja00478a008
PDF
Symmetry numbers, not statistical factors, should be used in absolute rate theory and in Broensted relations
Eli Pollak and Philip Pechukas
pp 2984 - 2991; DOI:
10.1021/ja00478a009
PDF
Statistical factors in reaction rate theories
D. Robert Coulson
pp 2992 - 2996; DOI:
10.1021/ja00478a010
PDF
Vibronic coupling model for calculation of mixed valence absorption profiles
Susan B. Piepho, Elmars R. Krausz, and P. N. Schatz
pp 2996 - 3005; DOI:
10.1021/ja00478a011
PDF
Interaction of Walsh orbitals in trishomocycloheptatrienes and related hydrocarbons
Jens Spanget-Larsen, Rolf Gleiter, Michael R. Detty, and Leo A. Paquette
pp 3005 - 3014; DOI:
10.1021/ja00478a012
PDF
Porphyrins. 36. Synthesis and optical and electronic properties of some ruthenium and osmium octaethylporphyrins
Artemis Antipas, Johann W. Buchler, Martin Gouterman, and Paul D. Smith
pp 3015 - 3024; DOI:
10.1021/ja00478a013
PDF
Structures and properties of N-methyltetraphenylporphyrin complexes. The crystal and molecular structure of chloro-N-methyl-.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinatozinc(II) and the chelate effect of zinc(II), cobalt(II), and cadmium(II) N-methylporphyrin complexes
David K. Lavallee, Alan B. Kopelove, and Oren P. Anderson
pp 3025 - 3033; DOI:
10.1021/ja00478a014
PDF
Displacement of iron-sulfur clusters from ferredoxins and other iron-sulfur proteins
Bruce A. Averill, Judith R. Bale, and W. H. Orme-Johnson
pp 3034 - 3043; DOI:
10.1021/ja00478a015
PDF
Intersystem crossing observed by ultrasonic relaxation of the singlet-quintet spin equilibrium of iron(II) complexes in solution
James K. Beattie, Robert A. Binstead, and Robert J. West
pp 3044 - 3050; DOI:
10.1021/ja00478a016
PDF
Nucleophilic attack at carbon in .sigma.,.pi.-acetylides. Bridging one carbon and two carbon iminium ion complexes via addition of cyclohexylamine to [Fe2(CO)6(C2Ph)(PPh2)]. X-ray structures of [Fe2(CO)6{CHC(NHC6H11-c)(Ph)}PPh2] and [Fe2(CO)6{C(NHC6H11-c)CHPh}(PPh2)].0.5C6H6
Arthur J. Carty, Graham N. Mott, Nicholas J. Taylor, and John E. Yule
pp 3051 - 3059; DOI:
10.1021/ja00478a017
PDF
Synthesis and characterization of trimethyl phosphite derivatives HFeCo3(CO)12-x[P(OCH3)3]x, x = 1,2,3,4. Crystal and molecular structure of HFeCo3(CO)9[P(OCH3)3]3 at -139.degree.C
B. T. Huie, C. B. Knobler, and H. D. Kaesz
pp 3059 - 3071; DOI:
10.1021/ja00478a018
PDF
A neutron diffraction study of HFeCo3(CO)9(P(OCH3)3)3, a metal cluster complex with a triply bridging hydride ligand
Raymond G. Teller, Robert D. Wilson, Richard K. McMullan, Thomas F. Koetzle, and Robert Bau
pp 3071 - 3077; DOI:
10.1021/ja00478a019
PDF
Solution structure and dynamics of binuclear dinitrogen complexes of bis(pentamethylcyclopentadienyl)titanium(II) and bis(pentamethylcyclopentadienyl)zirconium(II)
Juan M. Manriquez, Donald R. McAlister, Edward Rosenberg, Alan M. Shiller, Kenneth L. Williamson, Sunney I. Chan, and John E. Bercaw
pp 3078 - 3083; DOI:
10.1021/ja00478a020
PDF
Tetracarbon metallocarboranes. 4. Structure of the nido system (.eta.5-C5H5)Co(CH3)4C4B7H6OC2H5. The problem of the structural diversity of electronically analogous cage systems
J. Robert Pipal and Russell N. Grimes
pp 3083 - 3088; DOI:
10.1021/ja00478a021
PDF
Electronic and resonance Raman spectra of the octabromodimolybdate(4-) ion
Robin J. H. Clark and Norman R. D'Urso
pp 3088 - 3091; DOI:
10.1021/ja00478a022
PDF
Near zero coordinate calcium(2+) and strontium(2+) in zeolite A. Crystal structures of dehydrated Ca6-A and Sr6-A
Roger L. Firor and Karl Seff
pp 3091 - 3096; DOI:
10.1021/ja00478a023
PDF
Cationic polymers as templates in zeolite crystallization
Roland H. Daniels, George T. Kerr, and Louis D. Rollmann
pp 3097 - 3100; DOI:
10.1021/ja00478a024
PDF
Organometallic reaction mechanisms. 16. Use of 2,2,6,6-tetramethylhept-4-en-3-one as a probe for detection of single-electron transfer in Grignard reactions with ketones
E. C. Ashby and T. L. Wiesemann
pp 3101 - 3110; DOI:
10.1021/ja00478a025
PDF
Mechanistic aspects of transition metal and trichloroacetic acid catalyzed reactions of 3-oxaquadricyclanes
H. Hogeveen and B. J. Nusse
pp 3110 - 3122; DOI:
10.1021/ja00478a026
PDF
A nuclear magnetic resonance kinetic study of the acid-catalyzed epoxide ring opening of tetramethylethylene oxide
Y. Pocker and B. P. Ronald
pp 3122 - 3127; DOI:
10.1021/ja00478a027
PDF
Reduction of .alpha.-keto acids by low-valent metal ions. 1. Reaction of aqueous chromous ion with pyruvic acid
J. Konstantatos, N. Katsaros, E. Vrachnou-Astra, and D. Katakis
pp 3128 - 3132; DOI:
10.1021/ja00478a028
PDF
Electron spin resonance line-width alternation and sodium(1+) transfer in the ion pairs of 3,5-dinitropyridine
M. Barzaghi, P. Cremaschi, A. Gamba, G. Morosi, C. Oliva, and M. Simonetta
pp 3132 - 3139; DOI:
10.1021/ja00478a029
PDF
Nucleophilic solvent assistance in the solvolysis of endo-2-norbornyl derivatives
J. Milton Harris, Dwight L. Mount, and Douglas J. Raber
pp 3139 - 3143; DOI:
10.1021/ja00478a030
PDF
Structural effects in solvolytic reactions. 26. A critical study of the effect of solvent on the exo:endo rate ratio in the solvolysis of 2-norbornyl derivatives. Evidence that the exo:endo rate ratio is not the result of K.DELTA./Ks processes
Herbert C. Brown, M. Ravindranathan, Frank J. Chloupek, and Irvin Rothberg
pp 3143 - 3149; DOI:
10.1021/ja00478a031
PDF
On the role of Newman projections in conformational analysis. Evidence for nonalternating ground states in highly strained molecules
W. Douglas Hounshell, Dennis A. Dougherty, and Kurt Mislow
pp 3149 - 3156; DOI:
10.1021/ja00478a032
PDF
Strained small ring compounds. Structure of a substituted semibullvalene, 1-cyanotricyclo[3.3.0.02,8]octa-3,6-diene. Geometric evidence for homoaromaticity in the molecular ground state
Gary G. Christoph and Mark A. Beno
pp 3156 - 3163; DOI:
10.1021/ja00478a033
PDF
Mechanism of formation of Grignard reagents
E. A. Vogler, R. L. Stein, and J. M. Hayes
pp 3163 - 3166; DOI:
10.1021/ja00478a034
PDF
Structure-basicity relationships in 1-phosphabicyclo[2.2.2]octane 1-oxide and 1-phosphabicyclo[2.2.1]heptane 1-oxide
D. S. Milbrath, J. G. Verkade, G. L. Kenyon, and D. H. Eargle
pp 3167 - 3169; DOI:
10.1021/ja00478a035
PDF
Electronic excitation transfer in polymers. 3. Singlet-singlet, triplet-singlet, and triplet-triplet energy transfers. Evidence for triplet migration among pendant phenyl groups of polystyrene
Nicholas J. Turro, Irene E. Kochevar, Yasuhiro Noguchi, and Ming-Fea Chow
pp 3170 - 3177; DOI:
10.1021/ja00478a036
PDF
Photophysics of phenylcyclopropanes, styrenes, and benzocycloalkadienes
Arthur L. Lyons and Nicholas J. Turro
pp 3177 - 3181; DOI:
10.1021/ja00478a037
PDF
Diels-Alder reactions between trans-1-N-acylamino-1,3-dienes and methyl acrylate. A correlation between diene photoelectron ionization potentials and reactivity, stereoselectivity, and regioselectivity
Larry E. Overman, Garry F. Taylor, K. N. Houk, and L. N. Domelsmith
pp 3182 - 3189; DOI:
10.1021/ja00478a038
PDF
Photochemical cis/trans isomerization of a stilbazolium betaine. A protolytic/photochemical reaction cycle
U. Steiner, M. H. Abdel-Kader, P. Fischer, and H. E. A. Kramer
pp 3190 - 3197; DOI:
10.1021/ja00478a039
PDF
Monomeric methyl metaphosphate. 3. Electrophilic aromatic substitution in solution
Arnold C. Satterthwait and F. H. Westheimer
pp 3197 - 3203; DOI:
10.1021/ja00478a040
PDF
Biosynthesis of cyclonerodiol
David E. Cane and Ming-Shi Shiao
pp 3203 - 3207; DOI:
10.1021/ja00478a041
PDF
Stereochemical studies of isoprenoid biosynthesis. Biosynthesis of fomannosin from [1,2-13C2]acetate
David E. Cane and Robert B. Nachbar
pp 3208 - 3212; DOI:
10.1021/ja00478a042
PDF
Reaction of 2,2-bis(p-chlorophenyl)-1,1,1-trichloroethane (DDT) with iron(II) porphyrins. Isolation of the vinylidene carbene complex, tetraphenylporphyriniron(II) (C:C(p-Cl-C6H4)2)
D. Mansuy, M. Lange, and J. C. Chottard
pp 3213 - 3214; DOI:
10.1021/ja00478a043
PDF
Very low pressure reactor. A new technique for measuring rates and equilibriums of radical-molecule reactions at low temperature. Heat of formation of the methyl radical
M. H. Baghal-Vayjooee, A. J. Colussi, and S. W. Benson
pp 3214 - 3215; DOI:
10.1021/ja00478a044
PDF
On the structure of starch-iodine
Robert C. Teitelbaum, Stanley L. Ruby, and Tobin J. Marks
pp 3215 - 3217; DOI:
10.1021/ja00478a045
PDF
A novel rearrangement of butenylcobaloximes. A mechanism for some coenzyme B12 catalyzed rearrangements
Adrian Bury, Martyn R. Ashcroft, and Michael D. Johnson
pp 3217 - 3219; DOI:
10.1021/ja00478a046
PDF
Effect of anion type on rate of facilitated transport of cations across liquid membranes via neutral macrocyclic carriers
J. J. Christensen, J. D. Lamb, S. R. Izatt, S. E. Starr, G. C. Weed, M. S. Astin, B. D. Stitt, and R. M. Izatt
pp 3219 - 3220; DOI:
10.1021/ja00478a047
PDF
Electrochemistry of vitamin B12. 3. One-electron intermediates in the reduction of methylcobalamin and methylcobinamide
Doris Lexa and Jean Michel Saveant
pp 3220 - 3222; DOI:
10.1021/ja00478a048
PDF
A stable surface modified platinum electrode prepared by coating with electroactive polymer
A. Merz and Allen J. Bard
pp 3222 - 3223; DOI:
10.1021/ja00478a049
PDF
A poly-p-nitrostyrene electrode surface. Potential dependent conductivity and electrocatalytic properties
Michael R. Van de Mark and Larry L. Miller
pp 3223 - 3225; DOI:
10.1021/ja00478a050
PDF
Study of the binding of cis- and trans-dichlorodiammineplatinum(II) to calf thymus DNA by extended x-ray absorption fine structure spectroscopy
Boon-Keng Teo, P. Eisenberger, J. Reed, Jacqueline K. Barton, and Stephen J. Lippard
pp 3225 - 3227; DOI:
10.1021/ja00478a051
PDF
.beta.-Cyclodextrinylbisimidazole, a model for ribonuclease
Ronald Breslow, James B. Doherty, Genevieve Guillot, and Carol Lipsey
pp 3227 - 3229; DOI:
10.1021/ja00478a052
PDF
Stereochemistry of acrylonitrile dimerization
W. von E. Doering and Catherine A. Guyton
pp 3229 - 3230; DOI:
10.1021/ja00478a053
PDF
A deuterium-labeling method for the assignment of histidine nuclear magnetic resonance peaks of proteins
Y. Arata, A. Shimizu, and H. Matsuo
pp 3230 - 3232; DOI:
10.1021/ja00478a054
PDF
Imidazolate anion bridged metalloporphyrins of relevance to a model for cytochrome oxidase
John T. Landrum, Christopher A. Reed, K. Hatano, and W. Robert Scheidt
pp 3232 - 3234; DOI:
10.1021/ja00478a055
PDF
Fluorescence quenching by nitroxyl radicals in micellar environments. A useful probe for studying micelle-substrate interactions
Samir Atik and Lawrence A. Singer
pp 3234 - 3235; DOI:
10.1021/ja00478a056
PDF
Stereochemistry of the 1,3-proton loss from a chiral methyl group in the biosynthesis of cycloartenol as determined by tritium nuclear magnetic resonance spectroscopy
Lawrence J. Altman, Choong Yol Han, Arthur Bertolino, George Handy, Dilip Laungani, Wayne Muller, Steven Schwartz, Dave Shanker, Willem H. De Wolf, and Frances Yang
pp 3235 - 3237; DOI:
10.1021/ja00478a057
PDF
Stereospecific double alkylation of diphenylacetylene by .eta.5-cyclopentadienyl(triphenylphosphine)dimethylcobalt(III). Evidence for noninterconvertible diastereomeric complexes in cobalt-catalyzed isomerization of alkenes, and comments on factors effecting rates of reductive elimination reactions
Eric R. Evitt and Robert G. Bergman
pp 3237 - 3239; DOI:
10.1021/ja00478a058
PDF
Photoionization by green light in micellar solution
J. K. Thomas and P. Piciulo
pp 3239 - 3240; DOI:
10.1021/ja00478a059
PDF
RCu.BF3. 3. Conjugate addition to previously unreactive substituted enoate esters and enoic acids
Yoshinori Yamamoto and Kazuhiro Maruyama
pp 3240 - 3241; DOI:
10.1021/ja00478a060
PDF
Observation of transient intermediates in the photochemical decomposition of substituted s-tetrazines
Barry Dellinger, Mark A. Paczkowski, Robin M. Hochstrasser, and Amos B. Smith
pp 3242 - 3243; DOI:
10.1021/ja00478a061
PDF
Fluorescence and photochemistry of the charge-transfer band in alcoholic vanadium trichloride solution
Y. Doi and M. Tsutsui
pp 3243 - 3244; DOI:
10.1021/ja00478a062
PDF
Structural features which determine the carcinogenesis, mutagenesis, and rates of acid- and water-mediated solvolysis of and nucleophilic attack upon diol epoxides, bay-region and non-bay-region tetrahydro epoxides, and K-region and non-K-region arene oxides
Allyn R. Becker, John M. Janusz, Donald Z. Rogers, and Thomas C. Bruice
pp 3244 - 3246; DOI:
10.1021/ja00478a063
PDF
Hydrogenation of d0 complexes: zirconium(IV) alkyl hydrides
Kerrie I. Gell and Jeffrey Schwartz
pp 3246 - 3248; DOI:
10.1021/ja00478a064
PDF
Multiphoton dissociation of molecules with low power continuous wave infrared laser radiation
R. L. Woodin, D. S. Bomse, and J. L. Beauchamp
pp 3248 - 3250; DOI:
10.1021/ja00478a065
PDF
Synthesis of BC4H5Fe(CO)3. An example of the conversion of an organometallic compound into a metallocarborane
Thomas P. Fehlner
pp 3250 - 3251; DOI:
10.1021/ja00478a066
PDF
3-Oxo-6-thia-2-azabicyclo[2.2.0]hexanes: novel .beta.-lactams derived from penams
Frank DiNinno
pp 3251 - 3252; DOI:
10.1021/ja00478a067
PDF
Reactions of platinum metal complexes with strained-ring compounds: IrClH(.eta.3-C3H4C6H5)[P(C6H5)3]2, an isolable .eta.3-allyl metal hydride complex
Thomas H. Tulip and James A. Ibers
pp 3252 - 3254; DOI:
10.1021/ja00478a068
PDF
Approaches to homogeneous reduction of carbon monoxide: reaction of niobium hydrides with coordinated carbon monoxide
Jay A. Labinger, Kwai Sam Wong, and W. Robert Scheidt
pp 3254 - 3255; DOI:
10.1021/ja00478a069
PDF
Ab initio calculation of the free energy of liquid water
Mihaly Mezei, S. Swaminathan, and David L. Beveridge
pp 3255 - 3256; DOI:
10.1021/ja00478a070
PDF
Conversion of farnesyl and nerolidyl pyrophosphate to cyclonerodiol by a cell-free extract from Gibberella fujikuroi
David E. Cane and Radha Iyengar
pp 3256 - 3258; DOI:
10.1021/ja00478a071
PDF
2-Methylpentadienyl- and 2,4-dimethylpentadienylpotassium: first examples of U-shaped, though open-chain, organometallics
Manfred Schlosser and Guenter Rauchschwalbe
pp 3258 - 3260; DOI:
10.1021/ja00478a072
PDF
X-ray photoelectron diffraction: a new technique for structural studies of complex solids
John M. Adams, Stephen Evans, and John M. Thomas
pp 3260 - 3262; DOI:
10.1021/ja00478a073
PDF
Extended x-ray absorption fine structure studies of the hydrolytic polymerization of iron(III). I. Structural characterization of the .mu.-dihydroxo-octaaquodiiron(III) dimer
T. I. Morrison, A. H. Reis, G. S. Knapp, F. Y. Fradin, H. Chen, and T. E. Klippert
pp 3262 - 3264; DOI:
10.1021/ja00478a074
PDF
An electron spin resonance study of the fluxional nature of paramagnetic (.pi.-alkenyl)tris(trimethyl phosphite)iron complexes
S. D. Ittel, P. J. Krusic, and P. Meakin
pp 3264 - 3266; DOI:
10.1021/ja00478a075
PDF
Book Reviews

pp 3267 - 3268; DOI:
10.1021/ja00478a600
PDF

Issue 11


Selective kinetic equalization of chemical shifts in protonated 1,3-dithiane
Joseph B. Lambert, Evita Vulgaris, Sidney I. Featherman, and Michal Majchrzak
pp 3269 - 3274; DOI:
10.1021/ja00479a001
PDF
Molecular-beam study of the activation energy requirements for the dioxetane reaction
K. T. Alben, A. Auerbach, W. M. Ollison, J. Weiner, and R. J. Cross
pp 3274 - 3278; DOI:
10.1021/ja00479a002
PDF
Collisional activation and metastable ion characteristics. 59. Efficiency of collisional activation of gaseous organic ions
Myung S. Kim and Fred W. McLafferty
pp 3279 - 3282; DOI:
10.1021/ja00479a003
PDF
Laser photolysis study of the photoisomerization of retinals
Bernard Veyret, Stephen G. Davis, Massayoshi Yoshida, and Karl Weiss
pp 3283 - 3290; DOI:
10.1021/ja00479a004
PDF
Detection and investigation of allyl and benzyl radicals by photoelectron spectroscopy
F. A. Houle and J. L. Beauchamp
pp 3290 - 3294; DOI:
10.1021/ja00479a005
PDF
Reactions of recoil generated chlorine-38 atoms with 2,3-dichlorohexafluoro-2-butene. Cis/trans isomerization accompanying chlorine for chlorine replacement
D. J. Stevens and Leonard D. Spicer
pp 3295 - 3298; DOI:
10.1021/ja00479a006
PDF
The potential surface for 1,3-dimethylenecyclobutadiene
Ernest R. Davidson, Weston Thatcher Borden, and Justin Smith
pp 3299 - 3302; DOI:
10.1021/ja00479a007
PDF
Ab initio calculations on the very strong hydrogen bond of the biformate anion and comparative esterification studies
J. Emsley, O. P. A. Hoyte, and R. E. Overill
pp 3303 - 3306; DOI:
10.1021/ja00479a008
PDF
Prototypes for aliphatic and aromatic diazonium ions. An ab initio study of the methane- and benzenediazonium ions
Mark A. Vincent and Leo Radom
pp 3306 - 3312; DOI:
10.1021/ja00479a009
PDF
Charge distributions and chemical effects. 13. Ab initio study of the charge density-carbon-13 nuclear magnetic resonance shift correlation for ethylenic carbon atoms
Herve Henry and Sandor Fliszar
pp 3312 - 3315; DOI:
10.1021/ja00479a010
PDF
Prediction of carbon-13 nuclear magnetic resonance chemical shifts
Dennis H. Smith and Peter C. Jurs
pp 3316 - 3321; DOI:
10.1021/ja00479a011
PDF
Matrix electron nuclear double resonance studies of the proton environment of the radical in natural and solvent-refined coal
S. Schlick, P. A. Narayana, and Larry Kevan
pp 3322 - 3326; DOI:
10.1021/ja00479a012
PDF
Pressure saturation of the collisional quenching of the 3B1 state of sulfur dioxide
S. J. Strickler and R. Neil Rudolph
pp 3326 - 3331; DOI:
10.1021/ja00479a013
PDF
Determination of the absolute configuration of a secondary hydroxy group in a chiral secondary alcohol using glycosidation shifts in carbon-13 nuclear magnetic resonance spectroscopy
Shujiro Seo, Yutaka Tomita, Kazuo Tori, and Yohko Yoshimura
pp 3331 - 3339; DOI:
10.1021/ja00479a014
PDF
Three-dimensional aromaticity of polyhedral boranes
Junichi Aihara
pp 3339 - 3342; DOI:
10.1021/ja00479a015
PDF
Addition compounds of alkali metal hydrides. 15. Steric effects in the reaction of representative trialkylboranes with lithium and sodium hydrides to form the corresponding trialkylborohydrides
Herbert C. Brown, S. Krishnamurthy, and John L. Hubbard
pp 3343 - 3349; DOI:
10.1021/ja00479a016
PDF
An ultraviolet photoelectron spectroscopic-molecular orbital study of some cyclopolyphosphines
A. H. Cowley, M. J. S. Dewar, M. Lattman, J. L. Mills, and M. McKee
pp 3349 - 3354; DOI:
10.1021/ja00479a017
PDF
Reactions of metal-to-metal multiple bonds. 3. Addition of nitric oxide to hexakis(alkoxy)dimolybdenum compounds. Preparation and properties of bis(nitrosyl)hexakis(alkoxy)dimolybdenum compounds and structural characterization of the isopropoxy derivative
M. H. Chisholm, F. A. Cotton, M. W. Extine, and R. L. Kelly
pp 3354 - 3358; DOI:
10.1021/ja00479a018
PDF
Multiple metal-carbon bonds. 8. Preparation, characterization, and mechanism of formation of the tantalum and niobium neopentylidene complexes, M(CH2CMe3)3(CHCMe3)
Richard R. Schrock and Jere D. Fellmann
pp 3359 - 3370; DOI:
10.1021/ja00479a019
PDF
Heavy transition metal complexes of biologically important molecules. 3. Crystal and molecular structure of bis(.mu.-1-methylthyminato-N3,O4)bis(cis-diammineplatinum(II)) dinitrate hydrate, [(NH3)2Pt(C6H7N2O2)2Pt(NH3)2](NO3)2.H2O
Colin James Lyne Lock, Henry J. Peresie, Barnett Rosenberg, and Graham Turner
pp 3371 - 3374; DOI:
10.1021/ja00479a020
PDF
Iron(III) chelates with hexadentate ligands from triethylenetetramine and .beta.-diketones or salicylaldehyde. Spin state dependent crystal and molecular structures of [Fe(acac)2trien]PF6(S = 5/2), [Fe(acacCl)2trien]PF6(S = 5/2), [Fe(sal)2trien]Cl.2H2O(S = 1/2), and [Fe(sal)2trien]NO3.H2O(S = 1/2)
Ekk Sinn, Greig Sim, Eric V. Dose, Michael F. Tweedle, and Lon J. Wilson
pp 3375 - 3390; DOI:
10.1021/ja00479a021
PDF
Electron density in bis(dicarbonyl-.pi.-cyclopentadienyliron) at liquid nitrogen temperature by x-ray and neutron diffraction
Andre Mitschler, Bernard Rees, and Mogens S. Lehmann
pp 3390 - 3397; DOI:
10.1021/ja00479a022
PDF
The molybdenum site of nitrogenase. Preliminary structural evidence from x-ray absorption spectroscopy
Stephen P. Cramer, Keith O. Hodgson, William O. Gillum, and Leonard E. Mortenson
pp 3398 - 3407; DOI:
10.1021/ja00479a023
PDF
Allylic alkylation: preparation of .pi.-allylpalladium complexes from olefins
Barry M. Trost, Paul E. Strege, Lothar Weber, Terry J. Fullerton, and Thomas J. Dietsche
pp 3407 - 3415; DOI:
10.1021/ja00479a024
PDF
Allylic alkylation: nucleophilic attack on .pi.-allylpalladium complexes
Barry M. Trost, Lothar Weber, Paul E. Strege, Terry J. Fullerton, and Thomas J. Dietsche
pp 3416 - 3426; DOI:
10.1021/ja00479a025
PDF
Allylic alkylation: nature of the nucleophile and application to prenylation
Barry M. Trost, Lothar Weber, Paul Strege, Terry J. Fullerton, and Thomas J. Dietsche
pp 3426 - 3435; DOI:
10.1021/ja00479a026
PDF
Stereocontrolled approach to steroid side chain via organopalladium chemistry. Partial synthesis of 5.alpha.-cholestanone
Barry M. Trost and Thomas R. Verhoeven
pp 3435 - 3443; DOI:
10.1021/ja00479a027
PDF
A highly enantioselective synthesis of cyclopropane derivatives through chiral cobalt(II) complex catalyzed carbenoid reaction. General scope and factors determining the enantioselectivity
Akira Nakamura, Akira Konishi, Yoshitaka Tatsuno, and Sei Otsuka
pp 3443 - 3448; DOI:
10.1021/ja00479a028
PDF
Enantioselective carbenoid cyclopropanation catalyzed by chiral vic-dioximatocobalt(II) complexes prepared from natural camphor and .beta.-pinene. Mechanism and stereochemistry
Akira Nakamura, Akira Konishi, Ryoichi Tsujitani, Masaaki Kudo, and Sei Otsuka
pp 3449 - 3461; DOI:
10.1021/ja00479a029
PDF
Quinol intermediates in the reaction of .pi.-allylnickel bromides with quinones
Louis S. Hegedus and Bruce R. Evans
pp 3461 - 3467; DOI:
10.1021/ja00479a030
PDF
New silicon-phosphorus reagents in organic synthesis. Carbonyl and conjugate addition reactions of silicon phosphite esters and related systems
David A. Evans, Kenneth M. Hurst, and James M. Takacs
pp 3467 - 3477; DOI:
10.1021/ja00479a031
PDF
Properties and reactions of ketene in the gas phase by ion cyclotron resonance spectroscopy and photoionization mass spectrometry. Proton affinity, site specificity of protonation, and heat of formation of ketene
Juergen Vogt, Ashley D. Williamson, and J. L. Beauchamp
pp 3478 - 3483; DOI:
10.1021/ja00479a032
PDF
Photoreduction and photodecarboxylation of pyruvic acid. Applications of CIDNP to mechanistic photochemistry
G. L. Closs and R. J. Miller
pp 3483 - 3494; DOI:
10.1021/ja00479a033
PDF
The role of substituents in controlling the mode of intramolecular cycloaddition of nitrile ylides
Albert Padwa, Per H. J. Carlsen, and Audrey Ku
pp 3494 - 3505; DOI:
10.1021/ja00479a034
PDF
Reactivity of methyl-substituted ethylenebromonium ions. Correlation between charge distribution and regio- or chemoselectivity
Jacques-Emile Dubois and Jacques R. Chretien
pp 3506 - 3513; DOI:
10.1021/ja00479a035
PDF
Reactivity and ion pairing of alkali .beta.-ketoenolates
Vincent M. DePalma and Edward M. Arnett
pp 3514 - 3525; DOI:
10.1021/ja00479a036
PDF
Spectroelectrochemical studies of olefins. 3. The dimerization mechanism of the 4,4'-dimethoxystilbene cation radical in the absence and presence of methanol
Eberhard Steckhan
pp 3526 - 3533; DOI:
10.1021/ja00479a037
PDF
Formation of dithioether dications in the anchimerically assisted reduction of monosulfoxides of mesocyclic and acyclic dithioethers
Joyce T. Doi and W. Kenneth Musker
pp 3533 - 3536; DOI:
10.1021/ja00479a038
PDF
Neutral products from deprotonation of tertiary cations in the gas phase
William J. Marinelli and Thomas Hellman Morton
pp 3536 - 3539; DOI:
10.1021/ja00479a039
PDF
High-yield synthesis and crystal structure of 1,5,9,13-tetraazacyclohexadecane ([16]aneN4)
William L. Smith, James D. Ekstrand, and Kenneth N. Raymond
pp 3539 - 3544; DOI:
10.1021/ja00479a040
PDF
Antineoplastic agents. 53. The crystal structure of radiatin
James J. Einck, Cherry L. Herald, George R. Pettit, and Robert B. Von Dreele
pp 3544 - 3548; DOI:
10.1021/ja00479a041
PDF
2-Deoxypentoses. Stereoselective reduction of ketene dithioacetals
Margaret Y. H. Wong and Gary R. Gray
pp 3548 - 3553; DOI:
10.1021/ja00479a042
PDF
Complexation of 4-biphenylcarboxylate by cyclohexaamylose. A conductometric and carbon-13 nuclear magnetic resonance spectrometric analysis
Robert I. Gelb, Lowell M. Schwartz, Christopher T. Murray, and Daniel A. Laufer
pp 3553 - 3559; DOI:
10.1021/ja00479a043
PDF
Tyrosine protecting groups: minimization of rearrangement to 3-alkyltyrosine during acidolysis
M. Engelhard and R. B. Merrifield
pp 3559 - 3563; DOI:
10.1021/ja00479a044
PDF
Decarboxylation of monosubstituted derivatives of carbonic acid. Comparative studies of water- and acid-catalyzed decarboxylation of sodium alkyl carbonates in water and water-d2
Y. Pocker, B. L. Davison, and T. L. Deits
pp 3564 - 3567; DOI:
10.1021/ja00479a045
PDF
Nitrogen-15 nuclear magnetic resonance studies of iron-bound cyanide(nitrogen-15)(1-) ion in ferric low-spin cyanide complexes of various porphyrin derivatives and various hemoproteins
Isao Morishima and Toshiro Inubushi
pp 3568 - 3574; DOI:
10.1021/ja00479a046
PDF
Model compounds for R-state and T-state hemoglobins
Jon Geibel, John Cannon, Dwane Campbell, and T. G. Traylor
pp 3575 - 3585; DOI:
10.1021/ja00479a047
PDF
Avidin-biotin affinity columns. General methods for attaching biotin to peptides and proteins
Klaus Hofmann, Frances M. Finn, and Yoshiaki Kiso
pp 3585 - 3590; DOI:
10.1021/ja00479a048
PDF
Protein rotational correlation times determined in aqueous solution by carbon-13 rotating frame spin-lattice relaxation in the presence of an off-resonance radiofrequency field
Thomas L. James, Gerald B. Matson, and Irwin D. Kuntz
pp 3590 - 3594; DOI:
10.1021/ja00479a049
PDF
The primary water splitting light reaction. Mass spectrometric determination of gaseous hydrogen and oxygen evolution from water photolysis by platinized chlorophyll a dihydrate polycrystals
Francis K. Fong and Lory Galloway
pp 3594 - 3596; DOI:
10.1021/ja00479a050
PDF
Osmium-catalyzed vicinal oxyamination of olefins by N-chloro-N-argentocarbamates
Eugenio Herranz, Scott A. Biller, and K. Barry Sharpless
pp 3596 - 3598; DOI:
10.1021/ja00479a051
PDF
An intramolecular cyclization of enaminones involving benzyne intermediates and application to the synthesis of .gamma.-lycorane and related compounds
Hideo Iida, Yoshifumi Yuasa, and Chihiro Kibayashi
pp 3598 - 3599; DOI:
10.1021/ja00479a052
PDF
Total synthesis of (.+-.)-dendrobine
William R. Roush
pp 3599 - 3601; DOI:
10.1021/ja00479a053
PDF
Oxobis(2,2'-bipyridine)pyridineruthenium(IV) ion, [(bpy)2(py)Ru:O]2+
Bruce A. Moyer and Thomas J. Meyer
pp 3601 - 3603; DOI:
10.1021/ja00479a054
PDF
Mechanism of action of coenzyme B12. An overall anionic mechanism for carbon-skeleton rearrangement in a model reaction
A. Ian Scott, Jemo Kang, David Dalton, and S. K. Chung
pp 3603 - 3604; DOI:
10.1021/ja00479a055
PDF
Binuclear copper(II) "face to face" inclusion complex of a macrotricyclic ligand
Remy Louis, Yvette Agnus, and Raymond Weiss
pp 3604 - 3605; DOI:
10.1021/ja00479a056
PDF
Highly reduced organometallics. 3. Tetrasodium tetracarbonylmetalates(4-) of chromium, molybdenum, and tungsten, Na4M(CO)4
John E. Ellis, Charles P. Parnell, and Gary P. Hagen
pp 3605 - 3607; DOI:
10.1021/ja00479a057
PDF
MNDO parameters for third period elements
Michael J. S. Dewar, Michael L. McKee, and Henry S. Rzepa
pp 3607 - 3607; DOI:
10.1021/ja00479a058
PDF
Catalysis of ester aminolysis by macrocyclic ionophores
Richard D. Gandour, David A. Walker, Ashutosh Nayak, and George R. Newkome
pp 3608 - 3609; DOI:
10.1021/ja00479a059
PDF
3-Benzyloxyisoxazole system in construction of tetracyclines
Gilbert Stork and Alfred A. Hagedorn
pp 3609 - 3611; DOI:
10.1021/ja00479a060
PDF
Olefin homologation with titanium methylene compounds
F. N. Tebbe, G. W. Parshall, and G. S. Reddy
pp 3611 - 3613; DOI:
10.1021/ja00479a061
PDF
Chemistry of oxasilacyclopropane. 2. Formations of dioxasilacyclopentanes in the reaction of oxasilacyclopropane derivatives with adamantanone and norbornone
Wataru Ando, Masayuki Ikeno, and Akira Sekiguchi
pp 3613 - 3615; DOI:
10.1021/ja00479a062
PDF
Stereochemistry of vicinal cyanohydrin reduction-elimination
James A. Marshall and Lawrence J. Karas
pp 3615 - 3616; DOI:
10.1021/ja00479a063
PDF
Biosynthetic studies with carbon-13. Lankacidin group of antibiotics
Masakazu Uramoto, Noboru Otake, Lewis Cary, and Masato Tanabe
pp 3616 - 3617; DOI:
10.1021/ja00479a064
PDF
Aqueous lanthanide shift reagents. 6. Lanthanide effects on the proton and carbon-13 relaxation rates of sarcosine. Evidence for isostructural amino acid complexes along the lanthanide series
Gabriel A. Elgavish and Jacques Reuben
pp 3617 - 3619; DOI:
10.1021/ja00479a065
PDF
Sequential rearrangements via bridged carbocations
Wolfgang Kirmse and Bernd-Rainer Guenther
pp 3619 - 3620; DOI:
10.1021/ja00479a066
PDF
Lithium ion promotion in the synthesis of novel dinuclear iron-carbyne complexes
M. Nitay, Witta Priester, and Myron Rosenblum
pp 3620 - 3622; DOI:
10.1021/ja00479a067
PDF
Flash vacuum pyrolysis studies. 5. Methanesulfenic acid
Robert E. Penn, Eric Block, and Larry K. Revelle
pp 3622 - 3623; DOI:
10.1021/ja00479a068
PDF
Catalysis of carbon monoxide hydrogenation by soluble mononuclear complexes
J. W. Rathke and H. M. Feder
pp 3623 - 3625; DOI:
10.1021/ja00479a069
PDF
Alkali metal ion specificity in the solution ordering of a nucleotide, 5'-guanosine monophosphate
T. J. Pinnavaia, Christopher L. Marshall, Claudia M. Mettler, Cherie L. Fisk, H. Todd Miles, and Edwin D. Becker
pp 3625 - 3627; DOI:
10.1021/ja00479a070
PDF
Novel binuclear cationic complexes of rhodium(I) and iridium(I)
Martin Cowie, Joel T. Mague, and Alan R. Sanger
pp 3628 - 3629; DOI:
10.1021/ja00479a071
PDF
An unusual reaction of tri-tert-butylphosphine with rhodium(III) and iridium(III) chlorides
Ram G. Goel, Reynaldo G. Montemayor, and William O. Ogini
pp 3629 - 3630; DOI:
10.1021/ja00479a072
PDF
A model .beta. turn. Circular dichroism and infrared spectra of a tetrapeptide
M. Kawai and G. Fasman
pp 3630 - 3632; DOI:
10.1021/ja00479a073
PDF
Generation of stable acidic solutions of copper(III) chelates from basic copper(II) solutions
Philip Stevens, J. Michael Waldeck, John Strohl, and Robert Nakon
pp 3632 - 3634; DOI:
10.1021/ja00479a074
PDF
Octahydro- and perhydro[0.0]paracyclophane
Philip E. Eaton and Utpal R. Chakraborty
pp 3634 - 3635; DOI:
10.1021/ja00479a075
PDF
A novel synthesis of (.+-.)-4-demethoxydaunomycinone
Francis A. J. Kerdesky and Michael P. Cava
pp 3635 - 3636; DOI:
10.1021/ja00479a076
PDF
A general, selective, and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium
D. Milstein and J. K. Stille
pp 3636 - 3638; DOI:
10.1021/ja00479a077
PDF
A synthesis of dl-cocaine using nitrone intermediates
J. J. Tufariello and G. B. Mullen
pp 3638 - 3639; DOI:
10.1021/ja00479a078
PDF
Substrate selectivity and orientation in aromatic substitution by molecular fluorine
F. Cacace and A. P. Wolf
pp 3639 - 3641; DOI:
10.1021/ja00479a079
PDF
Thermolysis of .gamma.-peroxy-.gamma.-butyrolactones: alternate modes for fragmentation
Dorothy H. Gibson and Joseph T. Joseph
pp 3641 - 3642; DOI:
10.1021/ja00479a080
PDF
Properties and structure of a tetrakis(tert-phosphino) macrocycle
Raymond E. Davis, Carl W. Hudson, and Evan P. Kyba
pp 3642 - 3643; DOI:
10.1021/ja00479a081
PDF
Bicyclobutadienylene(tricyclo[4.2.0.02,5]octa-1,3,5,7-tetraene)-.eta.5-cyclopentadienylcobalt. A possible intermediate in the remarkable gas phase rearrangement of 1,2-diethynyl-.eta.4-cyclobutadiene-.eta.5-cyclopentadienylcobalt
John R. Fritch and K. Peter C. Vollhardt
pp 3643 - 3645; DOI:
10.1021/ja00479a082
PDF
Existence and structure of the molecular ion 18-vanadate(IV)
Garrett K. Johnson and E. O. Schlemper
pp 3645 - 3646; DOI:
10.1021/ja00479a083
PDF
Book Reviews

pp 3647 - 3648; DOI:
10.1021/ja00479a600
PDF

Issue 12


Energy transfer in excited ionic species. Rates and mechanism of dimerization of protonated amines with their neutral bases
Paul V. Neilson, Michael T. Bowers, Marian Chau, William R. Davidson, and Donald H. Aue
pp 3649 - 3658; DOI:
10.1021/ja00480a001
PDF
Generalized selection rules: symmetry rules for molecules or chromophores in perturbing fields
Pieter E. Schipper
pp 3658 - 3668; DOI:
10.1021/ja00480a002
PDF
Theoretical study of the vinyl azide-.upsilon.-triazole isomerization
Luke A. Burke, Georges Leroy, Minh Tho Nguyen, and Michel Sana
pp 3668 - 3674; DOI:
10.1021/ja00480a003
PDF
A theoretical study of substituted CHNO isomers
Dieter Poppinger and Leo Radom
pp 3674 - 3685; DOI:
10.1021/ja00480a004
PDF
Counterintuitive orbital mixing in semiempirical and ab initio molecular orbital calculations
J. H. Ammeter, H. B. Buergi, J. C. Thibeault, and R. Hoffmann
pp 3686 - 3692; DOI:
10.1021/ja00480a005
PDF
Interaction between matrix isolated nickel difluoride and carbon monoxide. An ab initio molecular orbital study
S. Besnainou and J. L. Whitten
pp 3692 - 3698; DOI:
10.1021/ja00480a006
PDF
Molecular orbitals from group orbitals. 6. Quantitative evaluation and nature of the stabilizing and destabilizing orbital interactions in difluoroethylenes and fluoropropenes
Myung-Hwan Whangbo, David J. Mitchell, and Saul Wolfe
pp 3698 - 3706; DOI:
10.1021/ja00480a007
PDF
Formation and disappearance of free radicals, and the micellar equilibrium in the detergent sodium 4-(6'-dodecyl)benzenesulfonate
A. Henglein and Th. Proske
pp 3706 - 3709; DOI:
10.1021/ja00480a008
PDF
Chemically modified electrodes. 10. Electron spectroscopy for chemical analysis and alternating current voltammetry of glassy carbon-bound tetra(aminophenyl)porphyrins
John C. Lennox and Royce W. Murray
pp 3710 - 3714; DOI:
10.1021/ja00480a009
PDF
Optically active amines. 24. Circular dichroism of the para-substituted benzene chromophore
Howard E. Smith, Elizabeth P. Burrows, and Fu-Ming Chen
pp 3714 - 3720; DOI:
10.1021/ja00480a010
PDF
Line intensity ratios in electron spin resonance spectra. A remarkable change accompanying saturation
G. Brunton, D. Forrest, D. Griller, K. U. Ingold, and A. H. Reddoch
pp 3721 - 3723; DOI:
10.1021/ja00480a011
PDF
Studies of the pH dependence of carbon-13 shifts and carbon-carbon coupling constants of [U-13C]aspartic and -glutamic acids
Robert E. London, Thomas E. Walker, Victor H. Kollman, and N. A. Matwiyoff
pp 3723 - 3729; DOI:
10.1021/ja00480a012
PDF
Photoelectron and ultraviolet spectra of small-ring fused aromatic molecules as probes of aromatic ring distortions
Cielo Santiago, Ruth Wells Gandour, K. N. Houk, Wutichai Nutakul, Wesley E. Cravey, and Randolph P. Thummel
pp 3730 - 3737; DOI:
10.1021/ja00480a013
PDF
Acid-base properties of 1-methyl-1,4-dihydroborabenzene, CH3BC5H6
S. A. Sullivan, H. Sandford, J. L. Beauchamp, and A. J. Ashe
pp 3737 - 3742; DOI:
10.1021/ja00480a014
PDF
Resonance Raman investigations of cytochrome P450CAM from Pseudomonas putida
P. M. Champion, I. C. Gunsalus, and G. C. Wagner
pp 3743 - 3751; DOI:
10.1021/ja00480a015
PDF
Microwave, infrared, and Raman spectra, conformation, dipole moment, and vibrational assignment of ethyldifluoroborane
J. D. Odom, Y. S. Li, E. J. Stampf, and J. R. Durig
pp 3751 - 3757; DOI:
10.1021/ja00480a016
PDF
Synthesis of closo- and nido-metalloboranes from metallocenes
R. N. Leyden, B. P. Sullivan, R. T. Baker, and M. F. Hawthorne
pp 3758 - 3765; DOI:
10.1021/ja00480a017
PDF
Detection of chlorothioborine, C1B:S, a new unstable triatomic molecule, by photoelectron and microwave spectroscopy
C. Kirby, H. W. Kroto, and N. P. C. Westwood
pp 3766 - 3768; DOI:
10.1021/ja00480a018
PDF
Organic metals. Systematic molecular modifications of hexamethylenetetraheterofulvalene donors
Edward M. Engler, Vishnu V. Patel, Jan R. Andersen, Robert R. Schumaker, and Alice A. Fukushima
pp 3769 - 3776; DOI:
10.1021/ja00480a019
PDF
Oxygen-17 magnetic resonance study of oxygen exchange between arsenite ion and solvent water
William C. Copenhafer and Philip H. Rieger
pp 3776 - 3780; DOI:
10.1021/ja00480a020
PDF
Natural solid state optical activity of tris(ethylenediamine)metal(II) nitrates. 4. Optical activity of tris(ethylenediamine)zinc(II) nitrate and assignment of the lowest electronic transition in nitrate(1-) ion
Richard Alan Palmer and Mark Chin-Lan Yang
pp 3780 - 3784; DOI:
10.1021/ja00480a021
PDF
Relationship of cis-diammineplatinum .alpha.-pyridone blue to other platinum blues. An x-ray photoelectron study
J. K. Barton, S. A. Best, S. J. Lippard, and R. A. Walton
pp 3785 - 3788; DOI:
10.1021/ja00480a022
PDF
Molecular and electronic structure of tetraallyldirhenium
F. Albert Cotton and Michael W. Extine
pp 3788 - 3792; DOI:
10.1021/ja00480a023
PDF
Multiple metal-carbon bonds. 9. Preparation and characterization of several alkylidene complexes, M(.eta.5-C5H5)2(alkylidene)X (M = tantalum or niobium), and the x-ray structure of Ta(.eta.5-C5H5)2(CHC6H5)(CH2C6H5). An investigation of alkylidene ligand rotation
Richard R. Schrock, Louis W. Messerle, Clayton D. Wood, and Lloyd J. Guggenberger
pp 3793 - 3800; DOI:
10.1021/ja00480a024
PDF
A dichlorine to oxide ion charge-transfer complex. Oxidation of hexasilver to silver chloride by dichlorine. Crystal structure of H2.25Ag12Cl2.25Si12Al12O48.6Cl2, a chlorine sorption complex of partially dehydrated fully silver(1+) ion-exchanged zeolite A
Yang Kim and Karl Seff
pp 3801 - 3805; DOI:
10.1021/ja00480a025
PDF
Experimental evidence for trapped valences in the mixed-valence complex .mu.-pyrazine-bis(pentaammineruthenium) tosylate. Electron paramagnetic resonance, magnetic susceptibility, and nuclear magnetic resonance results
Bruce C. Bunker, Russell S. Drago, David N. Hendrickson, Robert M. Richman, and Stephen L. Kessell
pp 3805 - 3814; DOI:
10.1021/ja00480a026
PDF
The molybdenum site of nitrogenase. 2. A comparative study of molybdenum-iron proteins and the iron-molybdenum cofactor by x-ray absorption spectroscopy
Stephen P. Cramer, William O. Gillum, Keith O. Hodgson, Leonard E. Mortenson, Edward I. Stiefel, John R. Chisnell, Winston J. Brill, and Vinod K. Shah
pp 3814 - 3819; DOI:
10.1021/ja00480a027
PDF
The photochemistry of 2-vinylstilbenes. 2. Photoreactions of 2-vinyl- and 2-propenylstilbene and of o-substitution products
M. Sindler-Kulyk and W. H. Laarhoven
pp 3819 - 3830; DOI:
10.1021/ja00480a028
PDF
Mechanisms of ionic reactions in the gas phase. Displacement reactions at carbonyl carbon
James K. Pau, Jhong K. Kim, and Marjorie C. Caserio
pp 3831 - 3837; DOI:
10.1021/ja00480a029
PDF
Mechanisms of ionic reactions in the gas phase. Formation, rearrangement, and fragmentation of oxygen-, sulfur- and nitrogen-stabilized carbocations. High-order hydride shifts
James K. Pau, Jhong K. Kim, and Marjorie C. Caserio
pp 3838 - 3846; DOI:
10.1021/ja00480a030
PDF
Structural changes in 2-arylnorbornyl and other aryl carbocations with increasing electron demand. Carbon-13 nuclear magnetic resonance as a probe
Donald G. Farnum, Robert E. Botto, William T. Chambers, and Bing Lam
pp 3847 - 3855; DOI:
10.1021/ja00480a031
PDF
A test for "wrong-bond" rupture in the thermal structural isomerization of phenylcyclopropane and a confirmation of the two-center epimerization mechanism in its stereomutation
John T. Wood, Jonathan S. Arney, David Cortes, and Jerome A. Berson
pp 3855 - 3860; DOI:
10.1021/ja00480a032
PDF
Excess acidities. A generalized method for the determination of basicities in aqueous acid mixtures
Robin A. Cox and Keith Yates
pp 3861 - 3867; DOI:
10.1021/ja00480a033
PDF
An electron paramagnetic resonance study of free-radical additions to trithiocarbonates and of the formation and destruction of tetrathiafulvalene by free-radical processes
D. Forrest and K. U. Ingold
pp 3868 - 3873; DOI:
10.1021/ja00480a034
PDF
The stereochemistry of free-radical eliminations on .beta.-phenylsulfinyl radicals
Thomas E. Boothe, Joseph L. Greene, Philip B. Shevlin, M. Robert Willcott, Ruth R. Inners, and Andre Cornelis
pp 3874 - 3879; DOI:
10.1021/ja00480a035
PDF
Phase transition autocatalysis of the hydrolysis of some esters of azo dyes
Richard L. Reeves, Shelley A. Harkaway, and Richard T. Klingbiel
pp 3879 - 3881; DOI:
10.1021/ja00480a036
PDF
Steric and electronic effects on nitrogen-15 chemical shifts of piperidine and decahydroquinoline hydrochlorides
Rudolf O. Duthaler and John D. Roberts
pp 3882 - 3889; DOI:
10.1021/ja00480a037
PDF
Steric and electronic effects on nitrogen-15 chemical shifts of saturated aliphatic amines and their hydrochlorides
Rudolf O. Duthaler and John D. Roberts
pp 3889 - 3895; DOI:
10.1021/ja00480a038
PDF
Amine quenching of aromatic fluorescence and fluorescent exciplexes
Shui-Pong Van and George S. Hammond
pp 3895 - 3902; DOI:
10.1021/ja00480a039
PDF
Use of a guest amino acid for the complete proton nuclear magnetic resonance assignments of blocked linear methionine homooligopeptides
Anthony A. Ribeiro, Murray Goodman, and Fred Naider
pp 3903 - 3907; DOI:
10.1021/ja00480a040
PDF
Role of the pyrimidine base in ribonuclease A hydrolysis of RNA. Determination of the conformation of cyclic .beta.-cytidine 2',3'-phosphate and cyclic .beta.-uridine 2',3'-phosphate in solution
David K. Lavallee and Ray B. Myers
pp 3907 - 3912; DOI:
10.1021/ja00480a041
PDF
Carbon-13 NMR conformational studies of oxytocin analogs with a prolyl residue in position 3
Roxanne Deslauriers, Ian C. P. Smith, George C. Levy, Ronald Orlowski, and Roderich Walter
pp 3912 - 3918; DOI:
10.1021/ja00480a042
PDF
Models for metal binding sites in zinc enzymes. Syntheses of tris[4(5)-imidazolyl]carbinol (4-TIC), tris(2-imidazolyl)carbinol (2-TIC), and related ligands, and studies on metal complex binding constants and spectra
Chaucer C. Tang, Dariush Davalian, Paul Huang, and Ronald Breslow
pp 3918 - 3922; DOI:
10.1021/ja00480a043
PDF
Interactions of melanin with metal ions. Electron spin resonance evidence for chelate complexes of metal ions with free radicals
C. C. Felix, J. S. Hyde, T. Sarna, and R. C. Sealy
pp 3922 - 3926; DOI:
10.1021/ja00480a044
PDF
Transition-state structures in sulfoxide and amine oxide thermolysis
Harold Kwart, Thomas J. George, Robert Louw, and Willem Ultee
pp 3927 - 3928; DOI:
10.1021/ja00480a045
PDF
Photochemical transformations of small ring compounds. 98. Hydrogen atom transfer reactions in the photochemistry of tetrasubstituted cyclopropenes
Albert Padwa, Ugo Chiacchio, and Naoto Hatanaka
pp 3928 - 3930; DOI:
10.1021/ja00480a046
PDF
A total synthesis of racemic and optically active ibogamine. Utilization and mechanism of a new silver ion assisted palladium catalyzed cyclization
Barry M. Trost, Stephen A. Godleski, and Jean P. Genet
pp 3930 - 3931; DOI:
10.1021/ja00480a047
PDF
Interaction between orthogonal magnetic orbitals in a copper(II)-oxovanadium(II) heterobinuclear complex
O. Kahn, P. Tola, J. Galy, and H. Coudanne
pp 3931 - 3933; DOI:
10.1021/ja00480a048
PDF
Total synthesis of nocardicin A. Synthesis of 3-ANA and nocardicin A
G. A. Koppel, L. McShane, F. Jose, and R. D. G. Cooper
pp 3933 - 3935; DOI:
10.1021/ja00480a049
PDF
Cyclic peroxides. 68. Mercuric trifluoroacetate catalyzed decomposition of an allylic hydroperoxide via a mercury-substituted 1,2-dioxetane
Waldemar Adam and Katsumasa Sakanishi
pp 3935 - 3936; DOI:
10.1021/ja00480a050
PDF
A low spin manganocene and its novel anionic derivative. Synthesis and characterization of decamethylmanganocene complexes
James C. Smart and John L. Robbins
pp 3936 - 3937; DOI:
10.1021/ja00480a051
PDF
Biosynthesis of the nucleoside skeleton of polyoxins
Kiyoshi Isono, Tsutomu Sato, Kiyoshi Hirasawa, Shunji Funayama, and Saburo Suzuki
pp 3937 - 3939; DOI:
10.1021/ja00480a052
PDF
Bis(pentamethylcyclopentadienyl)actinide chemistry: properties of stable thorium and uranium dialkyls and hydrides
Juan M. Manriquez, Paul J. Fagan, and Tobin J. Marks
pp 3939 - 3941; DOI:
10.1021/ja00480a053
PDF
Activation of water molecule. 1. Intermediates bearing on the water gas shift reaction catalyzed by platinum(0) complexes
Toshikatsu Yoshida, Yasuhiko Ueda, and Sei Otsuka
pp 3941 - 3942; DOI:
10.1021/ja00480a054
PDF
Complete kinetic analysis of thermal stereomutations of (+)-(1S,2S,3S)-r-1-cyano-t-2-phenyl-1,c-3-dideuteriocyclopropane
John E. Baldwin and Charles G. Carter
pp 3942 - 3944; DOI:
10.1021/ja00480a055
PDF
Generation of singlet oxygen in the reaction of superoxide anion radical with diacyl peroxides
Wayne C. Danen and Ravindra L. Arudi
pp 3944 - 3945; DOI:
10.1021/ja00480a056
PDF
SN2' reactions of cis-3,4-dichlorocyclobutene
Wolfgang Kirmse, Friedrich Scheidt, and Hans Joachim Vater
pp 3945 - 3946; DOI:
10.1021/ja00480a057
PDF
Novel route to iron-carbene complexes via .eta.2-carbon disulfide derivatives. 1,3-Dithiolium species as precursors for dithiolene-iron complexes and tetrathiafulvalenes
H. Le Bozec, A. Gorgues, and P. H. Dixneuf
pp 3946 - 3947; DOI:
10.1021/ja00480a058
PDF
Kinetic analysis and solvent polarity effects on the ylide-forming photocyclization reaction of 1-vinyl-2-pyridones
Patrick S. Mariano and Andrea A. Leone
pp 3947 - 3949; DOI:
10.1021/ja00480a059
PDF
Metal-assisted terpenoid syntheses. 6. Enantioselective hydrogen migration in prochiral allylamine systems by chiral cobalt catalysts
Hidenori Kumobayashi, Susumu Akutagawa, and Sei Otsuka
pp 3949 - 3950; DOI:
10.1021/ja00480a060
PDF
Stereoselective epoxidation of acyclic olefinic carboxylic acids via iodolactonization
Paul A. Bartlett and Joel Myerson
pp 3950 - 3952; DOI:
10.1021/ja00480a061
PDF
Photochemistry of carbanions. 1. Photoalkylation of resonance-stabilized carbanions in dimethyl sulfoxide
Laren M. Tolbert
pp 3952 - 3953; DOI:
10.1021/ja00480a062
PDF
An iron-bridged diborane(6) derivative. Preparation of K+[.mu.-Fe(CO)4B2H5-]
George Medford and Sheldon G. Shore
pp 3953 - 3954; DOI:
10.1021/ja00480a063
PDF
The new cluster dianion dodecacarbonyldihydrotetraruthenate(2-). Simple, high-yield, stepwise deprotonation of dodecacarbonyltetrahydrotetraruthenium
Kenneth E. Inkrott and Sheldon G. Shore
pp 3954 - 3955; DOI:
10.1021/ja00480a064
PDF
Matrix infrared spectrum of the O2Br radical. Bonding in the O2X species
D. E. Tevault and R. R. Smardzewski
pp 3955 - 3957; DOI:
10.1021/ja00480a065
PDF
Dynamics of tautomerization of formycin
Francis X. Cole and Paul R. Schimmel
pp 3957 - 3958; DOI:
10.1021/ja00480a066
PDF
Synthesis and aromatization of 2-carboxy- and 2-carbomethoxyoxepin-benzene oxide
Derek R. Boyd and Glenn A. Berchtold
pp 3958 - 3959; DOI:
10.1021/ja00480a067
PDF
Interpretation of the microwave dielectric relaxation of iron pentacarbonyl in terms of the molecule's fluxional nature
E. N. DiCarlo and E. P. Zurbach
pp 3959 - 3961; DOI:
10.1021/ja00480a068
PDF
Solvent effects on protomeric equilibriums: quantitative correlation with an electrostatic hydrogen-bonding model
Peter Beak and Johnny B. Covington
pp 3961 - 3963; DOI:
10.1021/ja00480a069
PDF
Sphingolipid base metabolism. Concerning the origin of the oxygen atom at carbon atom 4 of phytosphingosine
R. J. Kulmacz and G. J. Schroepfer
pp 3963 - 3964; DOI:
10.1021/ja00480a070
PDF
Optical rotatory dispersion studies. 123. Experimental evidence for preference of axial deuterium over axial hydrogen
Shy-Fuh Lee, Guenter Barth, Klaus Kieslich, and Carl Djerassi
pp 3965 - 3966; DOI:
10.1021/ja00480a071
PDF
A facile route to the [4.1.1]propellane system
Ursula Szeimies-Seebach and Guenter Szeimies
pp 3966 - 3967; DOI:
10.1021/ja00480a072
PDF
Metal ion binding to cytidine in solution. Compelling Raman and carbon-13 nuclear magnetic resonance spectral evidence for coordination to the exocyclic oxygen at position 2
Luigi G. Marzilli, Robert Charles Stewart, C. P. Van Vuuren, Baltazar De Castro, and John P. Caradonna
pp 3967 - 3968; DOI:
10.1021/ja00480a073
PDF
Production of hydrogen from interaction of an anion radical and water. Comment
H. C. Wang, G. Levin, and M. Szwarc
pp 3969 - 3969; DOI:
10.1021/ja00480a074
PDF
Catalytic reductions using carbon monoxide and water in place of hydrogen. 2. Reduction of aromatic nitro compounds to amines
K. Cann, T. Cole, W. Slegeir, and R. Pettit
pp 3969 - 3971; DOI:
10.1021/ja00480a075
PDF
Stabilizing effect of dangling bases on a short RNA double helix as determined by proton nuclear magnetic resonance spectroscopy
Paul J. Romaniuk, Donald W. Hughes, Rene J. Gregoire, Thomas Neilson, and Russell A. Bell
pp 3971 - 3972; DOI:
10.1021/ja00480a076
PDF
Reversible binding of dioxygen, nitric oxide, and carbon monoxide by bis(3,5-di-tert-butylcatecholato)vanadium(IV)
John P. Wilshire and Donald T. Sawyer
pp 3972 - 3973; DOI:
10.1021/ja00480a077
PDF
Synthesis of a tetraketone of the tetracyclo[5.5.1.04,13.010,13]tridecane ("staurane") series
R. Mitschka, J. M. Cook, and U. Weiss
pp 3973 - 3974; DOI:
10.1021/ja00480a078
PDF
Book Reviews

pp 3975 - 3980; DOI:
10.1021/ja00480a600
PDF

Issue 13


Conformations, stabilities, and charge distributions in 2- and 3-monosubstituted furans. An ab initio molecular orbital study
Ian G. John and Leo Radom
pp 3981 - 3991; DOI:
10.1021/ja00481a001
PDF
Hydrogen bonding in pure and aqueous formamide
A. Pullman, H. Berthod, C. Giessner-Prettre, J. F. Hinton, and D. Harpool
pp 3991 - 3994; DOI:
10.1021/ja00481a002
PDF
Application of the multiple scattering X.alpha. molecular orbital method to the determination of the electronic structure of metallocene compounds. 1. Dibenzenechromium and its cation
Jacques Weber, Michel Geoffroy, Annick Goursot, and Edouard Penigault
pp 3995 - 4003; DOI:
10.1021/ja00481a003
PDF
Conformational analysis of bridgehead diazadecalin derivatives by carbon-13 nuclear magnetic resonance
Stephen F. Nelsen and Edward L. Clennan
pp 4004 - 4012; DOI:
10.1021/ja00481a004
PDF
Low-temperature cyclic voltammetry. 3. Quantitative comparison of cyclic voltammetry and nuclear magnetic resonance as methods for conformational equilibrium and rate constant measurements
Stephen F. Nelsen, Edward L. Clennan, and Dennis H. Evans
pp 4012 - 4019; DOI:
10.1021/ja00481a005
PDF
Investigation and parametrization of a molecular dielectric function
David A. Greenberg, C. David Barry, and Garland R. Marshall
pp 4020 - 4026; DOI:
10.1021/ja00481a006
PDF
Basis set dependence of spatial electron distribution. Implications for calculated conformational equilibriums
A. T. Hagler and A. Lapiccirella
pp 4026 - 4029; DOI:
10.1021/ja00481a007
PDF
Circular dichroic power due to chiral exciton coupling between two polyacene chromophores
Nobuyuki Harada, Yuki Takuma, and Hisashi Uda
pp 4029 - 4036; DOI:
10.1021/ja00481a008
PDF
Experimental and theoretical studies on the magnetic circular dichroism of azanaphthalenes. Use of the CNDO/S-CI approximation
Akira Kaito and Masahiro Hatano
pp 4037 - 4044; DOI:
10.1021/ja00481a009
PDF
Hyperfine coupling in chlorophyll radical cations. A nuclear magnetic resonance approach
John C. Waterton and Jeremy K. M. Sanders
pp 4044 - 4049; DOI:
10.1021/ja00481a010
PDF
Nuclear magnetic resonance studies of rigid bicyclic systems. 6. Angular dependence of vicinal nitrogen-14-proton spin couplings in bicyclic ammonium salts
Marc J. O. Anteunis, Frans A. M. Borremans, Jan Gelan, Alan P. Marchand, and Robert W. Allen
pp 4050 - 4055; DOI:
10.1021/ja00481a011
PDF
Proton and carbon-13 nuclear magnetic resonance studies of the conformational dynamic properties of seven-membered rings. 2,4-Benzodioxepin and its derivatives
A. Blanchette, F. Sauriol-Lord, and M. St.-Jacques
pp 4055 - 4062; DOI:
10.1021/ja00481a012
PDF
Electron-impact and field-ionization mass spectrometry of .alpha.-ketol phosphate salts. Gas-phase thermolysis of phosphodiester to monomeric alkyl metaphosphate. Appearance and origins of original salt cations in mass spectra
Seymour Meyerson, Eugene S. Kuhn, Fausto Ramirez, James F. Marecek, and Hiroshi Okazaki
pp 4062 - 4067; DOI:
10.1021/ja00481a013
PDF
The reactions of sulfur atoms. 15. Absolute rate parameters for the sulfur(3P2,1,0) + alkyne reactions
A. Van Roodselaar, I. Safarik, O. P. Strausz, and H. E. Gunning
pp 4068 - 4073; DOI:
10.1021/ja00481a014
PDF
Induction and inhibition of chemical oscillations by iodide ion in the Belousov-Zhabotinskii reaction
Robert J. Kaner and Irving R. Epstein
pp 4073 - 4079; DOI:
10.1021/ja00481a015
PDF
The chemistry of 2-naphthyl bis[bis(dimethylphosphino)ethane] hydride complexes of iron, ruthenium, and osmium. 1. Characterization and reactions with hydrogen and Lewis base ligands
C. A. Tolman, S. D. Ittel, A. D. English, and J. P. Jesson
pp 4080 - 4089; DOI:
10.1021/ja00481a016
PDF
Molybdenum enzyme model studies. Synthesis and structure of the oxo-bridged binuclear complex, .mu.-oxo-bis[oxo(2,2'-methyliminodiethanethiolato)molybdenum(V)], Mo2O3[NCH3(C2H4S)2]2
Ying-Yen P. Tsao, Charles J. Fritchie, and Henri A. Levy
pp 4089 - 4095; DOI:
10.1021/ja00481a017
PDF
Photochemical substitution reactions of decacarbonyldimanganese
Dennis R. Kidd and Theodore L. Brown
pp 4095 - 4103; DOI:
10.1021/ja00481a018
PDF
Formation and properties of substituted manganese carbonyl radicals
Dennis R. Kidd, C. P. Cheng, and Theodore L. Brown
pp 4103 - 4107; DOI:
10.1021/ja00481a019
PDF
Metal clusters in catalysis. 15. A structural and chemical study of a dinuclear metal complex, hexacarbonylbis(.eta.3-2-propenyl)diiron(Fe-Fe)
Charles F. Putnik, James J. Welter, Galen D. Stucky, M. J. D'Aniello, B. A. Sosinsky, J. F. Kirner, and E. L. Muetterties
pp 4107 - 4116; DOI:
10.1021/ja00481a020
PDF
Photodissociation of molecular beams. Cleavage of metal-metal bonds in rhenium and manganese decacarbonyl
Andrew Freedman and Richard Bersohn
pp 4116 - 4118; DOI:
10.1021/ja00481a021
PDF
The solution behavior of unsaturated molybdenum carbonyl species as evidenced via stereospecific carbon-13 monoxide labeling studies
Donald J. Darensbourg and Albrecht Salzer
pp 4119 - 4124; DOI:
10.1021/ja00481a022
PDF
Metal-stabilized carbonium ions derived from bis(tricarbonylchromium) complexes of diarylmethanes
Dietmar Seyferth, Joseph S. Merola, and C. Scott Eschbach
pp 4124 - 4131; DOI:
10.1021/ja00481a023
PDF
Control of regioselectivity and excited singlet reaction rates by substitution in the di-.pi.-methane rearrangement. Mechanistic and exploratory photochemistry
Howard E. Zimmerman and Thomas R. Welter
pp 4131 - 4145; DOI:
10.1021/ja00481a024
PDF
The aryl vinyl methane version of the di-.pi.-methane rearrangement. Mechanistic and exploratory organic photochemistry
Howard E. Zimmerman, Mark G. Steinmetz, and Curtis L. Kreil
pp 4146 - 4162; DOI:
10.1021/ja00481a025
PDF
Photochemical electron-transfer and triplet reactions of 1,2-diphenylcyclopropene-3-carboxylate
Katherine A. Brown-Wensley, Susan L. Mattes, and Samir Farid
pp 4162 - 4172; DOI:
10.1021/ja00481a026
PDF
Intramolecular donor-acceptor systems. 3. A third type of emitting singlet state for N-alkyl-6-N-arylamino-2-naphthalenesulfonates. Solvent modulation of substituent effects on charge-transfer emissions
Edward M. Kosower and Hanna Dodiuk
pp 4173 - 4179; DOI:
10.1021/ja00481a027
PDF
Intramolecular donor-acceptor system. 4. Solvent effects on radiative and nonradiative processes for the charge-transfer states of N-arylaminonaphthalenesulfonates
Edward M. Kosower, Hanna Dodiuk, and Hanna Kanety
pp 4179 - 4188; DOI:
10.1021/ja00481a028
PDF
Friedel-Crafts isopropylation of a bituminous coal under remarkably mild conditions
Richard H. Schlosberg, Martin L. Gorbaty, and Thomas Aczel
pp 4188 - 4190; DOI:
10.1021/ja00481a029
PDF
Reactions of cation radicals of EE systems. 7. Mechanistic considerations and relative reactivities of nucleophiles in reaction with the cation radical of 9,10-diphenylanthracene
John F. Evans and Henry N. Blount
pp 4191 - 4196; DOI:
10.1021/ja00481a030
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 32. Further studies of quantum-mechanical tunneling in the isomerization of sterically hindered aryl radicals
G. Brunton, Jean A. Gray, D. Griller, L. R. C. Barclay, and K. U. Ingold
pp 4197 - 4200; DOI:
10.1021/ja00481a031
PDF
Dynamics and mechanism of the plasmolysis of anisole
Meguru Tezuka and Larry L. Miller
pp 4201 - 4208; DOI:
10.1021/ja00481a032
PDF
Synthesis of parazoanthoxanthins and pseudozoanthoxanthins
Manfred Braun, George Buechi, and Dean F. Bushey
pp 4208 - 4213; DOI:
10.1021/ja00481a033
PDF
Biomimetic transformations among monomeric macroline-related indole alkaloids
Robert L. Garnick and Philip W. Le Quesne
pp 4213 - 4219; DOI:
10.1021/ja00481a034
PDF
Total synthesis of indole and dihydroindole alkaloids. 14. A total synthesis of vindoline
James P. Kutney, Ursula Bunzli-Trepp, Ka Kong Chan, Joao P. De Souza, Yutaka Fujise, Toshio Honda, Junki Katsube, Frederick K. Klein, Albert Leutwiler, and et al.
pp 4220 - 4224; DOI:
10.1021/ja00481a035
PDF
Acyl tetramic acids. 6. Synthesis of 3-dienoyl tetramic acids related to streptolydigin and tirandamycin
Ving J. Lee, Alan R. Branfman, Thomas R. Herrin, and Kenneth L. Rinehart
pp 4225 - 4236; DOI:
10.1021/ja00481a036
PDF
3-acyl tetramic acids. 7. Synthesis of 3-acyl tetramic acids via aspartimide rearrangement
David Cartwright, Ving J. Lee, and Kenneth L. Rinehart
pp 4237 - 4239; DOI:
10.1021/ja00481a037
PDF
The dynamics of cryptand protonation
Richard Pizer
pp 4239 - 4241; DOI:
10.1021/ja00481a038
PDF
On the electron-donating properties of oxygen vs. sulfur. A study of the gas-phase ion chemistry of methoxymethylthioalkanes
James K. Pau, Michael B. Ruggera, Jhong K. Kim, and Marjorie C. Caserio
pp 4242 - 4248; DOI:
10.1021/ja00481a039
PDF
Electron transfer to and from molecules containing multiple, noninteracting redox centers. Electrochemical oxidation of poly(vinylferrocene)
James B. Flanagan, Shlomo Margel, Allen J. Bard, and Fred C. Anson
pp 4248 - 4253; DOI:
10.1021/ja00481a040
PDF
A MINDO/3 investigation of cyclic chloronium ion-chloroalkyl carbocation equilibriums. Comparisons with stable ion solution chemistry
Samuel D. Beatty, S. D. Worley, and Samuel P. McManus
pp 4254 - 4260; DOI:
10.1021/ja00481a041
PDF
Cycloaddition of diazoalkanes to penta- and hexafluoroacetones. Isolation of .DELTA.3-1,3,4-oxadiazolines and their decomposition via carbonyl ylides
Nobujiro Shimizu and Paul D. Bartlett
pp 4260 - 4267; DOI:
10.1021/ja00481a042
PDF
Acetylenic bond participation in biomimetic polyene cyclizations. Preliminary model studies
Michael B. Gravestock, William S. Johnson, Robert F. Myers, Thomas A. Bryson, D. Howard Miles, and Bruce E. Ratcliffe
pp 4268 - 4273; DOI:
10.1021/ja00481a043
PDF
Acetylenic bond participation in biomimetic polyene cyclizations. Model studies directed toward the synthesis of 20-keto steroids. Synthesis of dl-progesterone and dl-.DELTA.4-androstene-3,17-dione
Michael B. Gravestock, William S. Johnson, Brian E. McCarry, Ronald J. Parry, and Bruce E. Ratcliffe
pp 4274 - 4282; DOI:
10.1021/ja00481a044
PDF
Molecular structures of substrates and inhibitors of .DELTA.5-3-keto steroid isomerase and their relevance to the enzymic mechanism
H. L. Carrell, Jenny P. Glusker, Douglas F. Covey, F. H. Batzold, and C. H. Robinson
pp 4282 - 4289; DOI:
10.1021/ja00481a045
PDF
Conformation of cyclic peptides. 10. Conformational averaging in peptides with the sequence cyclo-(Gly-D-Xxx-L-Yyy)2
Kenneth D. Kopple, Anita Go, and Thomas J. Schamper
pp 4289 - 4295; DOI:
10.1021/ja00481a046
PDF
Binding of methotrexate to Escherichia coli dihydrofolate reductase as measured by visible and ultraviolet resonance Raman spectroscopy
David D. Saperstein, Alan J. Rein, Martin Poe, and Michael F. Leahy
pp 4296 - 4300; DOI:
10.1021/ja00481a047
PDF
Nonplanar structures of cyclobutadiene dications
Karsten Krogh-Jespersen, Paul von Rague Schleyer, John A. Pople, and Dieter Cremer
pp 4301 - 4302; DOI:
10.1021/ja00481a048
PDF
Acarnidines, novel antiviral and antimicrobial compounds from the sponge Acarnus erithacus (de Laubenfels)
Guy T. Carter and Kenneth L. Rinehart
pp 4302 - 4304; DOI:
10.1021/ja00481a049
PDF
On the structure of cyclobutadiene. Theoretical determination of its infrared spectrum
H. Kollmar and V. Staemmler
pp 4304 - 4305; DOI:
10.1021/ja00481a050
PDF
5-Fluorouracil-copper(II)-peptide ternary complex
Juan F. Villa, Joel Gelber, Ngarling Khoe, and Jose Cepeda
pp 4305 - 4307; DOI:
10.1021/ja00481a051
PDF
Enantiomer recognition and conformational equilibriums in platinum(0) complexes of 2,3-isopropylidene-2,3-trans-dihydroxy-1,4-bis(diphenylphosphino)butane (diop)
John M. Brown and Penny A. Chaloner
pp 4307 - 4309; DOI:
10.1021/ja00481a052
PDF
Anionic oxy-Cope rearrangements with aromatic substrates in bicyclo[2.2.1]heptene systems. Facile synthesis of cis-hydrindanone derivatives, including steroid analogs
Michael E. Jung and James P. Hudspeth
pp 4309 - 4311; DOI:
10.1021/ja00481a053
PDF
Thiocarbonyl complexes of iron(II) porphyrins. Formation by thiophosgene reduction
D. Mansuy, J. P. Battioni, and J. C. Chottard
pp 4311 - 4312; DOI:
10.1021/ja00481a054
PDF
Structural and chemical aspects of metal stabilized N-acyl isocyanide groups (MCNCOR)
P. Le Maux, G. Simonneaux, G. Jaouen, L. Ouahab, and P. Batail
pp 4312 - 4314; DOI:
10.1021/ja00481a055
PDF
Zinc-promoted one-step joining reaction of alkyl halides, activated olefins, and carbonyl compounds
Tatsuya Shono, Ikuzo Nishiguchi, and Manji Sasaki
pp 4314 - 4315; DOI:
10.1021/ja00481a056
PDF
On binding to transition states and ground states: remote catalysis
J. Rebek and J. E. Trend
pp 4315 - 4316; DOI:
10.1021/ja00481a057
PDF
Formation and rearrangement of ipso intermediates in aromatic free-radical chlorination reactions
Charles R. Everly and James G. Traynham
pp 4316 - 4317; DOI:
10.1021/ja00481a058
PDF
Heterogeneous photocatalytic preparation of supported catalysts. Photodeposition of platinum on titanium dioxide powder and other substrates
Bernhard Kraeutler and Allen J. Bard
pp 4317 - 4318; DOI:
10.1021/ja00481a059
PDF
Intramolecular antiferromagnetic exchange in tris(o-semiquinone) complexes of vanadium(III), chromium(III), and iron(III)
Robert M. Buchanan, Hartley H. Downs, William B. Shorthill, Cortlandt G. Pierpont, Stephen L. Kessel, and David N. Hendrickson
pp 4318 - 4320; DOI:
10.1021/ja00481a060
PDF
1,5-Methano[10]annulene. Synthesis and characterization of the 3-methoxy derivative
Lawrence T. Scott and William R. Brunsvold
pp 4320 - 4321; DOI:
10.1021/ja00481a061
PDF
A photochemically mediated [4C + 2C] annelation. Synthesis of (.+-.)-10-epijunenol
Paul A. Wender and John C. Lechleiter
pp 4321 - 4322; DOI:
10.1021/ja00481a062
PDF
Photodissociation of nitrogenous bases from hemochromes and kinetics of recombination of axial bases
M. Momenteau and D. Lavalette
pp 4322 - 4324; DOI:
10.1021/ja00481a063
PDF
Electron paramagnetic resonance spectra of carbalkoxycarbenes. Geometric isomerism in ground-state triplets
Richard S. Hutton and Heinz D. Roth
pp 4324 - 4325; DOI:
10.1021/ja00481a064
PDF
Exocyclic benzenes. Synthesis and properties of benzo[1,2-c:3,4-c':5,6-c'']trithiophene, a tristhiahexaradialene
Harold Hart and Michio Sasaoka
pp 4326 - 4327; DOI:
10.1021/ja00481a065
PDF
Book Reviews

pp 4328 - 4328; DOI:
10.1021/ja00481a600
PDF

Issue 14


Ab initio studies of the relative energetics of glycine and its zwitterion
Y. C. Tse, M. D. Newton, S. Vishveshwara, and J. A. Pople
pp 4329 - 4331; DOI:
10.1021/ja00482a001
PDF
Theoretical calculations of the hydrolysis energies of some "high-energy" molecules. 2. A survey of some biologically important hydrolytic reactions
David M. Hayes, George L. Kenyon, and Peter A. Kollman
pp 4331 - 4340; DOI:
10.1021/ja00482a002
PDF
Theoretical model for the conversion of an even .pi. orbital to an odd .pi. orbital system and its implication to vision
Himanshoo V. Navangul and Paul E. Blatz
pp 4340 - 4346; DOI:
10.1021/ja00482a003
PDF
Carbanions. 3. Nuclear magnetic resonance spectroscopic and theoretical study of homoaromaticity in cyclohexadienyl anions
George A. Olah, Gregorio Asensio, Herbert Mayr, and Paul v. R. Schleyer
pp 4347 - 4352; DOI:
10.1021/ja00482a004
PDF
Limitations of restricted open-shell self-consistent field calculations applied to molecules with multiple bonds. Electronic structure and geometry of the ground state of cyanocarbene
J. F. Harrison, A. Dendramis, and G. E. Leroi
pp 4352 - 4356; DOI:
10.1021/ja00482a005
PDF
Coupling constants between cisoidal protons in pentose nucleosides. Limitations of range of application of Karplus relation, and solution conformations of .beta.-arabinofuranosyl and .beta.-xylofuranosyl nucleosides
Andrzej Jaworski, Irena Ekiel, and David Shugar
pp 4357 - 4361; DOI:
10.1021/ja00482a006
PDF
Reactions of vibrationally excited ions. A theoretical and experimental analysis of the reaction (C4H9+)* + NH3 .fwdarw. NH4+ + C4H8
W. J. Chesnavich, T. Su, and M. T. Bowers
pp 4362 - 4366; DOI:
10.1021/ja00482a007
PDF
Three-electron .sigma. bonding in the radical cation from 1,3,6,8-tetraazatricyclo[4.4.1.13,8]dodecane
S. F. Nelsen, E. Haselbach, R. Gschwind, U. Klemm, and S. Lanyova
pp 4367 - 4368; DOI:
10.1021/ja00482a008
PDF
Extension of the Kirkwood-Westheimer model of substituent effects to general shapes, charges, and polarizabilities. Application to the substituted bicyclo[2.2.2]octanes
William H. Orttung
pp 4369 - 4375; DOI:
10.1021/ja00482a009
PDF
Adsorption, displacement, and ionization in water pools
F. M. Menger and G. Saito
pp 4376 - 4379; DOI:
10.1021/ja00482a010
PDF
Electrochemical and solid state studies of phthalocyanine thin film electrodes
Hiroyasu Tachikawa and Larry R. Faulkner
pp 4379 - 4385; DOI:
10.1021/ja00482a011
PDF
Water-soluble lanthanide porphyrins: shift reagents for aqueous solution
William DeW. Horrocks and Emmanuel G. Hove
pp 4386 - 4392; DOI:
10.1021/ja00482a012
PDF
Intervalence transfer in mixed-valence biferrocene ions
Michael J. Powers and Thomas J. Meyer
pp 4393 - 4398; DOI:
10.1021/ja00482a013
PDF
Intramolecular electron transfer in the N-hydroxyethylethylenediaminetriacetatovanadium(II,IV) binuclear ion
Frank J. Kristine and Rex E. Shepherd
pp 4398 - 4404; DOI:
10.1021/ja00482a014
PDF
Dynamics of monocapped octahedral [hydro(dicarbonyl)bis(bidentate phosphine)molybdenum])(1+) ions
S. Datta, B. Dezube, J. K. Kouba, and S. S. Wreford
pp 4404 - 4412; DOI:
10.1021/ja00482a015
PDF
Cavities in macrobicyclic ligands and complexation selectivity. Crystal structures of two cryptates, |Na+ .cntnd. 221|.cntdot.SCN- and |K+ .cntnd. 221|.cntdot.SCN-2
Francois Mathieu, Bernard Metz, Dino Moras, and Raymond Weiss
pp 4412 - 4416; DOI:
10.1021/ja00482a016
PDF
Manganese(II) porphyrin oxygen carriers. Equilibrium constants for the reaction of dioxygen with para-substituted meso-tetraphenylporphinatomanganese(II) complexes
Robert D. Jones, David A. Summerville, and Fred Basolo
pp 4416 - 4424; DOI:
10.1021/ja00482a017
PDF
Electrochemical oxidations of complexes of rhenium(II) containing metal-metal triple bonds. Synthesis and characterization of paramagnetic cations of the type [Re2X4(PR3)4]+, where X = chlorine or bromine, possessing metal-metal bonds of order 3.5
Patrick Brant, Dennis J. Salmon, and Richard A. Walton
pp 4424 - 4430; DOI:
10.1021/ja00482a018
PDF
Oxygen-17 nuclear magnetic resonance studies on bound water in manganese(II)-adenosine diphosphate
Mark S. Zetter, Grace Y. S. Lo, Harold W. Dodgen, and John P. Hunt
pp 4430 - 4436; DOI:
10.1021/ja00482a019
PDF
Hexafluoro-2-butyne-metal atom chemistry. Stable complexes, small organometallic clusters, and metal-acetylene telomers
Kenneth J. Klabunde, Thomas Groshens, Michael Brezinski, and William Kennelly
pp 4437 - 4440; DOI:
10.1021/ja00482a020
PDF
Interactions of nitrogen (N2+) and nitrosyl (NO+) ions with surfaces of graphite, diamond, teflon, and graphite monofluoride
J. Ashley Taylor, Gerald M. Lancaster, and J. Wayne Rabalais
pp 4441 - 4447; DOI:
10.1021/ja00482a021
PDF
Preparation and properties of dinitrogen-molybdenum complexes. 6. Syntheses and molecular structures of a five-coordinate molybdenum(0) complex Mo(CO)(Ph2PCH2CH2PPh2)2 and a related six-coordinate complex Mo(CO)(N2)(Ph2PCH2CH2PPh2)2.1/2C6H6
Maki Sato, Takashi Tatsumi, Teruyuki Kodama, Masanobu Hidai, Tokiko Uchida, and Yasuzo Uchida
pp 4447 - 4452; DOI:
10.1021/ja00482a022
PDF
Conformation of the choline phosphate zwitterion. Crystal and molecular structure of cyclopentylphosphorylcholine monohydrate, [(CH3)3N+CH2CH2O](c-C5H9O)P(O).lovin.O.H2O
Raghupathy Sarma, Fausto Ramirez, Poojappan Narayanan, Brian McKeever, Hiroshi Okazaki, and James F. Marecek
pp 4453 - 4458; DOI:
10.1021/ja00482a023
PDF
Structural studies of tetracyclines. Crystal and molecular structures of anhydrotetracycline hydrobromide monohydrate and 6-demethyl-7-chlorotetracycline hydrochloride trihydrate
Gus J. Palenik, M. Mathew, and R. Restivo
pp 4458 - 4464; DOI:
10.1021/ja00482a024
PDF
Structural studies of tetracyclines. Crystal and molecular structure of tetracycline-urea tetrahydrate
Gus J. Palenik and M. Mathew
pp 4464 - 4469; DOI:
10.1021/ja00482a025
PDF
Preparation, crystalline structure, and spectral properties of the fluorescent probe 4,4'-bis-1-phenylamino-8-naphthalenesulfonate
Fay J. Farris, Gregorio Weber, Chian C. Chiang, and Iain C. Paul
pp 4469 - 4474; DOI:
10.1021/ja00482a026
PDF
Chemistry of fluorenylidene at low temperatures
Robert A. Moss and Martin A. Joyce
pp 4475 - 4480; DOI:
10.1021/ja00482a027
PDF
Photochemical transformations of small-ring heterocyclic compounds. 99. 1,4-Substituent shifts in the photorearrangement of 2-hydroxymethyl-2H-azirine derivatives to N-Vinylimines
Albert Padwa, Per H. J. Carlsen, and Alan Tremper
pp 4481 - 4490; DOI:
10.1021/ja00482a028
PDF
Effects of pH in photoreduction by hydrazine
Shai Inbar and Saul G. Cohen
pp 4490 - 4495; DOI:
10.1021/ja00482a029
PDF
Chemiluminescence of diphenoyl peroxide. Chemically initiated electron exchange luminescence. A new general mechanism for chemical production of electronically excited states
Ja-Young Koo and Gary B. Schuster
pp 4496 - 4503; DOI:
10.1021/ja00482a030
PDF
Photochemistry of ketones in solution. 53. Stereospecific triplet-state photorearrangements of chiral 2-cyclohexenones: type A lumiketone rearrangement and phenyl migrations
David I. Schuster, Robert Hallam Brown, and Bruce M. Resnick
pp 4504 - 4512; DOI:
10.1021/ja00482a031
PDF
Differentiation of excited-state and biradical processes. Photochemistry of phenyl alkyl ketones in the presence of oxygen
R. D. Small and J. C. Scaiano
pp 4512 - 4519; DOI:
10.1021/ja00482a032
PDF
Hydrogen abstraction by tert-butoxy radicals. A laser photolysis and electron spin resonance study
H. Paul, R. D. Small, and J. C. Scaiano
pp 4520 - 4527; DOI:
10.1021/ja00482a033
PDF
A pulse radiolysis study of the triplet sensitized production of singlet oxygen: determination of energy transfer efficiencies
A. A. Gorman, G. Lovering, and M. A. J. Rodgers
pp 4527 - 4532; DOI:
10.1021/ja00482a034
PDF
Carbon acidity. 56. Equilibrium acidities of 4-methyl-, 4-ethyl-, and 4-isopropylbiphenyls with cesium cyclohexylamide
Andrew Streitwieser and Francois Guibe
pp 4532 - 4534; DOI:
10.1021/ja00482a035
PDF
Nuclear magnetic resonance studies of phosphorus inversion in and conformational analysis of cis- and trans-4-tert-butyl-1-phenylphosphorinane
G. D. Macdonell, K. D. Berlin, J. R. Baker, S. E. Ealick, Dick Van der Helm, and K. L. Marsi
pp 4535 - 4540; DOI:
10.1021/ja00482a036
PDF
Kinetics and mechanism of the reduction of chlorpromazine radical by ascorbic acid
Nina A. Klein and David L. Toppen
pp 4541 - 4543; DOI:
10.1021/ja00482a037
PDF
Interpolymeric reactions. The Fries rearrangement of acetoxy and benzyloxy derivatives of 4-hydroxy-3-nitrobenzylated polystyrene and 5-polystyrylmethyl-8-quinolinol
A. Warshawsky, R. Kalir, and A. Patchornik
pp 4544 - 4550; DOI:
10.1021/ja00482a038
PDF
Solvent effects on stacking. A kinetic and spectroscopic study of thionine association in aqueous alcohol solutions
T. G. Dewey, Paulette S. Wilson, and Douglas H. Turner
pp 4550 - 4554; DOI:
10.1021/ja00482a039
PDF
Host-guest complexation. 11. Survey of chiral recognition of amine and amino ester salts by dilocular bisdinaphthyl hosts
Evan P. Kyba, Joseph M. Timko, Lester J. Kaplan, Feike De Jong, George W. Gokel, and Donald J. Cram
pp 4555 - 4568; DOI:
10.1021/ja00482a040
PDF
Host-guest complexation. 12. Total optical resolution of amine and amino ester salts by chromatography
Lynn R. Sousa, G. D. Y. Sogah, Dale H. Hoffman, and Donald J. Cram
pp 4569 - 4576; DOI:
10.1021/ja00482a041
PDF
Thermodynamic studies of the cyclodextrin-accelerated cleavage of phenyl esters
Makoto Komiyama and Myron L. Bender
pp 4576 - 4579; DOI:
10.1021/ja00482a042
PDF
Studies on transfer ribonucleic acids and related compounds. 20. A new versatile ribooligonucleotide block with 2'-(o-nitrobenzyl) and 3'-phosphorodianilidate groups suitable for elongation of chains in the 3' and 5' directions
E. Ohtsuka, T. Tanaka, S. Tanaka, and M. Ikehara
pp 4580 - 4584; DOI:
10.1021/ja00482a043
PDF
Kinetic Studies on 1:1 Electron-Transfer Reactions Involving Blue Copper Proteins. 1. Evidence for an Unreactive Form of the Reduced Protein (pH<5) and for Protein-Complex Association in Reactions of Parsley (and Spinach) Plastocyanin
Michael G. Segal and A. Geoffrey Sykes
pp 4585 - 4592; DOI:
10.1021/ja00482a044
PDF
A new approach to the synthesis of tropolones: syntheses of colchicine and .beta.-dolabrin
David A. Evans, David J. Hart, and Peter M. Koelsch
pp 4593 - 4594; DOI:
10.1021/ja00482a045
PDF
Proton affinity of dichlorocarbene
P. Ausloos and S. G. Lias
pp 4594 - 4595; DOI:
10.1021/ja00482a046
PDF
Homogeneous catalysis of the water gas shift reaction by mixed-metal (iron/ruthenium) catalysts
Peter C. Ford, Robert G. Rinker, Charles Ungermann, Richard M. Laine, Vincent Landis, and Sergio A. Moya
pp 4595 - 4597; DOI:
10.1021/ja00482a047
PDF
Stereospecific synthesis of penicillins. Stereoelectronic control in the conversion of a peptide into a penicillin
Jack E. Baldwin and Michael A. Christie
pp 4597 - 4599; DOI:
10.1021/ja00482a048
PDF
Kinetics of the stereomutations of (+)-2-deuterio-3,7-dimethyl-7-methoxymethylcyclohepta-1,3,5-triene: one-centered epimerization at C(7) and [1,5] carbon migration with retention of configuration in a norcaradiene
John E. Baldwin and Bruce M. Broline
pp 4599 - 4600; DOI:
10.1021/ja00482a049
PDF
Fragmentation of butyrophenone ions
M. S. Kim, R. C. Dunbar, and F. W. McLafferty
pp 4600 - 4601; DOI:
10.1021/ja00482a050
PDF
Organic photochemistry with high energy (6.7 eV) photons: duality of carbene intermediates from cyclic olefins
R. Srinivasan and K. H. Brown
pp 4602 - 4603; DOI:
10.1021/ja00482a051
PDF
Two antiparallel tripeptide chains stabilized by an SS unit: S,S'-bis(Cbz-L-Ala-L-Cys-L-Ala-OMe) in chloroform solution
Norikazu Ueyama and Takeo Araki
pp 4603 - 4605; DOI:
10.1021/ja00482a052
PDF
Spontaneous polypeptide formation from amino acyl adenylates in surfactant aggregates
D. W. Armstrong, R. Seguin, C. J. McNeal, R. D. Macfarlane, and J. H. Fendler
pp 4605 - 4606; DOI:
10.1021/ja00482a053
PDF
A diborane(6) bridged diiron hexacarbonyl: preparation of B2H6Fe2(CO)6
Earl L. Andersen and Thomas P. Fehlner
pp 4606 - 4607; DOI:
10.1021/ja00482a054
PDF
A simple synthesis of sulfur substituted cyclopropanes. Effect of solvent and gegenion upon mechanism and product composition
R. Daniel Little and James R. Dawson
pp 4607 - 4609; DOI:
10.1021/ja00482a055
PDF
A stereoselective total synthesis of 14-hydroxymorphinans. Grewe approach
Ivo Monkovic, Carol Bachand, and Henry Wong
pp 4609 - 4610; DOI:
10.1021/ja00482a056
PDF
Regio- and stereoselective .gamma. substitution of allylic alcohols with alkyllithium compounds by using N,N-methylphenylaminotributylphosphonium iodide. Anti stereochemistry of SN2' reaction
Yoshio Tanigawa, Hiroyuki Ohta, Akio Sonoda, and Shunichi Murahashi
pp 4610 - 4612; DOI:
10.1021/ja00482a057
PDF
Electron spin resonance studies of sulfur-based donor heterocycles: sulfur-33 couplings
Fitzgerald B. Bramwell, Robert C. Haddon, Fred Wudl, Martin L. Kaplan, and James H. Marshall
pp 4612 - 4614; DOI:
10.1021/ja00482a058
PDF
Resonance Raman spectra of protocatechuate 3,4-dioxygenase. Evidence for coordination of tyrosine residue to ferric iron
Yoshitaka Tatsuno, Yukikazu Saeki, Masayoshi Iwaki, Toshiharu Yagi, Mitsuhiro Nozaki, Teizo Kitagawa, and Sei Otsuka
pp 4614 - 4615; DOI:
10.1021/ja00482a059
PDF
Catalytic hydrolysis of phenyl esters in aqueous didodecyldimethylammonium vesicles: remarkable rate difference between intra- and intervesicle reactions
Toyoki Kunitake and Tetsuo Sakamoto
pp 4615 - 4617; DOI:
10.1021/ja00482a060
PDF
Detection of carbon-13-nitrogen-15 coupled units in adenine derived from doubly labeled hydrogen cyanide or formamide
Hiroshi Yamada, Masaaki Hirobe, Kimio Higashiyama, Hiroshi Takahashi, and Kazuo T. Suzuki
pp 4617 - 4618; DOI:
10.1021/ja00482a061
PDF
Total synthesis of erythromycins. 3. Stereoselective routes to intermediates corresponding to C(1) to C(9) and C(10) to C(13) fragments of erythronolide B
E. J. Corey, Eugene J. Trybulski, Lawrence S. Melvin Jr., K. C. Nicolaou, John A. Secrist, Robert Lett, Peter W. Sheldrake, J. R. Falck, Daniel J. Brunelle, and et al.
pp 4618 - 4620; DOI:
10.1021/ja00482a062
PDF
Total synthesis of erythromycins. 4. Total synthesis of erythronolide B
E. J. Corey, Sunggak Kim, Sung-Eun Yoo, K. C. Nicolaou, Lawrence S. Melvin, Daniel J. Brunelle, J. R. Falck, Eugene J. Trybulski, Robert Lett, and Peter W. Sheldrake
pp 4620 - 4622; DOI:
10.1021/ja00482a063
PDF
Isocyanide insertion reactions. The role of isocyanide insertions in the metal assisted hydrogenation of isocyanides
Richard D. Adams and Nancy M. Golembeski
pp 4622 - 4623; DOI:
10.1021/ja00482a064
PDF
Tetrametallic nickel-boron clusters, (.eta.5-C5H5)4Ni4B4H4 and (.eta.5-C5H5)4Ni4B5H5. Synthesis of metalloboron cluster systems by transition metal aggregation on a small borane framework
James R. Bowser and Russell N. Grimes
pp 4623 - 4624; DOI:
10.1021/ja00482a065
PDF
Nickel-catalyzed addition of Grignard reagents to silylacetylenes. Synthesis of tetrasubstituted alkenes
Barry B. Snider, Michael Karras, and Robin S. E. Conn
pp 4624 - 4626; DOI:
10.1021/ja00482a066
PDF
First facile and convenient hydroboration reaction via a polyhedral borane. Implications regarding catalysis involving metalloboranes
B. J. Meneghelli and R. W. Rudolph
pp 4626 - 4627; DOI:
10.1021/ja00482a067
PDF
meso-Tetracarboranylporphyrins
R. C. Haushalter and R. W. Rudolph
pp 4628 - 4629; DOI:
10.1021/ja00482a068
PDF
Nature of naked-metal-cluster polyanions in solution. Evidence for (Sn9-xPbx)4-(x = 0-9) and tin-antimony clusters
R. W. Rudolph, W. L. Wilson, F. Parker, R. Craig Taylor, and D. C. Young
pp 4629 - 4630; DOI:
10.1021/ja00482a069
PDF
The molybdenum-iron-sulfur cluster complex [Mo2Fe6S9(SC2H5)8]3-. A synthetic approach to the molybdenum site in nitrogenase
Thomas E. Wolff, J. M. Berg, C. Warrick, Keith O. Hodgson, R. H. Holm, and R. B. Frankel
pp 4630 - 4632; DOI:
10.1021/ja00482a070
PDF
Generalized affinity chromatography: enzyme-sulfonamide conjugates can be isolated by adsorption on immobilized carbonic anhydrase
Rachel Horowitz and George M. Whitesides
pp 4632 - 4633; DOI:
10.1021/ja00482a071
PDF
Organic reactions of sulfur dioxide. 4. A facile regiospecific hydrogen-deuterium exchange in olefins. Consequence of the intermediacy of allylic sulfinic acids in the ene reaction of sulfur dioxide with double bonds
Divakar Masilamani and Milorad M. Rogic
pp 4634 - 4635; DOI:
10.1021/ja00482a072
PDF
Photochemical upconversion in the chlorophyll a water splitting light reaction: causative factors underlying the two-quanta/electron requirement in plant photosynthesis
L. Galloway, J. Roettger, D. R. Fruge, and F. K. Fong
pp 4635 - 4638; DOI:
10.1021/ja00482a073
PDF
Book Reviews

pp 4638 - 4642; DOI:
10.1021/ja00482a600
PDF

Issue 15


Nuclear magnetic resonance studies of chloride binding to proteins
Thomas Bull, Jan Erik Norne, Petur Reimarsson, and Bjorn Lindman
pp 4643 - 4647; DOI:
10.1021/ja00483a001
PDF
Alkali ion binding to aggregates of amphiphilic compounds studied by nuclear magnetic resonance chemical shifts
Hans Gustavsson and Bjorn Lindman
pp 4647 - 4654; DOI:
10.1021/ja00483a002
PDF
Sodium-23 nuclear magnetic resonance in polyanion solution. Correlation times and quadrupole coupling constants of sodium(+) bound to poly(methacrylic acid)
Hans Gustavsson, Bjorn Lindman, and Thomas Bull
pp 4655 - 4661; DOI:
10.1021/ja00483a003
PDF
Nitrogen-15 nuclear magnetic resonance spectroscopy. Differential rates of nitrogen-hydrogen proton-transfer reactions in phenylhydrazine
Issa Yavari and John D. Roberts
pp 4662 - 4664; DOI:
10.1021/ja00483a004
PDF
Characterization of anisotropic motion in fatty acid micelles by analysis of transverse relaxation in an AX2 nuclear spin system
James H. Prestegard and David M. Grant
pp 4664 - 4668; DOI:
10.1021/ja00483a005
PDF
The spatial configuration of a left-handed base stacked dinucleoside monophosphate
M. M. Dhingra, R. H. Sarma, S. Uesugi, and M. Ikehara
pp 4669 - 4673; DOI:
10.1021/ja00483a006
PDF
Electron photodetachment from cyclic enolate anions in the gas phase: electron affinities of cyclic enolate radicals
Albert H. Zimmerman, Robert L. Jackson, Bruce K. Janousek, and John I. Brauman
pp 4674 - 4676; DOI:
10.1021/ja00483a007
PDF
The water content of a micelle interior. The fjord vs. reef models
F. M. Menger, J. M. Jerkunica, and J. C. Johnston
pp 4676 - 4678; DOI:
10.1021/ja00483a008
PDF
Configuration interaction and the Woodward-Hoffmann rules. 2. Sigmatropic shifts
W. A. Seitz, T. L. Welsher, B. Yurke, and F. A. Matsen
pp 4679 - 4681; DOI:
10.1021/ja00483a009
PDF
Ab initio study of the benzene radical anion
Alan L. Hinde, Dieter Poppinger, and Leo Radom
pp 4681 - 4685; DOI:
10.1021/ja00483a010
PDF
Ab initio study of the conformations of vinyl mercaptan, methyl vinyl sulfide, and methyl allenyl sulfide
James Kao
pp 4685 - 4693; DOI:
10.1021/ja00483a011
PDF
Solvation of the proton by hydrogen cyanide and acetonitrile. Condensation of hydrogen cyanide with ions in the gas phase
Michael Meot-Ner
pp 4694 - 4699; DOI:
10.1021/ja00483a012
PDF
Normal and anomalous ring opening of 1-3-.eta.-pentaarylcyclobutenylpalladium complexes
Susan H. Taylor and Peter M. Maitlis
pp 4700 - 4710; DOI:
10.1021/ja00483a013
PDF
Crystal structures of [Pd{1-.eta.-C4(tolyl)4Ph}(Me2PhP)(acac)] and of [Pd{1:3,4-.eta.-C4(tolyl)4Ph}(S2CN-i-Pr2)], obtained by ring opening of cyclobutenylpalladium complexes
Pamela M. Bailey, Susan H. Taylor, and Peter M. Maitlis
pp 4711 - 4716; DOI:
10.1021/ja00483a014
PDF
Molecular structure and magnetic properties of .mu.-oxo-bis[4-chloro-2,6-pyridinedicarboxylatodiaquoiron(III)]tetrahydrate, [Cl-C7H2NO4(H2O)2Fe]2O.4H2O, a complex with linear Fe2O4+ unit
Chia Chih Ou, Ronald G. Wollmann, David N. Hendrickson, Joseph A. Potenza, and Harvey J. Schugar
pp 4717 - 4724; DOI:
10.1021/ja00483a015
PDF
A triad of homologous, air-stable compounds containing short, quadruple bonds between metal atoms of Group 6
F. Albert Cotton, Phillip E. Fanwick, Ron H. Niswander, and Janine C. Sekutowski
pp 4725 - 4732; DOI:
10.1021/ja00483a016
PDF
N-aminoporphyrins. Preparation and metal complexes. Structure of N-tosylamino-5,10,15,20-tetraphenylporphinatonickel(II)
H. J. Callot, B. Chevrier, and R. Weiss
pp 4733 - 4741; DOI:
10.1021/ja00483a017
PDF
X-ray photoelectron spectroscopy of porphyrins
J. P. Macquet, M. M. Millard, and T. Theophanides
pp 4741 - 4746; DOI:
10.1021/ja00483a018
PDF
Kinetics of alkali metal complex formation with cryptands in methanol
B. G. Cox, H. Schneider, and J. Stroka
pp 4746 - 4749; DOI:
10.1021/ja00483a019
PDF
Experimental and theoretical studies of Nin(C2H4)m. Synthesis, vibrational and electronic spectra, and generalized valence bond-configuration interaction studies. The metal atom chemistry and a localized bonding model for ethylene chemisorbed on bulk nickel
G. A. Ozin, W. J. Power, T. H. Upton, and W. A. Goddard
pp 4750 - 4760; DOI:
10.1021/ja00483a020
PDF
The chemical evolution of a nitrogenase model. 16. Reactions of the molybdenum-carbon bond in synthetic analogs of proposed organomolybdenum intermediates of reactions of nitrogenase with alternate substrates
G. N. Schrauzer, E. L. Moorehead, J. H. Grate, and L. Hughes
pp 4760 - 4765; DOI:
10.1021/ja00483a021
PDF
Lewis acid catalyzed [RFe(CO)4]- alkyl migration reactions. A mechanistic investigation
James P. Collman, Richard G. Finke, James N. Cawse, and John I. Brauman
pp 4766 - 4772; DOI:
10.1021/ja00483a022
PDF
Electron transfer quenching of nonemitting excited states of Ru(TPP)(py)2 and Ru(trpy)22+
Roger C. Young, Jeffrey K. Nagle, Thomas J. Meyer, and David G. Whitten
pp 4773 - 4778; DOI:
10.1021/ja00483a023
PDF
Electron spin resonance characterization of ground state triplet aryl cations substituted at the 4 position by dialkylamino groups
Alan Cox, Terence J. Kemp, David R. Payne, Martyn C. R. Symons, and Peter Pinot de Moira
pp 4779 - 4783; DOI:
10.1021/ja00483a024
PDF
An electron spin resonance study of the association of a surfactant nitroxyl radical with a cationic micelle using spin-intensity measurements and hyperfine structure analyses
C. L. Kwan, Samir Atik, and Lawrence A. Singer
pp 4783 - 4786; DOI:
10.1021/ja00483a025
PDF
Metal ion effects on intramolecular nucleophilic carboxyl group participation in amide and ester hydrolysis. Hydrolysis of N-(8-quinolyl)phthalamic acid and 8-quinolyl hydrogen glutarate
Thomas H. Fife and Vanessa Lum Squillacote
pp 4787 - 4793; DOI:
10.1021/ja00483a026
PDF
Lack of concertedness in the catalysis of the enolization of oxaloacetic acid by general acids and bases. Formation of a carbinolamine intermediate in the tertiary amine catalyzed enolization reaction
Paula Yurkanis Bruice and Thomas C. Bruice
pp 4793 - 4801; DOI:
10.1021/ja00483a027
PDF
Diethyl oxaloacetate. Nonconcerted general catalysis of enolization, tertiary amine catalyzed enolization via an addition-elimination mechanism, and general-acid-catalyzed dehydration and cleavage
Paula Yurkanis Bruice and Thomas C. Bruice
pp 4802 - 4808; DOI:
10.1021/ja00483a028
PDF
Reduction of dehydromethionine by thiols. Kinetics and mechanism
David O. Lambeth
pp 4808 - 4813; DOI:
10.1021/ja00483a029
PDF
Aromatic hydroxylation by peroxydisulfate
Cheves Walling, Donald M. Camaioni, and Sung Soo Kim
pp 4814 - 4818; DOI:
10.1021/ja00483a030
PDF
Regioselectivity as a criterion for mechanism in the base-promoted opening of methylbicyclo[6.1.0]nona-2,4,6-trienes
Stuart W. Staley, Gerard E. Linkowski, and Marye Anne Fox
pp 4818 - 4821; DOI:
10.1021/ja00483a031
PDF
Mild procedures for interconverting allylic oxygen functionality. Cyclization-induced [3,3] sigmatropic rearrangement of allylic carbamates
Larry E. Overman, Curtis B. Campbell, and Fredrick M. Knoll
pp 4822 - 4834; DOI:
10.1021/ja00483a032
PDF
Free-radical participation in the reactions of selected metalate anions with alkyl halides
Joseph San Filippo, Joseph Silbermann, and Paul J. Fagan
pp 4834 - 4842; DOI:
10.1021/ja00483a033
PDF
Aminohaloborane in organic synthesis. 1. Specific ortho substitution reaction of anilines
Tsutomu Sugasawa, Tatsuo Toyoda, Makoto Adachi, and Kazuyuki Sasakura
pp 4842 - 4852; DOI:
10.1021/ja00483a034
PDF
Synthesis of acetylenes from carboxylic acid derivatives via .beta.-keto sulfones
Paul A. Bartlett, Frederick R. Green, and Esther H. Rose
pp 4852 - 4858; DOI:
10.1021/ja00483a035
PDF
Total synthesis of brefeldin A
Paul A. Bartlett and Frederick R. Green
pp 4858 - 4865; DOI:
10.1021/ja00483a036
PDF
Synthesis of anthopleurine, the alarm pheromone from Anthopleura elegantissima
James A. Musich and Henry Rapoport
pp 4865 - 4872; DOI:
10.1021/ja00483a037
PDF
Characterization of cobalt(II) bovine carbonic anhydrase and of its derivatives
I. Bertini, G. Canti, C. Luchinat, and A. Scozzafava
pp 4873 - 4877; DOI:
10.1021/ja00483a038
PDF
Stereochemical evidence of dual chemoreceptors for an achiral sex pheromone in Lepidoptera
Orville L. Chapman, Kenneth C. Mattes, Robert S. Sheridan, and Jerome A. Klun
pp 4878 - 4884; DOI:
10.1021/ja00483a039
PDF
Infrared laser multiphoton dissociation of tetramethyldioxetane: direct observation of triplet acetone
Yehuda Haas and Giora Yahav
pp 4885 - 4886; DOI:
10.1021/ja00483a040
PDF
Synthesis of mesityldiphenylmethylenephosphine: a stable compound with a localized phosphorus:carbon bond
T. C. Klebach, R. Lourens, and F. Bickelhaupt
pp 4886 - 4888; DOI:
10.1021/ja00483a041
PDF
Hypervalent organoiodine chemistry. Syn elimination of alkyl iodoso compounds
Hans J. Reich and Steven L. Peake
pp 4888 - 4889; DOI:
10.1021/ja00483a042
PDF
Cyclobutadiene is not square
Satoru Masamune, Fernando A. Souto-Bachiller, Takahisa Machiguchi, and John E. Bertie
pp 4889 - 4891; DOI:
10.1021/ja00483a043
PDF
Isomerism and charge distribution in mixed-metal polyoxoanion clusters: oxygen-17 nuclear magnetic resonance structure determinations of cis-V2W4O194- and cis-HV2W4O193-
W. G. Klemperer and Wilfred Shum
pp 4891 - 4893; DOI:
10.1021/ja00483a044
PDF
Short syntheses of eburnamonine via .beta.-oxycyclopropylcarbonyl and related intermediates
Ernest Wenkert, Tomas Hudlicky, and H. D. Hollis Showalter
pp 4893 - 4894; DOI:
10.1021/ja00483a045
PDF
A short route to pseudoyohimbine and yohimbine
Ernest Wenkert, Gerhard Kunesch, Kazuhiko Orito, Wayne A. Temple, and Jhillu S. Yadav
pp 4894 - 4895; DOI:
10.1021/ja00483a046
PDF
Structure of mildiomycin, a new antifungal nucleoside antibiotic
S. Harada, E. Mizuta, and T. Kishi
pp 4895 - 4897; DOI:
10.1021/ja00483a047
PDF
Carbon-13-enriched S-methylmethionyl residues as a probe of protein conformation
Benjamin M. Harina, Douglas F. Dyckes, M. Robert Willcott, and Warren C. Jones
pp 4897 - 4899; DOI:
10.1021/ja00483a048
PDF
A C11H11 limit of longicyclic stabilization
M. J. Goldstein, Yujiro Nomura, Yoshito Takeuchi, and Shuji Tomoda
pp 4899 - 4900; DOI:
10.1021/ja00483a049
PDF
A novel inhibitor of steroid biosynthesis
James A. Nelson, Michael R. Czarny, Thomas A. Spencer, James S. Limanek, Keith R. McCrae, and Ta Yuan Chang
pp 4900 - 4902; DOI:
10.1021/ja00483a050
PDF
Regiospecific synthesis of substituted arenes. [3,3]Sigmatropic rearrangement of benzyl vinyl ethers
Stanley Raucher and Alfred S.-T. Lui
pp 4902 - 4903; DOI:
10.1021/ja00483a051
PDF
Direct observation of radical intermediates in the photo-Kolbe reaction - heterogeneous photocatalytic radical formation by electron spin resonance
Bernhard Kraeutler, Calvin D. Jaeger, and Allen J. Bard
pp 4903 - 4905; DOI:
10.1021/ja00483a052
PDF
Iron(+) ion-induced dehydrohalogenation and polymerization of phenyl halides in the gas phase
T. G. Dietz, D. S. Chatellier, and D. P. Ridge
pp 4905 - 4907; DOI:
10.1021/ja00483a053
PDF
Sigmatropic rearrangement of vinylallenes: a novel route to the 1-hydroxyvitamin D system
Milton L. Hammond, Antonio Mourino, and William H. Okamura
pp 4907 - 4908; DOI:
10.1021/ja00483a054
PDF
Crossed molecular beam study of the chemi-ionization reaction: SbF5 + RX .fwdarw. SbF5X- + R+
A. Auerbach, R. J. Cross, and M. Saunders
pp 4908 - 4910; DOI:
10.1021/ja00483a055
PDF
Evidence for a new mode of neighboring-group participation by the azo group
Evan L. Allred, Joseph E. Oberlander, and Paul F. Ranken
pp 4910 - 4911; DOI:
10.1021/ja00483a056
PDF
Kinetic energy release in the fragmentation of CSH3+ ions
Alex G. Harrison
pp 4911 - 4912; DOI:
10.1021/ja00483a057
PDF
CIDNP evidence for electron transfer between two neutral radicals in solution
Ronald G. Lawler, Paul F. Barbara, and Deborah Jacobs
pp 4912 - 4914; DOI:
10.1021/ja00483a058
PDF
Molecular recognition. Anion cryptates of a macrobicyclic receptor molecule for linear triatomic species
Jean Marie Lehn, Etienne Sonveaux, and Alvin K. Willard
pp 4914 - 4916; DOI:
10.1021/ja00483a059
PDF
Substituent effects on the decomposition of 1,2-dioxetanes
K. A. Zaklika, Arthur L. Thayer, and A. Paul Schaap
pp 4916 - 4918; DOI:
10.1021/ja00483a060
PDF
Interaction of an aliphatic carbon-hydrogen bond with copper in a norbornene(diethylenetriamine)copper(I) cation complex
Marco Pasquali, Carlo Floriani, Amelia Gaetani-Manfredotti, and Angiola Chiesi-Villa
pp 4918 - 4919; DOI:
10.1021/ja00483a061
PDF
Bromine adsorbed on a molecular sieve: a reagent for selective bromination
P. A. Risbood and D. M. Ruthven
pp 4919 - 4921; DOI:
10.1021/ja00483a062
PDF
Molecular tweezers: a simple model of bifunctional intercalation
C. W. Chen and H. W. Whitlock
pp 4921 - 4922; DOI:
10.1021/ja00483a063
PDF
Book Reviews

pp 4923 - 4924; DOI:
10.1021/ja00483a600
PDF

Issue 16


LNDO/S, a semiempirical SCF-CI method for the calculation of ionization potentials and electronic transition energies of valence electrons
Guenther Lauer, Karl Wilhelm Schulte, and Armin Schweig
pp 4925 - 4935; DOI:
10.1021/ja00484a001
PDF
A MINDO/3 study of the Norrish type II reaction of butanal
Michael J. S. Dewar and Charles Doubleday
pp 4935 - 4941; DOI:
10.1021/ja00484a002
PDF
Quantum and statistical studies of liquids. 1. An intermolecular potential function for the hydrogen fluoride dimer from ab initio 6-31G computations
William L. Jorgensen and Michael E. Cournoyer
pp 4942 - 4945; DOI:
10.1021/ja00484a003
PDF
Formation, stability, and protonation of dihydropyridines. A MINDO/3 study
Nicholas Bodor and Rodney Pearlman
pp 4946 - 4953; DOI:
10.1021/ja00484a004
PDF
Theoretical study of lithium hydride (Li2H). 3. Approximate natural orbital contour diagrams and occupation numbers for the formation and dissociation of Li2H
Walter England and Nora H. Sabelli
pp 4953 - 4961; DOI:
10.1021/ja00484a005
PDF
Theoretical analysis of long-range hyperfine interactions in bicyclic free radicals. Application conditions for the W and anti-W rules
Y. Ellinger, R. Subra, and G. Berthier
pp 4961 - 4963; DOI:
10.1021/ja00484a006
PDF
The intramolecular external heavy atom effect in bromo-, benzo-, and naphthonorbornenes
A. K. Chandra, N. J. Turro, A. L. Lyons, and P. Stone
pp 4964 - 4968; DOI:
10.1021/ja00484a007
PDF
Effects of solvent, protonation, and N-alkylation on the nitrogen-15 chemical shifts of pyridine and related compounds
Rudolf O. Duthaler and John D. Roberts
pp 4969 - 4973; DOI:
10.1021/ja00484a008
PDF
Nitrogen-15 and carbon-13 nuclear magnetic resonance spectra of diazo and diazonium compounds
Rudolf O. Duthaler, H. G. Foerster, and John D. Roberts
pp 4974 - 4979; DOI:
10.1021/ja00484a009
PDF
Studies of pH and anion complexation effects on L-arginine by natural abundance nitrogen-15 nuclear magnetic resonance spectroscopy
Keiko Kanamori, Anne H. Cain, and John D. Roberts
pp 4979 - 4981; DOI:
10.1021/ja00484a010
PDF
Pulsed nuclear magnetic resonance study of molecular motion in solid imipramine hydrochloride, desipramine hydrochloride, and iminobibenzyl
David W. Larsen, Ted A. Smentkowski, Barbara A. Soltz, and Frank E. Stary
pp 4982 - 4987; DOI:
10.1021/ja00484a011
PDF
Circular dichroism and the conformation of sugars having vicinal diacylamino substituents
C. Allen Bush and Anthony Duben
pp 4987 - 4990; DOI:
10.1021/ja00484a012
PDF
Optical spectra of oxy- and deoxyhemoglobin
William A. Eaton, Louise Karle Hanson, P. J. Stephens, J. C. Sutherland, and J. B. R. Dunn
pp 4991 - 5003; DOI:
10.1021/ja00484a013
PDF
The conformational energy surface of trans,trans,trans-1,5,9-cyclododecatriene
Frank A. L. Anet and T. N. Rawdah
pp 5003 - 5007; DOI:
10.1021/ja00484a014
PDF
Valence electron momentum distributions of ethylene from the (e,2e) experiment
M. A. Coplan, A. L. Migdall, J. H. Moore, and J. A. Tossell
pp 5008 - 5011; DOI:
10.1021/ja00484a015
PDF
Potential energy surfaces of cyclobutadiene: ab initio SCF and CI calculations for the low-lying singlet and triplet states
J. A. Jafri and M. D. Newton
pp 5012 - 5017; DOI:
10.1021/ja00484a016
PDF
Electronic structure of cyclopentadienylthallium(I)
Carl S. Ewig, Roman Osman, and John R. Van Wazer
pp 5017 - 5020; DOI:
10.1021/ja00484a017
PDF
Synthesis of C,Sn-chiral triorganotin halides via C-chiral arylcopper and arylgoldlithium intermediates. Crystal and molecular structure of one [2-[1-(S)-(dimethylamino)ethyl]phenyl]methylphenyltin bromide diastereomer
Gerard Van Koten, Johann T. B. H. Jastrzebski, Jan G. Noltes, Wilbert M. G. F. Pontenagel, Jan Kroon, and Anthony L. Spek
pp 5021 - 5028; DOI:
10.1021/ja00484a018
PDF
Electron transfer reactions of trifluoroacetylated horse heart cytochrome c
Robert A. Holwerda, Rita A. Read, Robert A. Scott, Scot Wherland, Harry B. Gray, and Francis Millett
pp 5028 - 5033; DOI:
10.1021/ja00484a019
PDF
Molecular structure of dicyclopentadienyltetracarbonyldimolybdenum(Mo.tplbond.Mo). Semibridging carbonyls as four-electron donors in complexes with metal-metal multiple bonds
Robert J. Klingler, William M. Butler, and M. David Curtis
pp 5034 - 5039; DOI:
10.1021/ja00484a020
PDF
Cluster condensation reactions. Synthesis and structure of pentascandium octachloride (Sc5Cl8). An infinite chain structure derived by cluster condensation
Kenneth R. Poeppelmeier and John D. Corbett
pp 5039 - 5044; DOI:
10.1021/ja00484a021
PDF
Tetracarbon metallocarboranes. 5. A new synthetic route: synthesis of Co2C4B6 and CoC4B7 nido cage systems by fusion of dicarbon cobaltacarboranes in ethanolic potassium hydroxide. Crystal structure of (.eta.5-C5H5)2Co2C4B6H10
Kwai-Sam Wong, James R. Bowser, J. Robert Pipal, and Russell N. Grimes
pp 5045 - 5051; DOI:
10.1021/ja00484a022
PDF
Zero-coordinate cadmium(II). Over ion exchange. Crystal structures of hydrated and dehydrated zeolite A exchanged with cadmium chloride to give cadmium chloride hydroxide (Cd9.5Cl4(OH)3-A)
Lynne B. McCusker and Karl Seff
pp 5052 - 5057; DOI:
10.1021/ja00484a023
PDF
Ring opening of the endo-alkoxytetraphenylcyclobutyl ligand coordinated to palladium(II)
Thomas R. Jack, Christopher J. May, and John Powell
pp 5057 - 5063; DOI:
10.1021/ja00484a024
PDF
Formation of a cobalt-carbon bond under mild conditions. Preparation and crystal structure of an acetonyl adduct of N,N'-ethylenebis(3-fluorosalicylideniminato)cobalt(II)
William P. Schaefer, Rand Waltzman, and Ben T. Huie
pp 5063 - 5067; DOI:
10.1021/ja00484a025
PDF
Electrochemistry, synthesis, and spectra of pentaammineruthenium(III) complexes of cytidine, adenosine, and related ligands
Michael J. Clarke
pp 5068 - 5075; DOI:
10.1021/ja00484a026
PDF
The influence of axial ligands on metalloporphyrin visible absorption spectra. Complexes of tetraphenylporphinatozinc
Mario Nappa and Joan S. Valentine
pp 5075 - 5080; DOI:
10.1021/ja00484a027
PDF
Attachment of permethylpolysilane groups to platinum by electroreduction of chloropermethylpolysilanes. X-ray photoelectron spectroscopy of permethylpolysilanes chemically bound to electrode surfaces
A. Louis Allred, Cherlynlavaughn Bradley, and Thomas H. Newman
pp 5081 - 5084; DOI:
10.1021/ja00484a028
PDF
Synthesis of water-soluble undecagold cluster compounds of potential importance in electron microscopic and other studies of biological systems
Paul A. Bartlett, Barr Bauer, and S. J. Singer
pp 5085 - 5089; DOI:
10.1021/ja00484a029
PDF
Amino acid mediated asymmetric transformation and catalytic asymmetric transformation of the .alpha.-triethylenetetraminecobalt(III) moiety
Robert C. Job
pp 5089 - 5094; DOI:
10.1021/ja00484a030
PDF
Oxidation-reduction reactions of organoselenium compounds. 1. Mechanism of the reaction between seleninic acids and thiols
John L. Kice and Thomas W. S. Lee
pp 5094 - 5102; DOI:
10.1021/ja00484a031
PDF
Preparation and crystal and molecular structure of sodium [bis(inosine 5'-monophosphate)(diethylenetriamine)copper(II)] decahydrate. Possible implications for intrastrand cross-linking of polynucleotides by copper(II) and platinum(II) complexes
Chian C. Chiang, Theophilus Sorrell, Thomas J. Kistenmacher, and Luigi G. Marzilli
pp 5102 - 5110; DOI:
10.1021/ja00484a032
PDF
Crystal and molecular structure of the N,N-dimethylurea derivatives of exo-5-ethoxy-5-isocyanatobicyclo[2.1.0]pentane and exo-6-ethoxy-6-isocyanatobicyclo[3.1.0]hexane. Confirmation of the .gamma.-steric shift in nitrogen-15 nuclear magnetic resonance as a tool for stereochemical assignment
R. Curtis Haltiwanger, John M. Burns, Geoffrey C. Crockett, and Tad H. Koch
pp 5110 - 5116; DOI:
10.1021/ja00484a033
PDF
Dioxirane. Its synthesis, microwave spectrum, structure, and dipole moment
R. D. Suenram and F. J. Lovas
pp 5117 - 5122; DOI:
10.1021/ja00484a034
PDF
Spectroscopic properties of cyclic and bicyclic azoalkanes
Manfred J. Mirbach, Kou-Chang Liu, Marlis F. Mirbach, William R. Cherry, Nicholas J. Turro, and Paul S. Engel
pp 5122 - 5129; DOI:
10.1021/ja00484a035
PDF
Syntheses of cyclic acyloxyphosphoranes from phosphine oxides: spectroscopy, stability, and molecular structure. A stable P-hydroxyphosphorane: 1-hydroxy-1,1'-spirobi[3H-2,1-benzoxaphosphole]-3,3'-dione
Yoffi Segall and Itshak Granoth
pp 5130 - 5134; DOI:
10.1021/ja00484a036
PDF
A study of multiple ring expansion and ring contraction rearrangements in observable cycloalkyl cations
Roger P. Kirchen, Ted S. Sorensen, and Kim E. Wagstaff
pp 5134 - 5140; DOI:
10.1021/ja00484a037
PDF
Stereochemistry of the photoinduced and Michael addition of methanol to seven- and eight-membered 2-cycloalkenones
Harold Hart and Ezra Dunkelblum
pp 5141 - 5147; DOI:
10.1021/ja00484a038
PDF
Substituted acetophenones. Importance of activation energies in mixed state models of photoreactivity
Michael Berger, Eoghan McAlpine, and Colin Steel
pp 5147 - 5151; DOI:
10.1021/ja00484a039
PDF
Interconversion of 1-methylene-3-vinylcyclopentane and 5-methylenecycloheptene. A Cope rearrangement
Sara Jane Rhoads, James M. Watson, and J. George Kambouris
pp 5151 - 5155; DOI:
10.1021/ja00484a040
PDF
Neighboring-group participation of aldehydes and ketones in ester hydrolysis. Mechanism of hydrolysis of O-acetylsalicylaldehyde
Joseph A. Walder, Ronald S. Johnson, and Irving M. Klotz
pp 5156 - 5159; DOI:
10.1021/ja00484a041
PDF
Catalysis of the hydrolysis of a nitrophenyl ester by o-hydroxybenzaldehyde in the presence of a poly(ethylenimine) derivative
Ronald S. Johnson, Joseph A. Walder, and Irving M. Klotz
pp 5159 - 5163; DOI:
10.1021/ja00484a042
PDF
Stable carbocations. 214. Effect of solvents of decreasing nucleophilicity (sulfur dioxide, sulfuryl chloride fluoride, sulfuryl fluoride, and methylene fluoride) on the complex formation and ionization of alkyl fluorides (chlorides) with antimony and arsenic pentafluoride
George A. Olah and Daniel J. Donovan
pp 5163 - 5169; DOI:
10.1021/ja00484a043
PDF
Reaction of 5-chlorouracil derivatives with cysteine
Bimal C. Pal
pp 5170 - 5174; DOI:
10.1021/ja00484a044
PDF
Total synthesis of ovine-.beta.-lipotropin by the solid-phase method
Donald Yamashiro and Choh Hao Li
pp 5174 - 5179; DOI:
10.1021/ja00484a045
PDF
Synthetic applications of N-acylamino-1,3-dienes. An efficient stereospecific total synthesis of dl-pumiliotoxin C, and a general entry to cis-decahydroquinoline alkaloids
Larry E. Overman and Peter J. Jessup
pp 5179 - 5185; DOI:
10.1021/ja00484a046
PDF
Bimolecular reactions of pyridinyl radicals in water and the mechanism of NAD+-NADH dehydrogenase reactions
Edward M. Kosower, Avraham Teuerstein, Hugh D. Burrows, and A. J. Swallow
pp 5185 - 5190; DOI:
10.1021/ja00484a047
PDF
Conformation and crystal structures of two cycloisomeric hexapeptides: cyclo-(L-alanyl-L-alanylglycylglycyl-L-alanylglycyl) monohydrate (I) and cyclo-(L-alanyl-L-alanylglycyl-L-alanylglycylglycyl) dihydrate (II)
M. Bilayet Hossain and Dick Van der Helm
pp 5191 - 5198; DOI:
10.1021/ja00484a048
PDF
Predicting the enantiomeric selectivity of chymotrypsin. Homologous series of ester substances
Harold M. Schwartz, Weh-Sai Wu, Peter W. Marr, and J. Bryan Jones
pp 5199 - 5203; DOI:
10.1021/ja00484a049
PDF
Stoichiometric determination of chlorophyll a-water aggregates and photosynthesis. Symbiotic roles of the magnesium atom and the ring V cyclopentanone group in the structural and photochemical properties of chlorophyll a monohydrate and dihydrate
John G. Brace, Francis K. Fong, Dale H. Karweik, Vaughn J. Koester, Allan Shepard, and Nicholas Winograd
pp 5203 - 5207; DOI:
10.1021/ja00484a050
PDF
Total synthesis of (.+-.)-seychellene. Use of silyloxydienes in synthesis
Michael E. Jung and Charles A. McCombs
pp 5207 - 5209; DOI:
10.1021/ja00484a051
PDF
Nuclear magnetic resonance manifestation of the configurational differences between the L- and D-norepinephrine complexes with cobaltous adenosine 5'-triphosphate, an aqueous chiral shift reagent
Joseph Granot and Jacques Reuben
pp 5209 - 5210; DOI:
10.1021/ja00484a052
PDF
Norepinephrine complexes and reduced vanadium(V) to reverse vanadate inhibition of the (sodium, potassium ion)-dependent ATPase
Lewis C. Cantley, John H. Ferguson, and Kenneth Kustin
pp 5210 - 5212; DOI:
10.1021/ja00484a053
PDF
Correlated rotation of tert-butyl groups in tri-tert-butylsilane
W. Douglas Hounshell, Linda D. Iroff, R. J. Wroczynski, and Kurt Mislow
pp 5212 - 5213; DOI:
10.1021/ja00484a054
PDF
Chemically modified electrodes. II. Predictability of formal potentials of covalently immobilized charge-transfer reagents
J. R. Lenhard, R. Rocklin, H. Abruna, K. Willman, K. Kuo, R. Nowak, and Royce W. Murray
pp 5213 - 5215; DOI:
10.1021/ja00484a055
PDF
Nonbonded interactions in phenylcarbenium ions
David A. Forsyth, Dennis E. Vogel, and Susan J. Stanke
pp 5215 - 5216; DOI:
10.1021/ja00484a056
PDF
Nitrogen-15 nuclear magnetic resonance spectroscopy. A simple procedure for determination of the rates of nitrogen-hydrogen proton exchange of cis- and trans-1-aza-2-cyclononanone
Issa Yavari and John D. Roberts
pp 5217 - 5218; DOI:
10.1021/ja00484a057
PDF
Stereoelectronic factors in the solvolysis of bay region diol epoxides of polycyclic aromatic hydrocarbons
Dale L. Whalen, Angela M. Ross, Haruhiko Yagi, Jean M. Karle, and Donald M. Jerina
pp 5218 - 5221; DOI:
10.1021/ja00484a058
PDF
1,4-Addition reaction of organolithium and -magnesium compounds to .alpha.,.beta.-unsaturated thioamides
Yoshinao Tamaru, Toshiro Harada, Hiromitsu Iwamoto, and Zenichi Yoshida
pp 5221 - 5223; DOI:
10.1021/ja00484a059
PDF
Biosynthesis of estrogens. Assignment of the chemical shift of the 19-pro-chiral hydrogen atoms of a 19-hydroxy precursor
E. Caspi, E. Santaniello, K. Patel, T. Arunachalam, and C. Eck
pp 5223 - 5224; DOI:
10.1021/ja00484a060
PDF
Synthesis of transition metal complexes of cycloheptatrienylidene
Neil T. Allison, Y. Kawada, and W. M. Jones
pp 5224 - 5226; DOI:
10.1021/ja00484a061
PDF
Trimethylamine-SO2, the prototype strong charge-transfer complex
John E. Douglas and Peter A. Kollman
pp 5226 - 5227; DOI:
10.1021/ja00484a062
PDF
Carbon-13-proton cross-polarization in liquids
R. D. Bertrand, W. B. Moniz, A. N. Garroway, and G. C. Chingas
pp 5227 - 5229; DOI:
10.1021/ja00484a063
PDF
A phosphoranoxide anion - direct observation and isolation of a stable model for the postulated intermediate in nucleophilic substitution at tetracoordinated phosphinoyl phosphorus
Itshak Granoth and J. C. Martin
pp 5229 - 5230; DOI:
10.1021/ja00484a064
PDF
A kinetic model for the formation of the conductor N-methylphenazinium tetracyanoquinodimethanide (NMP-TCNQ)
D. J. Sandman
pp 5230 - 5232; DOI:
10.1021/ja00484a065
PDF
Unequivocal structural assignments of N7- and N9-acyladenines
Jean M. Ohrt, T. Srikrishnan, R. Parthasarathy, S. P. Dutta, and Girish B. Chheda
pp 5232 - 5234; DOI:
10.1021/ja00484a066
PDF
Paramagnetic carbon monoxide adducts of reduced iron-sulfur tetramers: relevance to the mechanism of action of hydrogenase
Bruce A. Averill and William H. Orme-Johnson
pp 5234 - 5236; DOI:
10.1021/ja00484a067
PDF
Cadmium-113 nuclear magnetic resonance studies of metalloproteins. 1. [113Cd]-concanavalin A: a preliminary investigation
David B. Bailey, Paul D. Ellis, Alan D. Cardin, and W. David Behnke
pp 5236 - 5237; DOI:
10.1021/ja00484a068
PDF
Crystal and molecular structure of tetra(cyclopentadienyl)zirconium
Robin D. Rogers, R. Vann Bynum, and Jerry L. Atwood
pp 5238 - 5239; DOI:
10.1021/ja00484a069
PDF
.mu.-Carbonyl-.mu.-hydrido-decacarbonyltriferric acid, H2Fe3(CO)11
H. A. Hodali, D. F. Shriver, and C. A. Ammlung
pp 5239 - 5240; DOI:
10.1021/ja00484a070
PDF
High pressure electron paramagnetic resonance experiments. Effect of solvent contraction on hyperfine splitting
D. Griller
pp 5240 - 5241; DOI:
10.1021/ja00484a071
PDF
Rate of primary photoproduct formation for aqueous tris(ethylenediamine)chromium(III)
A. W. Adamson, R. T. Walters, R. Fukuda, and A. R. Gutierrez
pp 5241 - 5243; DOI:
10.1021/ja00484a072
PDF
Biosynthesis of lipoic acid. 2. Stereochemistry of sulfur introduction at C-6 of octanoic acid
Ronald J. Parry and Diane A. Trainor
pp 5243 - 5244; DOI:
10.1021/ja00484a073
PDF
Time-resolved electron paramagnetic resonance and flow-Fourier transform nuclear magnetic resonance study in radiation chemistry. An example of Overhauser CIDNP
A. D. Trifunac and D. J. Nelson
pp 5244 - 5246; DOI:
10.1021/ja00484a074
PDF
Unambiguous generation and trapping of a silabenzene
Thomas J. Barton and Gary T. Burns
pp 5246 - 5246; DOI:
10.1021/ja00484a075
PDF
Surfactants as electrophilic substrates. Micellar and self-phase transfer reactions of surfactant sulfonates
Robert A. Moss and Winfred J. Sanders
pp 5247 - 5248; DOI:
10.1021/ja00484a076
PDF
Oxygenation of cyclic dienes to endoperoxides
Reginald Tang, Henry J. Yue, J. Fredrick Wolf, and Frank Mares
pp 5248 - 5249; DOI:
10.1021/ja00484a077
PDF
Malonic anhydride
Charles L. Perrin and Thomas Arrhenius
pp 5249 - 5251; DOI:
10.1021/ja00484a078
PDF
Laser fluorescence spectra of the hexafluorobenzene cation in solid argon
V. E. Bondybey, J. H. English, and Terry A. Miller
pp 5251 - 5252; DOI:
10.1021/ja00484a079
PDF
A trinuclear molybdenum(IV) cluster compound having an unusual structure and unusual stability
Avi Bino, F. Albert Cotton, and Zvi Dori
pp 5252 - 5253; DOI:
10.1021/ja00484a080
PDF
Interaction of vicinal and nonvicinal amino-hydroxy group pairs in aminoglycoside-aminocyclitol antibiotics with transition metal cations. Selective N protection
T. L. Nagabhushan, A. B. Cooper, W. N. Turner, H. Tsai, S. McCombie, A. K. Mallams, D. Rane, J. J. Wright, P. Reichert, and et al.
pp 5253 - 5254; DOI:
10.1021/ja00484a081
PDF
Book Reviews

pp 5255 - 5256; DOI:
10.1021/ja00484a600
PDF

Issue 17


Chemically derivatized n-type semiconducting germanium photoelectrodes. Persistent attachment and photoelectrochemical activity of ferrocene derivatives
Jeffrey M. Bolts and Mark S. Wrighton
pp 5257 - 5262; DOI:
10.1021/ja00485a001
PDF
Infrared circular dichroism associated with the hydroxyl-stretching vibration in the methyl ester of mandelic acid
Curtis Marcott, Carol C. Blackburn, Thomas R. Faulkner, Albert Moscowitz, and John Overend
pp 5262 - 5264; DOI:
10.1021/ja00485a002
PDF
Intramolecular hydrogen tunneling in malonaldehyde
Eugene M. Fluder and Jose R. De la Vega
pp 5265 - 5267; DOI:
10.1021/ja00485a003
PDF
The aromaticity of annulenoannulenes
B. Andes Hess, L. J. Schaad, and Israel Agranat
pp 5268 - 5271; DOI:
10.1021/ja00485a004
PDF
Theoretical studies on the singlet and triplet cyclopropylidene allene system
Daniel J. Pasto, Michael Haley, and Daniel M. Chipman
pp 5272 - 5278; DOI:
10.1021/ja00485a005
PDF
Chemical consequences of orbital interactions. 14. Ab initio molecular orbital study of the geometries, properties, and protonation of simple organofluorides
William L. Jorgensen and Michael E. Cournoyer
pp 5278 - 5285; DOI:
10.1021/ja00485a006
PDF
Molecular orbital theory of the hydrogen bond. 20. Pyrrole and imidazole as proton donors and proton acceptors
Janet E. Del Bene and Irwin Cohen
pp 5285 - 5290; DOI:
10.1021/ja00485a007
PDF
Ground states of molecules. 48. MINDO/3 study of some radical addition reactions
Michael J. S. Dewar and Santiago Olivella
pp 5290 - 5295; DOI:
10.1021/ja00485a008
PDF
Calculation of phosphororganic compounds by MINDO/3. 1. Parametrization of the phosphorus-carbon bond
G. Frenking, H. Goetz, and F. Marschner
pp 5295 - 5296; DOI:
10.1021/ja00485a009
PDF
Structure and stability of the carbocations C2H3+ and C2H4X+, X = hydrogen, fluorine, chlorine, and methyl. Ab initio investigation including electron correlation and a comparison with MINDO/3 results
Hans Lischka and Hans Joachim Koehler
pp 5297 - 5305; DOI:
10.1021/ja00485a010
PDF
The bonding capabilities of transition metal clusters
Joseph W. Lauher
pp 5305 - 5315; DOI:
10.1021/ja00485a011
PDF
Proton magnetic resonance properties of the tetranuclear clusters [Fe4S4(SR)4]3-, analogs of the 4-Fe sites of reduced ferredoxins
John G. Reynolds, Edward J. Laskowski, and R. H. Holm
pp 5315 - 5322; DOI:
10.1021/ja00485a012
PDF
Synthetic analogs of the 4-Fe active sites of reduced ferredoxins. Electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3- and the structure of [(C2H5)3(CH3)N]3[Fe4S4(SC6H5)4]
E. J. Laskowski, R. B. Frankel, W. O. Gillum, G. C. Papaefthymiou, J. Renaud, James A. Ibers, and R. H. Holm
pp 5322 - 5337; DOI:
10.1021/ja00485a013
PDF
Reaction chemistry of the iron-sulfur protein site analogs [Fe4S4(SR)4]2-. Sequential thiolate ligand substitution reactions with electrophiles
Richard W. Johnson and R. H. Holm
pp 5338 - 5344; DOI:
10.1021/ja00485a014
PDF
Photooxidation of dichloro- and trichlorocuprate(I) ions in acid solution
Dennis D. Davis, Kenneth L. Stevenson, and Charles R. Davis
pp 5344 - 5349; DOI:
10.1021/ja00485a015
PDF
Environmentally hindered radiationless transitions between states of different orbital parentage in iridium(III) complexes. Application of rigid-matrix induced perturbations of the pseudo-Jahn-Teller potential to the rigidochromic effect in d6 metal complexes
Richard J. Watts and Duncan Missimer
pp 5350 - 5357; DOI:
10.1021/ja00485a016
PDF
Structures of two spiroarsoranes and their dynamic implications
Harold Goldwhite and Raymond G. Teller
pp 5357 - 5362; DOI:
10.1021/ja00485a017
PDF
Coordination chemistry of microbial iron transport compounds. 9. Stability constants for catechol models of enterobactin
Alex Avdeef, Stephen R. Sofen, Thomas L. Bregante, and Kenneth N. Raymond
pp 5362 - 5370; DOI:
10.1021/ja00485a018
PDF
Coordination chemistry of microbial iron transport compounds. 10. Characterization of the complexes of rhodotorulic acid, a dihydroxamate siderophore
Carl J. Carrano and Kenneth N. Raymond
pp 5371 - 5374; DOI:
10.1021/ja00485a019
PDF
The relationship of thermodynamic data for base adduct formation with cobalt protoporphyrin IX dimethyl ester to the corresponding enthalpies of forming dioxygen adducts with implications to oxygen binding cooperativity
Russell S. Drago, Tony Beugelsdijk, John A. Breese, and J. Patrick Cannady
pp 5374 - 5382; DOI:
10.1021/ja00485a020
PDF
Gallium-71 and phosphorus-31 nuclear magnetic resonance studies of the interactions of gallium with phosphoric acid in aqueous solution
Robert E. Lenkinski, C. H. Francis Chang, and Jerry D. Glickson
pp 5383 - 5386; DOI:
10.1021/ja00485a021
PDF
Chemistry of thiono- and selenonophosphoranes. A mechanistic study of chlorination reactions of phosphorus thionoesters >P(S)OR: reactive intermediates and stereochemistry
Jan Michalski, Jerzy Mikolajczak, and Aleksandra Skowronska
pp 5386 - 5390; DOI:
10.1021/ja00485a022
PDF
Crystal and molecular structure of phosphate esters. 9. Crystal and molecular structure of o-hydroxyphenyl-o-phenylene phosphate, (o-HOC6H4)(C6H4)PO4. Equilibrium between pentavalent and tetravalent phosphorus in solutions
Raghupathy Sarma, Fausto Ramirez, Brian McKeever, Mark Nowakowski, and James F. Marecek
pp 5391 - 5395; DOI:
10.1021/ja00485a023
PDF
Synthetic methods and reactions. 46. Oxidation of organic compounds with uranium hexafluoride in haloalkane solutions
George A. Olah and John Welch
pp 5396 - 5402; DOI:
10.1021/ja00485a024
PDF
Stabilities of carbonium ions in solution. 7. A low-temperature calorimetric approach to enthalpies of formation of carbocations in solution
Edward M. Arnett and Craig Petro
pp 5402 - 5407; DOI:
10.1021/ja00485a025
PDF
Stabilities of carbonium ions in solution. 8. Heats of ionization of some simple alkyl halides in superacidic media
Edward M. Arnett and Craig Petro
pp 5408 - 5416; DOI:
10.1021/ja00485a026
PDF
Reactivity of arylcarbenium ions with alkylamines and ammonia in solutions. Kinetic effect of cyclopropyl substitution. Solvent effect
Vincent M. DePalma, Ying Wang, and Leon M. Dorfman
pp 5416 - 5419; DOI:
10.1021/ja00485a027
PDF
Reagent distribution and micellar catalysis of carbocation reactions
Clifford A. Bunton, Nelson Carrasco, Sung K. Huang, Chang H. Paik, and Laurence S. Romsted
pp 5420 - 5425; DOI:
10.1021/ja00485a028
PDF
Disproportionation of cis-stilbene radical anions
F. Jachimowicz, G. Levin, and M. Szwarc
pp 5426 - 5427; DOI:
10.1021/ja00485a029
PDF
Dipole-stabilized carbanions from thioesters. Evidence for stabilization by the carbonyl group
David B. Reitz, Peter Beak, Robert F. Farney, and Larry S. Helmick
pp 5428 - 5436; DOI:
10.1021/ja00485a030
PDF
Activation of molecular oxygen: rhodium-catalyzed oxidation of olefins
Hubert Mimoun, M. Mercedes Perez Machirant, and Irenee Seree de Roch
pp 5437 - 5444; DOI:
10.1021/ja00485a031
PDF
Mechanisms of general acid and base catalysis of the reactions of water and alcohols with formaldehyde
Lance H. Funderburk, Lois Aldwin, and William P. Jencks
pp 5444 - 5459; DOI:
10.1021/ja00485a032
PDF
Acidities and basicities of carboxylic acids. Correlations between core-ionization energies, proton affinities, and gas-phase acidities
S. R. Smith and T. D. Thomas
pp 5459 - 5466; DOI:
10.1021/ja00485a033
PDF
Bonding energies in association ions of aromatic compounds. Correlations with ionization energies
Michael Meot-Ner, Peter Hamlet, Edward P. Hunter, and Frank H. Field
pp 5466 - 5471; DOI:
10.1021/ja00485a034
PDF
Cleavage of carbon-carbon bonds. Copper(II)-induced oxygenolysis of o-benzoquinones, catechols, and phenols. On the question of nonenzymic oxidation of aromatics and activation of molecular oxygen
Milorad M. Rogic and Timothy R. Demmin
pp 5472 - 5487; DOI:
10.1021/ja00485a035
PDF
Electron transfer versus hydrogen abstraction in photoreduction of quinones. An application of chemically induced dynamic electron polarization
S. King Wong
pp 5488 - 5490; DOI:
10.1021/ja00485a036
PDF
Asymmetric synthesis. An asymmetric homogeneous hydrogenation catalyst which breeds its own chirality
M. D. Fryzuk and B. Bosnich
pp 5491 - 5494; DOI:
10.1021/ja00485a037
PDF
On the mechanism of decomposition of geminal diamines
Graeme Moad and S. J. Benkovic
pp 5495 - 5499; DOI:
10.1021/ja00485a038
PDF
Intramolecular nucleophilic attack by imidazole on aliphatic and phenolic esters of o-(2-imidazoyl)benzoic acid. Relationship of anion and neutral species attack
Thomas H. Fife, Raymond J. Bambery, and Bruce R. DeMark
pp 5500 - 5507; DOI:
10.1021/ja00485a039
PDF
Antiaromatic interaction in the 9-methoxybicyclo[4.2.1]nona-2,4,7-trien-9-yl cation. Evidence of orbital symmetry control over 4.pi.-electron interactions
P. Schipper and H. M. Buck
pp 5507 - 5512; DOI:
10.1021/ja00485a040
PDF
Oxasecoalkylation via cyclobutanone intermediates
Barry M. Trost, Mitchell J. Bogdanowicz, W. Jack Frazee, and Thomas N. Salzmann
pp 5512 - 5525; DOI:
10.1021/ja00485a041
PDF
A base-induced coupling-condensation of aryl o-methylarenesulfonates and o-methylarenesulfonanilides
William E. Truce and Barry VanGemert
pp 5525 - 5529; DOI:
10.1021/ja00485a042
PDF
Intermediates in nucleophilic aromatic substitution. 18. The elusive 1,1-Meisenheimer complex from 2,4,6-trinitroanisole and aryloxide ions. A stopped-flow temperature-jump study
Claude F. Bernasconi and Morris C. Muller
pp 5530 - 5533; DOI:
10.1021/ja00485a043
PDF
Aryl shifts from silicon to carbon via .gamma.- and .delta.-silyl radicals
James W. Wilt, Willy K. Chwang, Carolyn F. Dockus, and Neil M. Tomiuk
pp 5534 - 5540; DOI:
10.1021/ja00485a044
PDF
Kinetics of the formation and decomposition of carbon-cobalt(III) bonds in aqueous solutions by the reaction of aliphatic free radicals with a coenzyme B-12r model cobalt(II) complex
Hanoch Elroi and Dan Meyerstein
pp 5540 - 5548; DOI:
10.1021/ja00485a045
PDF
Reaction kinetics of the metal ion catalyzed .beta.-phenylserine-pyridoxal model system
Kuniyasu Tatsumoto and Arthur E. Martell
pp 5549 - 5553; DOI:
10.1021/ja00485a046
PDF
Structural studies of organometallic compounds. 3. Determination of the crystal structure of .alpha.,.alpha.-diferrocenylmethylium tetrafluoroborate, a stable carbenium ion salt, and a comparison of its structure with those of other organometallic carbenium cations
Michael Cais, Sanda Dani, Frank H. Herbstein, and Moshe Kapon
pp 5554 - 5558; DOI:
10.1021/ja00485a047
PDF
Kinetics of unimolecular dioxetanone chemiluminescence. Competitive parallel reaction paths
Steven P. Schmidt and Gary B. Schuster
pp 5559 - 5561; DOI:
10.1021/ja00485a048
PDF
Synthesis of homopropargylic and .alpha.-allenic alcohols from lithium chloropropargylide, trialkylboranes, and aldehydes
George Zweifel, Stephen J. Backlund, and Teresa Leung
pp 5561 - 5562; DOI:
10.1021/ja00485a049
PDF
Crystal and molecular structure of a biscyclopentadienyluranium(IV) phosphoylide dimer, [.mu.-(CH)(CH2)P(C6H5)2U(C5H5)2]2.(C2H5)2O
Roger E. Cramer, Richard B. Maynard, and John W. Gilje
pp 5562 - 5564; DOI:
10.1021/ja00485a050
PDF
Cyclic tautomers of tryptophans and tryptamines. I. Formation and reactions
Tohru Hino and Mikio Taniguchi
pp 5564 - 5565; DOI:
10.1021/ja00485a051
PDF
Total synthesis of confertin via metal-promoted cyclization-lactonization
M. F. Semmelhack, A. Yamashita, J. C. Tomesch, and K. Hirotsu
pp 5565 - 5567; DOI:
10.1021/ja00485a052
PDF
A new contractive coupling procedure. Convenient phosphorus expulsion reaction
George R. Newkome and David C. Hager
pp 5567 - 5568; DOI:
10.1021/ja00485a053
PDF
True vs. apparent asymmetry
Y. Jean and L. Salem
pp 5568 - 5569; DOI:
10.1021/ja00485a054
PDF
Acoustic emission during the preparation of dichloro(pyrazine)zinc(II)
Johannes A. C. Van Ooijen, Eric Van Tooren, and Jan Reedijk
pp 5569 - 5570; DOI:
10.1021/ja00485a055
PDF
Preparation and crystal structure of oxotechnetium bis(thiomercaptoacetate) and its relationship to radiopharmaceuticals labeled with technetium-99m
B. V. DePamphilis, A. G. Jones, M. A. Davis, and A. Davison
pp 5570 - 5571; DOI:
10.1021/ja00485a056
PDF
A thiol complex of technetium pertinent to radiopharmaceutical use of technetium-99m
James E. Smith, E. F. Byrne, F. Albert Cotton, and Janine C. Sekutowski
pp 5571 - 5572; DOI:
10.1021/ja00485a057
PDF
Structural studies of precursor and partially oxidized conducting complexes. 17. Synthesis and electrical properties of the first homologous series of 1-dimensional (platinum-platinum) metals containing the (FHF)- and F- anions
Jack M. Williams, Arthur J. Schultz, Kevin B. Cornett, and Richard E. Besinger
pp 5572 - 5573; DOI:
10.1021/ja00485a058
PDF
Minor and trace sterols in marine invertebrates. 24-Ethyl-.DELTA.5,24(28),28-cholestatrien-3.beta.-ol - a naturally occurring allenic marine sterol
Norbert Theobald, J. N. Shoolery, Carl Djerassi, Timothy R. Erdman, and Paul J. Scheuer
pp 5574 - 5575; DOI:
10.1021/ja00485a059
PDF
Chiral aggregation phenomena. 1. Acid dependent chiral recognition in a monolayer
Edward M. Arnett, Jean Chao, Barbara Kinzig, Martin Stewart, and Orlean Thompson
pp 5575 - 5576; DOI:
10.1021/ja00485a060
PDF
Noncoulomb variation of ion pairing in polar solvents
Raymond M. Fuoss
pp 5576 - 5577; DOI:
10.1021/ja00485a061
PDF
Thermal isomerization of 2,2-difluoromethylenecyclopropane
William R. Dolbier and Thomas H. Fielder
pp 5577 - 5578; DOI:
10.1021/ja00485a062
PDF
Dioxygen fixation. Oxene transfer in the reaction of singlet dioxygen with .alpha.-keto acids
Robert M. Moriarty, Anton Chin, and Michael P. Tucker
pp 5578 - 5580; DOI:
10.1021/ja00485a063
PDF
Autoxidation of ketenes. Diradicaloid and zwitterionic mechanisms of reactions of triplet molecular oxygen and ketenes
Nicholas J. Turro, Ming-Fea Chow, and Yashikatsu Ito
pp 5580 - 5582; DOI:
10.1021/ja00485a064
PDF
Ozonation of ketenes. Nature of intermediates
R. M. Moriarty, Kenneth B. White, and A. Chin
pp 5582 - 5584; DOI:
10.1021/ja00485a065
PDF
Photoelectron spectra of the ozonides of ethylene, cyclopentene, and cyclohexene. Experimental evidence for the magnitude of the "pure" inductive effect of an ether oxygen on ionization energy
R. S. Brown and R. W. Marcinko
pp 5584 - 5586; DOI:
10.1021/ja00485a066
PDF
An exceedingly short quadruple bond involving tungsten and the enigma of heteronuclear metal-metal bonds with multiple bond character
Vladimir Katovic and Robert E. McCarley
pp 5586 - 5587; DOI:
10.1021/ja00485a067
PDF
Book Reviews

pp 5587 - 5588; DOI:
10.1021/ja00485a600
PDF

Issue 18


Long-range electronic transmission in conformationally rigid .alpha.-diketones
Richard Bartetzko, Rolf Gleiter, Jean L. Muthard, and Leo A. Paquette
pp 5589 - 5594; DOI:
10.1021/ja00486a001
PDF
Electron photodetachment spectroscopy of polyene anions. Electron affinities of pentadienyl and heptatrienyl radicals
Albert H. Zimmerman, Ruedi Gygax, and John I. Brauman
pp 5595 - 5597; DOI:
10.1021/ja00486a002
PDF
Photoelectron spectroscopy of carbonyls. Lone-pair interactions in .alpha.-, .beta.-, .gamma.-, and .delta.-dicarbonyls
D. Dougherty, P. Brint, and S. P. McGlynn
pp 5597 - 5603; DOI:
10.1021/ja00486a003
PDF
Steric effects in fast thermal Z,E isomerization of overcrowded ethylenes. Conformational behavior of N,N'-dimethylbiacridans
Israel Agranat and Yitzhak Tapuhi
pp 5604 - 5609; DOI:
10.1021/ja00486a004
PDF
Intersystem crossing observed by ultrasonic relaxation of the 2T .dblharw. 6A spin equilibrium of hexadentate iron(III) complexes in solution
Robert A. Binstead, James K. Beattie, Eric V. Dose, Michael F. Tweedle, and Lon J. Wilson
pp 5609 - 5614; DOI:
10.1021/ja00486a005
PDF
Secondary ion mass spectrometry. Cationization of organic molecules with metals
H. Grade and R. G. Cooks
pp 5615 - 5621; DOI:
10.1021/ja00486a006
PDF
The nature of solution spectra. Inhomogeneous broadening and phonon effects in frozen solutions
William C. McColgin, Alfred P. Marchetti, and Joseph H. Eberly
pp 5622 - 5626; DOI:
10.1021/ja00486a007
PDF
Conformational equilibriums in vitamin D. Synthesis and proton and carbon-13 dynamic nuclear magnetic resonance study of 4,4-dimethylvitamin D3, 4,4-dimethyl-1.alpha.-hydroxyvitamin D3, and 4,4-dimethyl-1.alpha.-hydroxyepivitamin D3
Elisha Berman, Noga Friedman, Yehuda Mazur, and Mordechai Sheves
pp 5626 - 5634; DOI:
10.1021/ja00486a008
PDF
High-resolution carbon-13 nuclear magnetic resonance spectra of frozen liquids using magic angle spinning
C. A. Fyfe, J. R. Lyerla, and C. S. Yannoni
pp 5635 - 5636; DOI:
10.1021/ja00486a009
PDF
Carbon-13 nuclear magnetic resonance spectra with coherent proton decoupling: peak-height distortions within spin multiplets
Ray Freeman, John B. Grutzner, Gareth Morris, and David L. Turner
pp 5637 - 5640; DOI:
10.1021/ja00486a010
PDF
Heat capacity and structure in liquids. Application to the structure of water
Sidney W. Benson
pp 5640 - 5644; DOI:
10.1021/ja00486a011
PDF
Vibrational circular dichroism in amino acids and peptides. 2. Simple alanyl peptides
Max Diem, Paul J. Gotkin, Joel M. Kupfer, and Laurence A. Nafie
pp 5644 - 5650; DOI:
10.1021/ja00486a012
PDF
Ground states of molecules. 49. MINDO/3 study of the retro-Diels-Alder reaction of cyclohexene
Michael J. S. Dewar, Santiago Olivella, and Henry S. Rzepa
pp 5650 - 5659; DOI:
10.1021/ja00486a013
PDF
The electronic states of Ni2 and Ni2+
Thomas H. Upton and William A. Goddard
pp 5659 - 5668; DOI:
10.1021/ja00486a014
PDF
Theoretical studies of the ground and excited states of a model of the active site in oxidized and reduced rubredoxin
Raymond A. Bair and William A. Goddard
pp 5669 - 5676; DOI:
10.1021/ja00486a015
PDF
Theoretical studies of dodecahedrane. 2. Dodecahedrane, inclusion compounds, and fluorine derivatives
Jerome M. Schulman and Raymond L. Disch
pp 5677 - 5681; DOI:
10.1021/ja00486a016
PDF
Localized molecular orbitals for polyatomic molecules. 6. Condensed aromatic ring systems
D. A. Dixon, D. A. Kleier, and W. N. Lipscomb
pp 5681 - 5694; DOI:
10.1021/ja00486a017
PDF
Ab initio SCF-MO study of cyclopentadienylberyllium hydride and of beryllocene
Eluvathingal D. Jemmis, Spiro Alexandratos, Paul v. R. Schleyer, Andrew Streitwieser, and Henry F. Schaefer
pp 5695 - 5700; DOI:
10.1021/ja00486a018
PDF
The role of primary-secondary orbital interactions in affecting regioselectivities. Cycloaddition reactions between 1,3-dipoles and electron-deficient alkynes
Michael D. Gordon, Peter V. Alston, and Angelo R. Rossi
pp 5701 - 5705; DOI:
10.1021/ja00486a019
PDF
Monte Carlo studies on the structure of a dilute aqueous solution of methane
S. Swaminathan, S. W. Harrison, and David L. Beveridge
pp 5705 - 5712; DOI:
10.1021/ja00486a020
PDF
The importance of .sigma. conjugative interactions in rotational isomerism
James R. Larson, N. D. Epiotis, and F. Bernardi
pp 5713 - 5716; DOI:
10.1021/ja00486a021
PDF
Valence shell electron pair interactions in water and hydrogen sulfide. A test of the valence shell electron pair repulsion theory
William E. Palke and Bernard Kirtman
pp 5717 - 5721; DOI:
10.1021/ja00486a022
PDF
Influence of substituents upon ionization potential. Dependence of the .pi.-ionization energy on the orientation of an allylic hydroxyl or methoxyl substituent
R. S. Brown and Randall W. Marcinko
pp 5721 - 5727; DOI:
10.1021/ja00486a023
PDF
Genesis of a supported-metal catalyst. Aggregation of polymer-bound rhodium clusters
M. S. Jarrell, B. C. Gates, and E. D. Nicholson
pp 5727 - 5732; DOI:
10.1021/ja00486a024
PDF
Mechanisms of chlorine oxidation of hydrogen peroxide
A. M. Held, D. J. Halko, and J. K. Hurst
pp 5732 - 5740; DOI:
10.1021/ja00486a025
PDF
Preparation and properties of molybdenum and tungsten dinitrogen complexes. 8. Diazoalkane complexes of molybdenum and tungsten
Masanobu Hidai, Yasushi Mizobe, Maki Sato, Teruyuki Kodama, and Yasuzo Uchida
pp 5740 - 5748; DOI:
10.1021/ja00486a026
PDF
Synthetic, physicochemical, and structural study of phosphacymantrenes
Francois Mathey, Andre Mitschler, and Raymond Weiss
pp 5748 - 5755; DOI:
10.1021/ja00486a027
PDF
Transition metal compounds of N(3)-alkylated 6-aminopurines. Synthesis and unusually high stability of bis(acetylacetonato)(nitro)(N(3)-alkylated 6-aminopurine)cobalt(III) complexes. Crystal and molecular structure of the triacanthine complex
Theophilus Sorrell, Leon A. Epps, Thomas J. Kistenmacher, and Luigi G. Marzilli
pp 5756 - 5763; DOI:
10.1021/ja00486a028
PDF
Reactions of metal-to-metal multiple bonds. 4. .mu.-Acetylene-bis(cyclopentadienyl)tetracarbonyldimolybdenum compounds. Preparations, properties, structural characterizations, and dynamical solution behavior
W. I. Bailey, M. H. Chisholm, F. A. Cotton, and L. A. Rankel
pp 5764 - 5773; DOI:
10.1021/ja00486a029
PDF
Infrared spectra of the argon-matrix isolated alkali halide salt/ammonia complexes. Spectrum of the NH3M+ cation
Bruce S. Ault
pp 5773 - 5777; DOI:
10.1021/ja00486a030
PDF
Isotropic shifts in a series of cobalt bis(salicylaldehyde)ethylenediimine derivatives
C. Srivanavit and Dennis G. Brown
pp 5777 - 5783; DOI:
10.1021/ja00486a031
PDF
Selenium-77 nuclear magnetic resonance studies. 1. Chemical shifts, coupling constants, and relaxation times for selenium-dl-cystine, selenium-dl-methionine, and several selenium-containing transition metal complexes
W. H. Pan and John P. Fackler
pp 5783 - 5789; DOI:
10.1021/ja00486a032
PDF
Ground and excited state electron transfer processes involving fac-tricarbonylchloro(1,10-phenanthroline)rhenium(I). Electrogenerated chemiluminescence and electron transfer quenching of the lowest excited state
John C. Luong, Louis Nadjo, and Mark S. Wrighton
pp 5790 - 5795; DOI:
10.1021/ja00486a033
PDF
Photochemical generation of superoxide radicals in aqueous solutions
Richard A. Holroyd and Benon H. J. Bielski
pp 5796 - 5800; DOI:
10.1021/ja00486a034
PDF
Palladium-assisted intramolecular amination of olefins. Synthesis of nitrogen heterocycles
Louis S. Hegedus, Gary F. Allen, Joseph J. Bozell, and Edward L. Waterman
pp 5800 - 5807; DOI:
10.1021/ja00486a035
PDF
Oxidative addition and reductive elimination reactions involving platinum metallacycles
G. Brent Young and George M. Whitesides
pp 5808 - 5815; DOI:
10.1021/ja00486a036
PDF
Structure and solid-state chemistry of 3-carboxy-2-naphthalenediazonium bromide
J. Zanos Gougoutas and J. Johnson
pp 5816 - 5820; DOI:
10.1021/ja00486a037
PDF
Ozonation of nucleophiles. 10. Ethers
Philip S. Bailey and Duane A. Lerdal
pp 5820 - 5825; DOI:
10.1021/ja00486a038
PDF
Binding energies and stabilities of chloronium ions from study of the gas-phase equilibriums: R1+ + ClR2 = R1ClR2+
Dilip K. Sen Sharma and Paul Kebarle
pp 5826 - 5830; DOI:
10.1021/ja00486a039
PDF
Triplet sensitization and exciplex quenching of the photochemical reaction between phenanthrene and dimethyl fumarate
David Creed, Richard A. Caldwell, and Mary McKenney Ulrich
pp 5831 - 5841; DOI:
10.1021/ja00486a040
PDF
Laser-induced photoconversion of trans-stilbene dianions into cis-stilbene radical anions
G. Levin, B. E. Holloway, C. R. Mao, and M. Szwarc
pp 5841 - 5844; DOI:
10.1021/ja00486a041
PDF
Domino Diels-Alder reactions. 6. Domino Diels-Alder cycloadditions to 9,10-dihydrofulvalene and 11,12-dihydrosesquifulvalene. A synthetic tool for the elaboration of polycondensed alicyclic systems
Leo A. Paquette, Matthew J. Wyvratt, Howard C. Berk, and Rudi E. Moerck
pp 5845 - 5855; DOI:
10.1021/ja00486a042
PDF
Synthesis and protonation studies of syn- and anti-2,4-bishomotropone. Comparison with the behavior of epimeric 2,4-bishomocycloheptatrienols under long- and short-lived ionization conditions
Leo A. Paquette and Michael R. Detty
pp 5856 - 5863; DOI:
10.1021/ja00486a043
PDF
Synthesis and reactions of bicyclo[3.1.0]hexatrienes
William N. Washburn, Robert Zahler, and Ida Chen
pp 5863 - 5874; DOI:
10.1021/ja00486a044
PDF
Complexation chemistry of cyclohexaamyloses. 2. p-Methylcinnamate anion
Robert I. Gelb, Lowell M. Schwartz, and Daniel A. Laufer
pp 5875 - 5879; DOI:
10.1021/ja00486a045
PDF
The amide hydrogen bond and the anomalous packing of adipamide
A. T. Hagler and L. Leiserowitz
pp 5879 - 5887; DOI:
10.1021/ja00486a046
PDF
Nucleophilic ion pairs. 5. Facile cleavage of amide substrates by a hydroxamate anion in aprotic solvents. Efficient inhibition by minute amounts of water
Seiji Shinkai, Naotoshi Nakashima, and Toyoki Kunitake
pp 5887 - 5892; DOI:
10.1021/ja00486a047
PDF
Hydration of thioesters. Evaluation of the free-energy changes for the addition of water to some thioesters, rate-equilibrium correlations over very wide ranges in equilibrium constants, and a new mechanistic criterion
J. Peter Guthrie
pp 5892 - 5904; DOI:
10.1021/ja00486a048
PDF
Solvolyses of polycyclic cyclobutyl toluenesulfonate derivatives
A. F. Diaz and R. D. Miller
pp 5905 - 5910; DOI:
10.1021/ja00486a049
PDF
Tracer studies of carboxylic acids. 7. Oxygen-18 exchange of propionic acid with solvent water and with surfactant solubilized water in benzene
Terence D. Lomax and Charmian J. O'Connor
pp 5910 - 5914; DOI:
10.1021/ja00486a050
PDF
Electron transfer reactions of transition metal aminocarboxylates in the presence of micelle-forming surfactants. Catalysis by cetyltrimethylammonium bromide of the reduction of Mn(cydta)- by Co(edta)2- and Co(cydta)2-
Anil A. Bhalekar and Jan B. F. N. Engberts
pp 5914 - 5920; DOI:
10.1021/ja00486a051
PDF
Preparation and kinetic properties of cysteine surfactants
Robert A. Moss, Thomas J. Lukas, and Robert C. Nahas
pp 5920 - 5927; DOI:
10.1021/ja00486a052
PDF
Synthesis of bile pigments. 9. Chemical total synthesis of (+)-(2R,16R)- and (+)-(2S,16R)-phycoerythrobilin dimethyl ester
A. Gossauer and J. P. Weller
pp 5928 - 5933; DOI:
10.1021/ja00486a053
PDF
Glyoxalase I enzyme studies. 4. General base catalyzed enediol proton transfer rearrangement of methyl- and phenylglyoxalglutathionylhemithiol acetal to S-lactoyl- and S-mandeloylglutathione followed by hydrolysis. A model for the glyoxalase enzyme system
Stan S. Hall, Arthur M. Doweyko, and Frank Jordan
pp 5934 - 5939; DOI:
10.1021/ja00486a054
PDF
Resonance Raman spectra of copper-sulfur complexes and the blue copper protein question
Nancy S. Ferris, William H. Woodruff, David B. Rorabacher, T. E. Jones, and L. A. Ochrymowycz
pp 5939 - 5942; DOI:
10.1021/ja00486a055
PDF
Transmutation of natural amino acid residues: replacement of sulfur by oxygen in derivatives of cysteine and other mercaptans
Sue Kirkman and Richard Wolfenden
pp 5943 - 5944; DOI:
10.1021/ja00486a056
PDF
A kinetic study of the Friedel-Crafts benzylation reaction in excess aromatic and in nitromethane
Franklin P. DeHaan, William D. Covey, Mark S. Anisman, Robert L. Ezelle, Joanna E. Margetan, Kurt D. Miller, Steven A. Pace, Sharon L. Pilmer, Michael J. Sollenberger, and Daryl S. Wolf
pp 5944 - 5945; DOI:
10.1021/ja00486a057
PDF
Kinetics of the silane and silylene decompositions under shock tube conditions
Charles G. Newman, Morey A. Ring, and H. Edward O'Neal
pp 5945 - 5946; DOI:
10.1021/ja00486a058
PDF
Stereospecific total synthesis of dl-helenalin: a general route to helenanolides and ambrosanolides
Yasufumi Ohfune, Paul A. Grieco, C. L. J. Wang, and G. Majetich
pp 5946 - 5948; DOI:
10.1021/ja00486a059
PDF
Nonselective proton transfer from p-cymene as the radical-cation half of an exciplex
Peter J. Wagner and Allen E. Puchalski
pp 5948 - 5949; DOI:
10.1021/ja00486a060
PDF
Structure of reactively produced choropropene cations by laser photodissociation
Robert G. Orth and Robert C. Dunbar
pp 5949 - 5951; DOI:
10.1021/ja00486a061
PDF
Luminescent probes for detergent solutions. A simple procedure for determination of the mean aggregation number of micelles
Nicholas J. Turro and Ahmad Yekta
pp 5951 - 5952; DOI:
10.1021/ja00486a062
PDF
Elucidation of the thermal isomerization mechanism for azobenzene in a cholesteric liquid crystal solvent
Jeanne M. Nerbonne and Richard G. Weiss
pp 5953 - 5954; DOI:
10.1021/ja00486a063
PDF
An isotope effect maximum for proton transfer between normal acids and bases
N. A. Bergman, Y. Chiang, and A. J. Kresge
pp 5954 - 5956; DOI:
10.1021/ja00486a064
PDF
General acid catalysis of the aminolysis of phenyl acetate by a preassociation mechanism
Michael M. Cox and William P. Jencks
pp 5956 - 5957; DOI:
10.1021/ja00486a065
PDF
New geometric isomers of vitamin A and carotenoids. 6. Fluorinated rhodopsin analogs from 10-fluoro- and 14-fluororetinal
Alfred E. Asato, Hiroyuki Matsumoto, Marlene Denny, and R. S. H. Liu
pp 5957 - 5960; DOI:
10.1021/ja00486a066
PDF
Interproton distances for the .beta.-turn residues of the peptide gramicidin S determined from nuclear Overhauser effect ratios
Claude R. Jones, Cynthia T. Sikakana, Mei-Chang Kuo, and William A. Gibbons
pp 5960 - 5961; DOI:
10.1021/ja00486a067
PDF
Kinetics of reactions in solutions under pressure. 52. Effect of pressure on concerted and stepwise sigmatropic shifts
W. J. Le Noble and M. Rajaona Daka
pp 5961 - 5962; DOI:
10.1021/ja00486a068
PDF
Multiple metal-carbon bonds. 10. Thermally stable tantalum alkylidyne complexes and the crystal structure of Ta(.eta.5-C5Me5)(CPh)(PMe3)2Cl
S. J. McLain, C. D. Wood, L. W. Messerle, R. R. Schrock, Frederick J. Hollander, Wiley J. Youngs, and Melvyn Rowen Churchill
pp 5962 - 5964; DOI:
10.1021/ja00486a069
PDF
Multiple metal-carbon bonds. 11. bisneopentylidene complexes of niobium and tantalum
J. D. Fellmann, G. A. Rupprecht, C. D. Wood, and R. R. Schrock
pp 5964 - 5966; DOI:
10.1021/ja00486a070
PDF
Reductive elimination of isobutane from an isobutyl hydride derivative of bis(pentamethylcyclopentadienyl)zirconium
Donald R. McAlister, David K. Erwin, and John E. Bercaw
pp 5966 - 5968; DOI:
10.1021/ja00486a071
PDF
The existence of colorless europium(IV)
Christian K. Jorgensen
pp 5968 - 5968; DOI:
10.1021/ja00486a072
PDF
Homogeneous catalysis of the water gas shift reaction using a platinum chloride-tin chloride system
Chien-Hong Cheng and Richard Eisenberg
pp 5968 - 5970; DOI:
10.1021/ja00486a073
PDF
Metallocenes: first models for nuclear magnetic resonance isotope shifts in paramagnetic molecules
F. H. Koehler and W. Proessdorf
pp 5970 - 5972; DOI:
10.1021/ja00486a074
PDF
Structures and energetics of planar and tetrahedral dilithiomethane. A near degeneracy of singlet and triplet electronic states
William D. Laidig and Henry F. Schaefer
pp 5972 - 5973; DOI:
10.1021/ja00486a075
PDF
Low temperature cleavage of alkanes by small nickel particles. Clustering of metal atoms in organic media. 7
Stephen C. Davis and Kenneth J. Klabunde
pp 5973 - 5974; DOI:
10.1021/ja00486a076
PDF
Intramolecular 1,4 proton transfer in the 5-hexenyl anion. The 5-hexenyl probe as a detector of both alkyl radical and anion intermediates
John F. Garst, Joseph A. Pacifici, Christopher C. Felix, and Alok Nigam
pp 5974 - 5975; DOI:
10.1021/ja00486a077
PDF
Mechanism of lipid-protein interaction in lipoproteins. A synthetic peptide-lecithin vesicle model
D. J. Kroon, J. P. Kupferberg, E. T. Kaiser, and F. J. Kezdy
pp 5975 - 5977; DOI:
10.1021/ja00486a078
PDF
Effect of phenyl substituents on the hydrolyses of trifluoroacetanilides catalyzed by imidazolyl cation and hydroxide ion
Makoto Komiyama and Myron L. Bender
pp 5977 - 5978; DOI:
10.1021/ja00486a079
PDF
Preparation and decomposition of a cis cyclic tetrazene, 1,4-dimethyl-1,2,3,4-tetraaza-2-cycloheptene
C. J. Michejda, S. R. Koepke, and D. H. Campbell
pp 5978 - 5979; DOI:
10.1021/ja00486a080
PDF
Ion-pair equilibriums in cyclic 1,2-semidiones
Glen A. Russell and C. E. Osuch
pp 5979 - 5981; DOI:
10.1021/ja00486a081
PDF
Conversion of allyl alcohols to dienes by sulfoxide and selenoxide syn elimination. Synthesis of PCB arene oxides
Hans J. Reich, Ieva L. Reich, and Susan Wollowitz
pp 5981 - 5982; DOI:
10.1021/ja00486a082
PDF
Intramolecular ligand reorganization in five-membered-ring tetraoxyselenuranes
Donald B. Denney, Dorothy Z. Denney, and Y. F. Hsu
pp 5982 - 5983; DOI:
10.1021/ja00486a083
PDF
Book Reviews

pp 5983 - 5984; DOI:
10.1021/ja00486a600
PDF

Issue 19


Heterogeneous photocatalytic decomposition of saturated carboxylic acids on titanium dioxide powder. Decarboxylative route to alkanes
Bernhard Kraeutler and Allen J. Bard
pp 5985 - 5992; DOI:
10.1021/ja00487a001
PDF
Magnetic field and isotope effects induced by hyperfine interaction in a steady state photochemical experiment
W. Bube, R. Haberkorn, and M. E. Michel-Beyerle
pp 5993 - 5995; DOI:
10.1021/ja00487a002
PDF
Electrogenerated chemiluminescence with solvated electrons in hexamethylphosphoramide. 2
Kingo Itaya, Mikio Kawai, and Shinobu Toshima
pp 5996 - 6002; DOI:
10.1021/ja00487a003
PDF
Kinetics of the protolysis of cryptands in basic aqueous solution
B. G. Cox, D. Knop, and H. Schneider
pp 6002 - 6007; DOI:
10.1021/ja00487a004
PDF
A study of the vinyl anion system. Rearrangements and formation from hydride(1-) ion and acetylene
Clifford E. Dykstra, A. J. Arduengo, and T. Fukunaga
pp 6007 - 6012; DOI:
10.1021/ja00487a005
PDF
The thermal reaction of vinylcyclopropylidene to cyclopentenylidene. An exploration of the electronic hypersurface
W. W. Schoeller and U. H. Brinker
pp 6012 - 6017; DOI:
10.1021/ja00487a006
PDF
Quantitative nonempirical estimates of the effects of orbital interactions. Applications to difluoroethylenes
F. Bernardi, A. Bottoni, N. D. Epiotis, and M. Guerra
pp 6018 - 6022; DOI:
10.1021/ja00487a007
PDF
Theoretical studies of the binding of thiols to the alkali and alkaline earth metals
Jan A. Pappas
pp 6023 - 6027; DOI:
10.1021/ja00487a008
PDF
Ionization energies of organic compounds by equilibrium measurements
Sharon G. Lias and P. Ausloos
pp 6027 - 6034; DOI:
10.1021/ja00487a009
PDF
Optically active amines. 25. Circular dichroism of 1-substituted indans
Howard E. Smith, Benjamin G. Padilla, Jon R. Neergaard, and Fu-Ming Chen
pp 6035 - 6039; DOI:
10.1021/ja00487a010
PDF
The properties of clusters in the gas phase. 2. Ammonia about metal ions
A. W. Castleman, Paul M. Holland, D. M. Lindsay, and Karen I. Peterson
pp 6039 - 6045; DOI:
10.1021/ja00487a011
PDF
Direct mixture analysis by mass-analyzed ion kinetic energy spectrometry using negative chemical ionization
Gary A. McClusky, Richard W. Kondrat, and Robert G. Cooks
pp 6045 - 6051; DOI:
10.1021/ja00487a012
PDF
Electron spin resonance studies of alkali radical ion pairs and triple ions of 1,2- and 1,4-dicarbonyl compounds
K. S. Chen and J. K. S. Wan
pp 6051 - 6056; DOI:
10.1021/ja00487a013
PDF
Nitrogen-14 nuclear quadrupole resonance spectra of coordinated imidazole
Carol I. H. Ashby, C. P. Cheng, and Theodore L. Brown
pp 6057 - 6063; DOI:
10.1021/ja00487a014
PDF
Crystal structure and nitrogen-14 nuclear quadrupole resonance spectrum of catena-.mu.-imidazolatobis(imidazole)zinc nitrate. Donor characteristics of coordinated imidazolate
Carol I. H. Ashby, C. P. Cheng, E. N. Duesler, and Theodore L. Brown
pp 6063 - 6067; DOI:
10.1021/ja00487a015
PDF
Synthesis, characterization, and structure of tri-.mu.-halogeno-hexacarbonyldirhenate(I) salts of monocationic porphyrin acids
C. P. Hrung, M. Tsutsui, D. L. Cullen, E. F. Meyer, and C. N. Morimoto
pp 6068 - 6076; DOI:
10.1021/ja00487a016
PDF
Resonance Raman spectra and vibrational modes of iron(III) tetraphenylporphine .mu.-oxo dimer. Evidence for phenyl interaction and lack of dimer splitting
J. M. Burke, J. R. Kincaid, and T. G. Spiro
pp 6077 - 6083; DOI:
10.1021/ja00487a017
PDF
Structure-sensitive resonance Raman bands of tetraphenyl and "picket fence" porphyrin-iron complexes, including an oxyhemoglobin analog
J. M. Burke, J. R. Kincaid, S. Peters, R. R. Gagne, J. P. Collman, and T. G. Spiro
pp 6083 - 6088; DOI:
10.1021/ja00487a018
PDF
Electronic structure of M4(CO)12Hn and M4Cp4Hn complexes
Roald Hoffmann, Birgitte E. R. Schilling, Robert Bau, Herbert D. Kaesz, and D. Michael P. Mingos
pp 6088 - 6093; DOI:
10.1021/ja00487a019
PDF
The band structure of the tetracyanoplatinate chain
Myung-Hwan Whangbo and Roald Hoffmann
pp 6093 - 6098; DOI:
10.1021/ja00487a020
PDF
Novel reactions of metal-metal bonds. Insertion of isocyanides and carbon monoxide into the palladium-palladium bond of some palladium(I) dimers
Linda S. Benner and Alan L. Balch
pp 6099 - 6106; DOI:
10.1021/ja00487a021
PDF
Active intermediates in the reduction of nitric oxide by ammonia over a CoY zeolite
Tokio Iizuka and Jack H. Lunsford
pp 6106 - 6110; DOI:
10.1021/ja00487a022
PDF
Organic chemistry by infrared lasers. 2. Retro-Diels-Alder reactions
Dana Garcia and Philip M. Keehn
pp 6111 - 6113; DOI:
10.1021/ja00487a023
PDF
Conformational analysis. 37. Gauche-repulsive interactions in 5-methoxy- and 5-methylthio-1,3-dithianes
Ernest L. Eliel and Eusebio Juaristi
pp 6114 - 6119; DOI:
10.1021/ja00487a024
PDF
Mechanism of carbanion addition to carbonyl compounds. Equilibriums and kinetics of substituted cyanohydrin cleavage and formation in aqueous solution. Substituted cyanohydrin proton dissociation constants
Wei-Mei Ching and Roland G. Kallen
pp 6119 - 6124; DOI:
10.1021/ja00487a025
PDF
Transition-state structure for the neutral water-catalyzed hydrolysis of ethyl trifluorothiolacetate
K. S. Venkatasubban, Kenneth R. Davis, and John L. Hogg
pp 6125 - 6128; DOI:
10.1021/ja00487a026
PDF
Gas-phase pathways for ester hydrolysis
Keiko Takashima and Jose M. Riveros
pp 6128 - 6132; DOI:
10.1021/ja00487a027
PDF
Keto-enol tautomerism of gas-phase ions. Structure of reactive 1,3-cyclohexadien-5-one radical cations
D. H. Russell, M. L. Gross, and N. M. M. Nibbering
pp 6133 - 6137; DOI:
10.1021/ja00487a028
PDF
Dimerization of the lithium, sodium, potassium, and cesium salts of diphenylethylene radical anions and the equilibriums and kinetics of their formation by attachment of electron-cation pairs. The nature of electron-cation aggregates
H. C. Wang, G. Levin, and M. Szwarc
pp 6137 - 6141; DOI:
10.1021/ja00487a029
PDF
Electron photodetachment from aliphatic molecular anions. Gas-phase electron affinities of methoxyl, tert-butoxyl, and neopentoxyl radicals
Bruce K. Janousek, Albert H. Zimmerman, Kenneth J. Reed, and John I. Brauman
pp 6142 - 6148; DOI:
10.1021/ja00487a030
PDF
Photoelectron spectra of ortho- and meta-substituted benzonorbornadienes. Relationships to regioselectivities in triplet di-.pi.-methane rearrangements
Cielo Santiago, E. J. McAlduff, K. N. Houk, R. A. Snow, and L. A. Paquette
pp 6149 - 6156; DOI:
10.1021/ja00487a031
PDF
Flash photolytic studies on the photochemical formation of five-membered sulfur heterocycles
Thomas Wolff
pp 6157 - 6159; DOI:
10.1021/ja00487a032
PDF
Synthesis and structure of a novel macrocyclic polydisulfide
M. Braid, G. T. Kokotailo, P. S. Landis, S. L. Lawton, and A. O. M. Okorodudu
pp 6160 - 6162; DOI:
10.1021/ja00487a033
PDF
Stopped-flow kinetics of proton transfer involving cyclopentadiene derivatives
Tadashi Okuyama, Yoshiya Ikenouchi, and Takayuki Fueno
pp 6162 - 6166; DOI:
10.1021/ja00487a034
PDF
Conformational effects of acetolysis of bicyclo[3.2.0]hept-6-en-2-yl and bicyclo[3.2.0]hept-2-yl derivatives. Homoallylic participation vs. .sigma. participation
Kazuyuki Yano, Masayoshi Isobe, and Kitaro Yoshida
pp 6166 - 6170; DOI:
10.1021/ja00487a035
PDF
Naphtho[b,e]dicyclobutene
Randolph P. Thummel and Wutichai Nutakul
pp 6171 - 6174; DOI:
10.1021/ja00487a036
PDF
Studies in terpene biosynthesis. Synthesis and resolution of presqualene and prephytoene alcohols
Lawrence J. Altman, Robert C. Kowerski, and Dilip R. Laungani
pp 6174 - 6182; DOI:
10.1021/ja00487a037
PDF
Model studies for anthracyclinone synthesis. The chemistry of 1-lithio-3,3,6,6-tetramethoxycyclohexa-1,4-diene, an umpolung for quinone
John S. Swenton, Daniel K. Jackson, Michael J. Manning, and Peter W. Raynolds
pp 6182 - 6188; DOI:
10.1021/ja00487a038
PDF
A regiospecific synthesis of the anthracycline aglycons, daunomycinone and adriamycinone
John S. Swenton and Peter W. Raynolds
pp 6188 - 6195; DOI:
10.1021/ja00487a039
PDF
Color dimorphism of 14-hydroxymorphinone. X-ray analysis of two different crystalline modifications
Chian C. Chiang, Wilson H. DeCamp, David Y. Curtin, Iain C. Paul, Sidney Shifrin, and Ulrich Weiss
pp 6195 - 6201; DOI:
10.1021/ja00487a040
PDF
Chemistry of anthocyanin pigments. 3. Relaxation amplitudes in pH-jump experiments
Raymond Brouillard, Bernard Delaporte, and Jacques Emile Dubois
pp 6202 - 6205; DOI:
10.1021/ja00487a041
PDF
Sterol metabolism. 44. Oxidation of cholesterol by dioxygen species
Leland L. Smith, Martin J. Kulig, Denis Miiller, and G. A. S. Ansari
pp 6206 - 6211; DOI:
10.1021/ja00487a042
PDF
Total synthesis of dl-19-hydroxyprostaglandin E1 and dl-13-cis-15-epi-19-hydroxyprostaglandin E1
C. Luethy, Peter Konstantin, and Karl G. Untch
pp 6211 - 6217; DOI:
10.1021/ja00487a043
PDF
Asymmetric total synthesis of estradiol by an intramolecular cycloaddition of benzocyclobutene derivative
Tetsuji Kametani, Hiroo Matsumoto, Hideo Nemoto, and Keiichiro Fukumoto
pp 6218 - 6220; DOI:
10.1021/ja00487a044
PDF
Field desorption mass spectrometry using needleless emitters. A study of five synthetic tripeptides as hormone models
Willi Frick, Elisabeth Barofsky, G. Doyle Daves, Douglas F. Barofsky, Ding Chang, and Karl Folkers
pp 6221 - 6225; DOI:
10.1021/ja00487a045
PDF
An unconventional approach to structure determination of isomeric cage compounds
Benzion Fuchs and Mordechai Pasternak
pp 6225 - 6228; DOI:
10.1021/ja00487a046
PDF
Photoreduction of tetraphenylporphyrins by amines in the visible. Photochemical syntheses of reduced tetraphenylporphyrins and the mechanism of photoreduction
Y. Harel and J. Manassen
pp 6228 - 6234; DOI:
10.1021/ja00487a047
PDF
Formation of the totally degenerate bicyclo[3.2.2]nonatrienyl radical by electron transfer
William N. Washburn
pp 6235 - 6236; DOI:
10.1021/ja00487a048
PDF
The role of trimethylsilylmethylsilylene in the gas-phase reactions of tetramethyldisilene
William D. Wulff, William F. Goure, and Thomas J. Barton
pp 6236 - 6238; DOI:
10.1021/ja00487a049
PDF
Simultaneous carbonylation and homologation of dimethyl ether and homologation of methyl acetate to ethyl acetate in the presence of ruthenium catalysts
Giuseppe Braca, Glauco Sbrana, Giorgio Valentini, Giampaolo Andrich, and Guglielmo Gregorio
pp 6238 - 6240; DOI:
10.1021/ja00487a050
PDF
Equilibrium isotope effect on hydrogen distribution between carbon- and metal-bound sites. A neutron diffraction study of partially deuterated decacarbonyldihydridomethylenetriosmium
R. Bruce Calvert, John R. Shapley, Arthur J. Schultz, Jack M. Williams, Steven L. Suib, and Galen D. Stucky
pp 6240 - 6241; DOI:
10.1021/ja00487a051
PDF
Reactions of dioxygen platinum(II) complexes with activated acetylenes
H. C. Clark, A. B. Goel, and C. S. Wong
pp 6241 - 6243; DOI:
10.1021/ja00487a052
PDF
Methylthiolation of allylic sulfides. A degenerate [2,3]-sigmatropic rearrangement
Jhong K. Kim, Margaret L. Kline, and Marjorie C. Caserio
pp 6243 - 6245; DOI:
10.1021/ja00487a053
PDF
Photochemical interconversion of phenylnitrene and the isomeric pyridylmethylenes
O. L. Chapman, R. S. Sheridan, and J. P. LeRoux
pp 6245 - 6247; DOI:
10.1021/ja00487a054
PDF
Effects of electric and magnetic fields on prochiral chemical reactions: macroscopic electric and magnetic fields can cause asymmetric synthesis
William Rhodes and Ralph C. Dougherty
pp 6247 - 6248; DOI:
10.1021/ja00487a055
PDF
A synthesis of human .beta.-endorphin in solution
Chrysa Tzougraki, Raymond C. Makofske, Thomas F. Gabriel, Su-Sun Wang, Rostyslaw Kutny, Johannes Meienhofer, and Choh Hao Li
pp 6248 - 6249; DOI:
10.1021/ja00487a056
PDF
A kinetic .alpha.-deuterium isotope effect for the binding of purine nucleosides to calf spleen purine nucleoside phosphorylase. Evidence for catalysis by distortion
R. L. Stein, R. Romero, H. G. Bull, and E. H. Cordes
pp 6249 - 6251; DOI:
10.1021/ja00487a057
PDF
Resonance coherent anti-Stokes Raman scattering evidence for out-of-plane heme iron displacement within 6 ns of carbon monoxide dissociation in carbon monoxide hemoglobin
R. F. Dallinger, J. R. Nestor, and T. G. Spiro
pp 6251 - 6252; DOI:
10.1021/ja00487a058
PDF
The "uncatalyzed" oxidation of sulfur(IV) in aqueous solutions
Albin Huss, Phooi Kong Lim, and C. A. Eckert
pp 6252 - 6253; DOI:
10.1021/ja00487a059
PDF
Role of anhydrovinblastine in the biosynthesis of the antitumor dimeric indole alkaloids
A. I. Scott, F. Gueritte, and S. L. Lee
pp 6253 - 6255; DOI:
10.1021/ja00487a060
PDF
Inverted redox catalysis: catalysis of substitution on ruthenium(II) by an extraordinarily labile ruthenium(III) metal center
Tadashi Matsubara and Carol Creutz
pp 6255 - 6257; DOI:
10.1021/ja00487a061
PDF
The molybdenum iodide cluster anion undecaiodotetramolybdate(2-). A new cluster type structurally related to the octaiodohexamolybdenum(4+) octahedral cluster
Steven Stensvad, Barbara J. Helland, M. W. Babich, Robert A. Jacobson, and Robert E. McCarley
pp 6257 - 6258; DOI:
10.1021/ja00487a062
PDF
A novel mode of carbonate binding. Structure of spin-paired .mu.-carbonato-bis(2,4,4,7-tetramethyl-1,5,9-triazacyclododec-1-ene)dicopper(II) perchlorate
Alan R. Davis, Frederick W. B. Einstein, Neil F. Curtis, and John W. L. Martin
pp 6258 - 6260; DOI:
10.1021/ja00487a063
PDF
Metal-ammonia solutions. 11. Gold(1-), a solvated transition metal anion
William J. Peer and J. J. Lagowski
pp 6260 - 6261; DOI:
10.1021/ja00487a064
PDF
Carbon-13-carbon-13 and carbon-13-hydrogen coupling constants in 2,2,4,4-tetramethylbicyclo[1.1.0]butane
Horst Finkelmeier and Wolfgang Luettke
pp 6261 - 6262; DOI:
10.1021/ja00487a065
PDF
New .sigma.-ethyl compounds of dimolybdenum (M.tplbond.M) and evidence for dinuclear reductive elimination with a concomitant metal-metal triple to quadruple bond transformation: Et-M.tplbond.M-Et .fwdarw. M::M + C2H4 + C2H6
Malcolm H. Chisholm, Deborah A. Haitko, and Carlos A. Murillo
pp 6262 - 6263; DOI:
10.1021/ja00487a066
PDF
Stereoselective total synthesis of racemic kalafungin and nanaomycin A
Tsung-Tee Li and Robert H. Ellison
pp 6263 - 6265; DOI:
10.1021/ja00487a067
PDF
Transverse relaxation of multiple quantum coherence in nuclear magnetic resonance as a probe of molecular motion
G. Bodenhausen, N. M. Szeverenyi, R. L. Vold, and R. R. Vold
pp 6265 - 6266; DOI:
10.1021/ja00487a068
PDF
A MINDO/3 study of some hydrogen-bonded systems
Theresa Julia Zielinski, Donna L. Breen, and Robert Rein
pp 6266 - 6267; DOI:
10.1021/ja00487a069
PDF
Hydrogen bonding in the MINDO/3 approximation
Gilles Klopman, Patricia Andreozzi, A. J. Hopfinger, O. Kikuchi, and M. J. S. Dewar
pp 6267 - 6268; DOI:
10.1021/ja00487a070
PDF
The mechanism of the Cope rearrangement
Joseph J. Gajewski and Neal D. Conrad
pp 6268 - 6269; DOI:
10.1021/ja00487a071
PDF
Variable transition-state structure in the Cope rearrangement as deduced from secondary deuterium kinetic isotope effects
Joseph J. Gajewski and Neal D. Conrad
pp 6269 - 6270; DOI:
10.1021/ja00487a072
PDF
An unusual xenon cation containing xenon-nitrogen bonds
Darryl D. DesMarteau
pp 6270 - 6271; DOI:
10.1021/ja00487a073
PDF
Stereochemistry of free-radical substitution at trivalent phosphorus. Permutational processes available for stereochemically nonrigid phosphoranyl-radical intermediates
Akira Nakanishi and Wesley G. Bentrude
pp 6271 - 6273; DOI:
10.1021/ja00487a074
PDF
The possibility of a noncentered structure for (CO)9Co3CCR2+
Birgitte E. R. Schilling and Roald Hoffmann
pp 6274 - 6274; DOI:
10.1021/ja00487a075
PDF
Pyrolysis of the carbonate tosylhydrazone salts derived from erythro- and threo-4-methylpentane-2,3-diol
Weston Thatcher Borden and Lin Hin Hoo
pp 6274 - 6276; DOI:
10.1021/ja00487a076
PDF
Wavelength dependent photoprocesses in acenaphthaquinone
Tai-Shan Fang and Lawrence A. Singer
pp 6276 - 6278; DOI:
10.1021/ja00487a077
PDF
Photorearrangements of bicyclo[3.2.1]oct-2-en-7-ones. A substituent effect study. Mechanistic studies in photochemistry. 19
Richard S. Givens and Woo Ki Chae
pp 6278 - 6280; DOI:
10.1021/ja00487a078
PDF
Anion radicals of pheophytin and chlorophyll a: their role in the primary charge separations of plant photosynthesis
I. Fujita, M. S. Davis, and J. Fajer
pp 6280 - 6282; DOI:
10.1021/ja00487a079
PDF
Regiocontrolled head-to-tail coupling of allylic boron "ate" complexes with allylic halides
Yoshinori Yamamoto and Kazuhiro Maruyama
pp 6282 - 6284; DOI:
10.1021/ja00487a080
PDF
Outer-sphere intervalence transfer
Jeff C. Curtis and Thomas J. Meyer
pp 6284 - 6286; DOI:
10.1021/ja00487a081
PDF
Photoelectrochemical cells based on electron-transfer quenching of excited states
Bill Durham and Thomas J. Meyer
pp 6286 - 6287; DOI:
10.1021/ja00487a082
PDF
Highly discriminative binding of nucleoside phosphates by a lipophilic diammonium salt embedded in a bicyclic skeleton
Iwao Tabushi, Junichi Imuta, Norihiko Seko, and Yoshiaki Kobuke
pp 6287 - 6288; DOI:
10.1021/ja00487a083
PDF
Stereochemistry of ketonization of enolpyruvate by pyruvate kinase. Evidence for its role as an intermediate
Donald J. Kuo and Irwin A. Rose
pp 6288 - 6289; DOI:
10.1021/ja00487a084
PDF
An intramolecular Diels-Alder route to eudesmane sesquiterpenes
Stephen R. Wilson and David T. Mao
pp 6289 - 6291; DOI:
10.1021/ja00487a085
PDF
Use of intramolecular [3 + 2] cycloaddition reactions in the synthesis of natural products. A stereospecific synthesis of (.+-.)-biotin from cycloheptene
Pat N. Confalone, E. Dianne Lollar, Giacomo Pizzolato, and Milan R. Uskokovic
pp 6291 - 6292; DOI:
10.1021/ja00487a086
PDF
The n value for the electrochemical reduction of 1-iododecane depends on electrolysis time
Daniel M. La Perriere, Brian C. Willett, William F. Carroll, Eric C. Torp, and Dennis G. Peters
pp 6293 - 6294; DOI:
10.1021/ja00487a087
PDF
A new synthesis of conjugated nitro cyclo olefins, unusually versatile synthetic intermediates
E. J. Corey and Herbert Estreicher
pp 6294 - 6295; DOI:
10.1021/ja00487a088
PDF
Photochemistry of enolate anions. Anion-directed photochemical cyclization of a dienone
James D. White and Richard W. Skeean
pp 6296 - 6297; DOI:
10.1021/ja00487a089
PDF
Book Reviews

pp 6297 - 6298; DOI:
10.1021/ja00487a600
PDF

Issue 20


Stable carbocations. 215. Carbon-13 nuclear magnetic resonance spectroscopic study of the benzenium, naphthalenium, and anthracenium ions
George A. Olah, John S. Staral, Gregorio Asencio, Gao Liang, David A. Forsyth, and Gheorghe D. Mateescu
pp 6299 - 6308; DOI:
10.1021/ja00488a001
PDF
Dipole moment, optical anisotropy, and molar Kerr constant of triacetin
Wayne L. Mattice and Enrique Saiz
pp 6308 - 6314; DOI:
10.1021/ja00488a002
PDF
Dynamics of light-induced redox processes in microemulsion systems
J. Kiwi and M. Graetzel
pp 6314 - 6320; DOI:
10.1021/ja00488a003
PDF
Study of the micelle formation and the effect of additives on this process in reversed micellar systems by positron annihilation techniques
Yan-Ching Jean and Hans J. Ache
pp 6320 - 6327; DOI:
10.1021/ja00488a004
PDF
Permutational isomerization of spirosulfuranes derived from catechols
Benjamin A. Belkind, Donald B. Denney, Dorothy Z. Denney, Y. F. Hsu, and G. Edwin Wilson
pp 6327 - 6329; DOI:
10.1021/ja00488a005
PDF
Effect of molecular structure on mesomorphism. 7. Enhancement of smectic-isotropic transition temperatures in binary mixtures of a new liquid crystal series: the 4-nitrophenyl 4'-n-alkoxybenzoates
Anselm C. Griffin, Richard F. Fisher, and Stephen J. Havens
pp 6329 - 6333; DOI:
10.1021/ja00488a006
PDF
Valence shell electron pair repulsions and the Pauli exclusion principle
Michael B. Hall
pp 6333 - 6338; DOI:
10.1021/ja00488a007
PDF
SCF MO calculations of nitromethane and nitromethyl anion
Joseph R. Murdoch, Andrew Streitwieser, and Sam Gabriel
pp 6338 - 6340; DOI:
10.1021/ja00488a008
PDF
An unrestricted Hartree-Fock study of the lowest triplet state of methylglyoxal and other carbonyls
Suheil F. Abdulnur
pp 6341 - 6343; DOI:
10.1021/ja00488a009
PDF
Photoelectron spectra of organic compounds. 12. Electronic structure of exo-dimethylenecycloalkanes
P. Hemmersbach, M. Klessinger, and P. Bruckmann
pp 6344 - 6347; DOI:
10.1021/ja00488a010
PDF
The assignment of the photoelectron spectrum of trans-oxalyl fluoride
W. Von Niessen, G. H. F. Diercksen, and L. S. Cederbaum
pp 6347 - 6349; DOI:
10.1021/ja00488a011
PDF
Conformational polymorphism. 2. Crystal energetics by computational substitution. Further evidence for the sensitivity of the method
A. T. Hagler and J. Bernstein
pp 6349 - 6354; DOI:
10.1021/ja00488a012
PDF
Six coordination in high-spin ferric porphyrins. A new structural type and models for aquomethemoglobin
Toshio Mashiko, Margaret E. Kastner, K. Spartalian, W. Robert Scheidt, and Christopher A. Reed
pp 6354 - 6362; DOI:
10.1021/ja00488a013
PDF
Small ring metallocycles. 4. Synthesis and chemical reactivity of cyclo-metalladisiloxanes, MSiR2OSiR2, and cyclo-metalladisilabutanes, MSiR2CH2SiR2
M. David Curtis and John Greene
pp 6362 - 6367; DOI:
10.1021/ja00488a014
PDF
Binuclear copper(II) complexes as mimics for type 3 coppers in metalloenzymes. 1. The importance of cooperative interactions between metals in the reversible multielectron transfer in bis(1,3,5-triketonato)dicopper(II) complexes
D. Earl Fenton and R. L. Lintvedt
pp 6367 - 6375; DOI:
10.1021/ja00488a015
PDF
Resonance interactions in metal chelates of o-hydroxyazo compounds. Crystal growth, structure, and spectra of 1-(2-pyridylazo)-2-naphtholatochlorocopper(II)
Gautam R. Desiraju, Henry R. Luss, and Douglas L. Smith
pp 6375 - 6382; DOI:
10.1021/ja00488a016
PDF
Metalation of ferrocene by n-butyllithium-pentamethyldiethylenetriamine
M. Walczak, K. Walczak, R. Mink, M. D. Rausch, and Galen Stucky
pp 6382 - 6388; DOI:
10.1021/ja00488a017
PDF
Nucleophilic substitution at phosphorus. The effect of ion association on the stereochemistry and rate of substitution at phosphorus in a six-membered ring phosphate
Mike Bauman and William S. Wadsworth
pp 6388 - 6394; DOI:
10.1021/ja00488a018
PDF
A phosphorus analog of .alpha.-pyrone and evidence for monomeric mesitylmetaphosphonate
Irving Sigal and Leslie Loew
pp 6394 - 6398; DOI:
10.1021/ja00488a019
PDF
Free-radical reactions of organophosphorus compounds. 9. The question of memory effects in the alkoxy-radical oxidations of cyclic trivalent phosphorus derivatives
Akira Nakanishi, Koichi Nishikida, and Weslev G. Bentrude
pp 6398 - 6402; DOI:
10.1021/ja00488a020
PDF
Free-radical reactions of organophosphorus compounds. 10. Memory effects in alkoxy-radical oxidations of trialkyl phosphites. Alkoxy group equivalence in (RO)4P.cntdot., a reexamination
Akira Nakanishi, Koichi Nishikida, and Wesley G. Bentrude
pp 6403 - 6406; DOI:
10.1021/ja00488a021
PDF
Kinetics of cyclopropane formation by 1,3-deoxystannylation. A kinetic isotope effect as a probe for the mechanism of neighboring group participation
Donald C. McWilliam, Tiruvenkatanathapuram R. Balasubramanian, and Henry G. Kuivila
pp 6407 - 6413; DOI:
10.1021/ja00488a022
PDF
.pi.,.pi.-Biradicaloid hydrocarbons. The pleiadene family. 3. A facile symmetry-forbidden thermal conversion of a polycyclic butadiene moiety to a cyclobutene
Richard P. Steiner and Josef Michl
pp 6413 - 6415; DOI:
10.1021/ja00488a023
PDF
An investigation of mesocyclic and acyclic dithioether cation radicals and dications
W. Kenneth Musker, Thomas L. Wolford, and Patricia B. Roush
pp 6416 - 6421; DOI:
10.1021/ja00488a024
PDF
Reactivity in methyl transfer reactions. 2. Leaving group effect on rates with substituted thiophenoxides
Edward S. Lewis and Steven H. Vanderpool
pp 6421 - 6424; DOI:
10.1021/ja00488a025
PDF
The reaction of carbonylcarbene with cyclic ethers. Competition between deoxygenation and insertion into the carbon-oxygen bond
Thomas R. Forbus, Philip A. Birdsong, and Philip B. Shevlin
pp 6425 - 6428; DOI:
10.1021/ja00488a026
PDF
A CIDNP study of the decomposition of aryldiazenes
William T. Evanochko and Philip B. Shevlin
pp 6428 - 6432; DOI:
10.1021/ja00488a027
PDF
Oxygenation of 3-aryl-2-hydroxyacrylic acids. The question of linear fragmentation vs. cyclization and cleavage of intermediates
Charles W. Jefford, Willy Knoepfel, and Peter A. Cadby
pp 6432 - 6436; DOI:
10.1021/ja00488a028
PDF
Reaction of singlet oxygen with norbornenyl ethers. Characterization of dioxetanes and evidence for zwitterionic peroxide precursors
Charles W. Jefford and Christian G. Rimbault
pp 6437 - 6445; DOI:
10.1021/ja00488a029
PDF
Stereoselective conversion of keto groups into methyl vinyl quaternary carbon centers
Brian L. Buckwalter, Ivor R. Burfitt, Hugh Felkin, Monique Joly-Goudket, K. Naemura, Mary F. Salomon, Ernest Wenkert, and Peter M. Wovkulich
pp 6445 - 6450; DOI:
10.1021/ja00488a030
PDF
Applications of the water-gas shift reaction. Hydroformylation and hydrohydroxymethylation with carbon monoxide and water
Richard M. Laine
pp 6451 - 6454; DOI:
10.1021/ja00488a031
PDF
General acid catalyzed imidazolidine hydrolysis. Hydrolysis of 2-(tert-butyl)-N,N'-dimethyl-1,3-imidazolidine and 2-(p-methoxyphenyl)-N-isopropyl-N'-phenyl-1,3-imidazolidine
Thomas H. Fife, J. E. C. Hutchins, and August M. Pellino
pp 6455 - 6462; DOI:
10.1021/ja00488a032
PDF
In situ studies of chemical reactions by carbon-13 Fourier transform nuclear magnetic resonance. Application to the Fischer indole synthesis
Alan W. Douglas
pp 6463 - 6469; DOI:
10.1021/ja00488a033
PDF
Stereochemistry of allylic rearrangements. 16. Ion-pair return associated with solvolysis of exo- and endo-bicyclo[3.2.1]oct-3-en-2-yl p-nitrobenzoate in aqueous acetone
Harlan L. Goering and Raymond P. Anderson
pp 6469 - 6474; DOI:
10.1021/ja00488a034
PDF
Antiallergenic 8-azapurines. Structural characterization of 9-diethylcarbamoyl-2-(2-propoxyphenyl)-8-azahypoxanthine
H. Eugene LeMay and Derek J. Hodgson
pp 6474 - 6478; DOI:
10.1021/ja00488a035
PDF
A direct synthesis of spiro-activated cyclopropanes from alkenes via the irradiation of isopropylidene diazomalonate
Tom Livinghouse and Robert V. Stevens
pp 6479 - 6482; DOI:
10.1021/ja00488a036
PDF
A new approach to substituted arene oxides. Total synthesis of senepoxide and seneol
Bruce Ganem, Gene W. Holbert, Lawrence B. Weiss, and Kikuo Ishizumi
pp 6483 - 6491; DOI:
10.1021/ja00488a037
PDF
Structure and absolute configuration of thienamycin
Georg Albers-Schoenberg, Byron H. Arison, Otto D. Hensens, Jordan Hirshfield, Karst Hoogsteen, Edward A. Kaczka, Robert E. Rhodes, Jean S. Kahan, Frederick M. Kahan, and et al.
pp 6491 - 6499; DOI:
10.1021/ja00488a038
PDF
An ab initio molecular orbital calculation of the structure of silabenzene
H. Bernhard Schlegel, Brian Coleman, and Maitland Jones
pp 6499 - 6501; DOI:
10.1021/ja00488a039
PDF
The significance of a secondary deuterium isotope effect in the photorearrangement of 1-iminopyridinium ylides
H. Kwart, D. A. Benko, J. Streith, D. J. Harris, and J. L. Schuppiser
pp 6501 - 6502; DOI:
10.1021/ja00488a040
PDF
Identification by means of heavy-atom isotope effects of a photoactivated reaction as a ground-state process
H. Kwart, D. A. Benko, J. Streith, and J. L. Schuppiser
pp 6502 - 6504; DOI:
10.1021/ja00488a041
PDF
Radical ions. 22. Radical anion and radical trianion of 1,4-bis(dimethylphosphino)benzene
W. Kaim and H. Bock
pp 6504 - 6506; DOI:
10.1021/ja00488a042
PDF
Spectral differences between "isospectral" molecules
Edgar Heilbronner and Taylor B. Jones
pp 6506 - 6507; DOI:
10.1021/ja00488a043
PDF
Molecular structure of pentaphenylethane by x-ray diffraction
Riccardo Destro, Tullio Pilati, and Massimo Simonetta
pp 6507 - 6509; DOI:
10.1021/ja00488a044
PDF
Organic photochemistry. 43. Stereoselective addition of singlet oxygen to 7-isopropylidenenorbornene derivatives. Possibility of .pi.-orbital distortion in the homoconjugated system
Keiji Okada and Toshio Mukai
pp 6509 - 6510; DOI:
10.1021/ja00488a045
PDF
Electronic control of stereoselectivity. 1. Singlet oxygen and related electrophilic additions to aryl-substituted 7-isopropylidenebenzonorbornenes
Leo A. Paquette, Larry W. Hertel, Rolf Gleiter, and Michael Boehm
pp 6510 - 6512; DOI:
10.1021/ja00488a046
PDF
Hydridocyclophosphazenes. Synthesis via organocopper reagents
Paul J. Harris and Harry R. Allcock
pp 6512 - 6513; DOI:
10.1021/ja00488a047
PDF
Photochemical generation of superoxide ion (O2-) by rose bengal and Ru(bpy)32+
Vakula S. Srinivasan, Denise Podolski, Ned J. Westrick, and Douglas C. Neckers
pp 6513 - 6515; DOI:
10.1021/ja00488a048
PDF
Reaction of singlet oxygen with a norbornadienol ether. Intramolecular interception of a zwitterionic peroxide
Charles W. Jefford and Christian G. Rimbault
pp 6515 - 6516; DOI:
10.1021/ja00488a049
PDF
1,5-Diazabicyclo[3.3.0]octadienediones (9,10-dioxabimanes). Strongly fluorescent syn isomers
Edward M. Kosower, Barak Pazhenchevsky, and Eli Hershkowitz
pp 6516 - 6518; DOI:
10.1021/ja00488a050
PDF
Picosecond studies of excited-state decay kinetics in chromium(III): trans-diisothiocyanatobis(ethylenediamine)chromium(III), Reinecke's salt, and hexaisothiocyanatochromium(III) in water and water-d2 at room temperature
Stephen C. Pyke and Maurice W. Windsor
pp 6518 - 6519; DOI:
10.1021/ja00488a051
PDF
Intramolecular Diels-Alder reactions. A new entry into bridgehead bicyclo[3.n.1]alkenes
Kenneth J. Shea and Sean Wise
pp 6519 - 6521; DOI:
10.1021/ja00488a052
PDF
A new fluorescence technique to measure the permeation of water molecules across bilayer membranes
Ruediger Lawaczeck
pp 6521 - 6523; DOI:
10.1021/ja00488a053
PDF
Cyanoketenes. Mechanism of tert-butylcyanoketene cycloaddition to methyl- and dimethylketene
Harold W. Moore and D. Scott Wilbur
pp 6523 - 6525; DOI:
10.1021/ja00488a054
PDF
Fast rearrangement of 3-quadricyclyl radical to bicyclo[3.2.0]hepta-3,6-dien-2-yl radical
Yoshio Sugiyama, Takashi Kawamura, and Teijiro Yonezawa
pp 6525 - 6526; DOI:
10.1021/ja00488a055
PDF
Infrared laser photochemistry of matrix-isolated molecules
R. A. Crocombe, N. R. Smyrl, and G. Mamantov
pp 6526 - 6527; DOI:
10.1021/ja00488a056
PDF
Applications of the water-gas shift reaction. 2. Catalytic exchange of deuterium for hydrogen at saturated carbon
R. M. Laine, D. W. Thomas, L. W. Cary, and S. E. Buttrill
pp 6527 - 6528; DOI:
10.1021/ja00488a057
PDF
Correlation time measurements of amino acid side chains from proton selective spin-lattice relaxation rates
Neri Niccolai, Maria de la P. Leon de Miles, Sean P. Hehir, and William A. Gibbons
pp 6528 - 6529; DOI:
10.1021/ja00488a058
PDF
Ultraviolet resonance Raman study of oxytyrosinase. Comparison with oxyhemocyanins
Nancy C. Eickman, Edward I. Solomon, James A. Larrabee, Thomas G. Spiro, and Konrad Lerch
pp 6529 - 6531; DOI:
10.1021/ja00488a059
PDF
Schizophrenic substituents: the origin of anomalous substituent effects on cycloaddition regioselectivity
K. N. Houk, L. N. Domelsmith, R. W. Strozier, and Robert T. Patterson
pp 6531 - 6533; DOI:
10.1021/ja00488a060
PDF
Simultaneous observation of nuclear spin polarization and line broadening. Evidence for an alternative polarization mechanism
Marcia L. Manion-Schilling and Heinz D. Roth
pp 6533 - 6535; DOI:
10.1021/ja00488a061
PDF
Circumambulatory rearrangements of 1,7-bridged homotropylium cations
Lawrence T. Scott and William R. Brunsvold
pp 6535 - 6536; DOI:
10.1021/ja00488a062
PDF
Stereospecific total synthesis of dl-pentalenolactone
S. Danishefsky, M. Hirama, K. Gombatz, T. Harayama, E. Berman, and P. Schuda
pp 6536 - 6538; DOI:
10.1021/ja00488a063
PDF
Thione S-methylides as quasi-Wittig reagents
Edward M. Burgess and Maria C. Pulcrano
pp 6538 - 6539; DOI:
10.1021/ja00488a064
PDF
Isolation and characterization of two C11H11 cationic rearrangements
M. J. Goldstein and D. P. Warren
pp 6539 - 6541; DOI:
10.1021/ja00488a065
PDF
Quantitative analysis of two C11H11 homoallyl cationic rearrangements
M. J. Goldstein and D. P. Warren
pp 6541 - 6543; DOI:
10.1021/ja00488a066
PDF
Additions and Corrections - Stable Carbocations. 198. Formation of Allyl Cations via Protonation of Alkynes in Magic Acid Solution. Evidence for 1,2-Hydrogen and Alkyl Shifts in the Intermediate Vinyl Cations.
G. A. Olah, and H. Mayr
pp 6544 - 6544; DOI:
10.1021/ja00488a600
PDF
Additions and Corrections - Synthesis and Characterization of HOs3(CO)10(CH3), H2Os3(CO)10(CH2), and H3Os3(CO)9(CH). Interconversion of Cluster-Bound Methyl and Methylene Ligands.
R. Bruce Calvert, and John R. Shapely
pp 6544 - 6544; DOI:
10.1021/ja00488a601
PDF
Additions and Corrections - On the Characterization of Transition States by Structure-Reactivity Coefficients
David A. Jencks, and William P. Jencks
pp 6544 - 6544; DOI:
10.1021/ja00488a602
PDF
Additions and Corrections - Stereochemistry of the Hydroxypalladation of Ethylene. Evidence for Trans Addition in the Wacker Process
J. K. Stille, and R. Divakaruni
pp 6544 - 6544; DOI:
10.1021/ja00488a603
PDF
Additions and Corrections - Steroselectivity and Mechanisms of Acid-Catalyzed Additions of Acetic Acid to (E)- and (Z)-2-Butene in Acetic Acid
Daniel J. Pasto, and James F. Gadberry
pp 6544 - 6544; DOI:
10.1021/ja00488a604
PDF
Additions and Corrections - 2-Methylpentadienyl- and 2,4-Dimethylpentadienylpotassium: First Examples of U-Shaped, though Open-Chain Organometallics
Manfred Schlosser, and Günter Rauchschwalbe
pp 6544 - 6544; DOI:
10.1021/ja00488a605
PDF
Additions and Corrections - A Highly Enantioselective Synthesis of Cyclopropane Derivatives through Chiral Cobalt(II) Complex Catalyzed Carbenoid Reaction. General Scope and Factors Determining the Enantioselectivity.
Akira Nakamura, Akira Konishi, Yoshitaka Tatsuno, and Sei Otsuka
pp 6544 - 6546; DOI:
10.1021/ja00488a606
PDF
Additions and Corrections - Solvent Effects on Protomeric Equilibria: Quantitative Correlation with an Electrostatic Hydrogen-Bonding Model.
Peter Beak, and Johnny B. Covington
pp 6546 - 6546; DOI:
10.1021/ja00488a607
PDF
Book Reviews

pp 6546 - 6548; DOI:
10.1021/ja00488a608
PDF

Issue 21


Monolayer films of surfactant ester derivatives of tris(2,2'-bipyridine)ruthenium(II)2+
G. L. Gaines, P. E. Behnken, and S. J. Valenty
pp 6549 - 6559; DOI:
10.1021/ja00489a001
PDF
Hydrogen bonding of water to gas-phase ions. Structural and stereochemical effects in protonated phenols
D. P. Martinsen and S. E. Buttrill
pp 6559 - 6563; DOI:
10.1021/ja00489a002
PDF
Ionization potentials of ferricytochrome c, ferrocytochrome c, and ferricytochrome c3
Keisaku Kimura, Naoki Sato, Shojun Hino, Tatsuhiko Yagi, and Hiroo Inokuchi
pp 6564 - 6567; DOI:
10.1021/ja00489a003
PDF
Correlation of open-circuit voltage and short-circuit current of the totally illuminated, thin-layer iron-thionine photogalvanic cell with photostationary composition
Peter D. Wildes and Norman N. Lichtin
pp 6568 - 6572; DOI:
10.1021/ja00489a004
PDF
Does a methyl substituent stabilize or destabilize anions?
Addy Pross and Leo Radom
pp 6572 - 6575; DOI:
10.1021/ja00489a005
PDF
Theoretical ab initio SCF investigation of the photochemical behavior of three-membered rings. 1. Diazirine
B. Bigot, R. Ponec, A. Sevin, and A. Devaquet
pp 6575 - 6580; DOI:
10.1021/ja00489a006
PDF
Bond order orbitals and eigenvalues
Karl Jug
pp 6581 - 6586; DOI:
10.1021/ja00489a007
PDF
Cyclic and bifurcated hydrogen bonds
Ralph C. Kerns and Leland C. Allen
pp 6587 - 6594; DOI:
10.1021/ja00489a008
PDF
Speed and accuracy in molecular orbital calculations. A comparison of CNDO/2, INDO, PRDDO, STO-3G, and other methods, including AAMOM, VRDDO, and ESE MO
Thomas A. Halgren, Daniel A. Kleier, John H. Hall, Leo D. Brown, and William N. Lipscomb
pp 6595 - 6608; DOI:
10.1021/ja00489a009
PDF
Theoretical study of the [chlorine] (Cl2)2 dimer
J. Prissette and E. Kochanski
pp 6609 - 6613; DOI:
10.1021/ja00489a010
PDF
Hydrogenation of oriented monolayers of .omega.-unsaturated fatty acids supported on platinum
Michael A. Richard, John Deutch, and George M. Whitesides
pp 6613 - 6625; DOI:
10.1021/ja00489a011
PDF
Reactions of recoiling silicon atoms with phosphine-diene mixtures and the question of silylene intermediates
Rong-Juh Hwang and Peter P. Gaspar
pp 6626 - 6635; DOI:
10.1021/ja00489a012
PDF
(Polystyrylbipyridine)(tetracarbonyl)tungsten. An active, reusable heterogeneous catalyst for metathesis of internal olefins
Seizo Tamagaki, Roger J. Card, and Douglas C. Neckers
pp 6635 - 6639; DOI:
10.1021/ja00489a013
PDF
Hydrogen rearrangements of gaseous butanoic acid cations
D. J. McAdoo, D. N. Witiak, F. W. McLafferty, and J. D. Dill
pp 6639 - 6643; DOI:
10.1021/ja00489a014
PDF
Energetics and mechanism of the solid-state polymerization of diacetylenes
G. N. Patel, R. R. Chance, E. A. Turi, and Y. P. Khanna
pp 6644 - 6649; DOI:
10.1021/ja00489a015
PDF
Electronic excitation energy partitioning in dissymmetric dioxetane thermolyses. The absolute chemiluminescence yields and triplet to singlet excited state ratios for 3-acetyl-4,4-dimethyl-1,2-dioxetane
Keith A. Horn and Gary B. Schuster
pp 6649 - 6656; DOI:
10.1021/ja00489a016
PDF
Light energy conversion with chlorophyll monolayer electrodes. In vitro electrochemical simulation of photosynthetic primary processes
Tsutomu Miyasaka, Tadashi Watanabe, Akira Fujishima, and Kenichi Honda
pp 6657 - 6665; DOI:
10.1021/ja00489a017
PDF
Photoisomerization of bis(9-anthryl)methane and other linked anthracenes. The role of excimers and biradicals in photodimerization
William R. Bergmark, Guilford Jones, Thomas E. Reinhardt, and Arthur M. Halpern
pp 6665 - 6673; DOI:
10.1021/ja00489a018
PDF
Photochemical transformations. 22. Photo-Wagner-Meerwein rearrangements and photoreactions of some halogen derivatives in dibenzobicyclononatriene systems
Stanley J. Cristol, Dean P. Stull, and Rory D. Daussin
pp 6674 - 6678; DOI:
10.1021/ja00489a019
PDF
Intramolecular photocyclization of 2-vinylbiphenyl-like compounds. 1. A quantitative study of the cyclization under steady-state illumination
Rafik Koussini, Rene Lapouyade, and Philippe Fornier de Violet
pp 6679 - 6683; DOI:
10.1021/ja00489a020
PDF
Intramolecular photocyclization of 2-vinylbiphenyl-like compounds. 2. Detection of the intermediates and kinetic study by laser flash photolysis of 1-(o-diphenyl)-1-phenylethylene
Philippe Fornier de Violet, R. Bonneau, Rene Lapouyade, Rafik Koussini, and W. R. Ware
pp 6683 - 6687; DOI:
10.1021/ja00489a021
PDF
.pi.,.pi.-Biradicaloid hydrocarbons. The pleiadene family. 4. Involvement of upper and/or hot excited singlet and triplet states in a photochemical conversion of a polycyclic cyclobutene to a butadiene
Alain Castellan, Jaroslav Kolc, and Josef Michl
pp 6687 - 6692; DOI:
10.1021/ja00489a022
PDF
Upper and/or hot excited states in organic photochemistry in dense media. A cycloreversion in a polycyclic cyclobutene
Mark A. Souto, Jaroslav Kolc, and Josef Michl
pp 6692 - 6696; DOI:
10.1021/ja00489a023
PDF
Thermal rearrangements of 1,2-dihydropyridines
Iltifat Hasan and Frank W. Fowler
pp 6696 - 6699; DOI:
10.1021/ja00489a024
PDF
Concurrent general acid and general base catalysis in the hydrolysis of an imidate ester. I. Monofunctional catalysis
Yin-Nan Lee and Gaston L. Schmir
pp 6700 - 6707; DOI:
10.1021/ja00489a025
PDF
Structure-reactivity coefficients for general acid catalysis of semicarbazone formation
Lance H. Funderburk and William P. Jencks
pp 6708 - 6714; DOI:
10.1021/ja00489a026
PDF
O6,5'-Cyclo-5,6-dihydro-2'-deoxyuridine. Novel deoxyuridine photoproducts
Jean Cadet, Lou-Sing Kan, and Shih Yi Wang
pp 6715 - 6720; DOI:
10.1021/ja00489a027
PDF
The Fischer indole synthesis and pinacol rearrangement in the mass spectrometer
G. L. Glish and R. G. Cooks
pp 6720 - 6725; DOI:
10.1021/ja00489a028
PDF
Structure of a hydrated sodium-lasalocid A (X-537A) dimer: an intermediate in complex formation
G. David Smith, William L. Duax, and Suzanne Fortier
pp 6725 - 6727; DOI:
10.1021/ja00489a029
PDF
Fungal extractives. 12. Construction of the vellerane skeleton with total syntheses of racemic velleral, vellerolactone, and pyrovellerolactone. Revised structures
Jan Froborg and Goran Magnusson
pp 6728 - 6733; DOI:
10.1021/ja00489a030
PDF
Stereochemistry of macrolides. 3. X-ray crystal structure analysis of 11,4''-bis[O-(p-bromobenzoyl)]oleandomycin
Haruo Ogura, Kimio Furuhata, Yoshinori Harada, and Yoichi Iitaka
pp 6733 - 6737; DOI:
10.1021/ja00489a031
PDF
Carbon-13 and proton nuclear magnetic resonance studies of gangliosides
Patricia L. Harris and Edward R. Thornton
pp 6738 - 6745; DOI:
10.1021/ja00489a032
PDF
Nuclear magnetic resonance studies of catecholamines. Temperature and solvent effects on the association with adenosine triphosphate and its divalent metal ion chelates
Joseph Granot
pp 6745 - 6749; DOI:
10.1021/ja00489a033
PDF
Isolation and identification of thymine products from DNA .gamma. irradiated in oxygen-free aqueous solutions
Robert Teoule, Andre Bonicel, Christian Bert, and Brigitte Fouque
pp 6749 - 6750; DOI:
10.1021/ja00489a034
PDF
Configuration of the tert-butyl radical
D. Griller, K. U. Ingold, P. J. Krusic, and H. Fischer
pp 6750 - 6752; DOI:
10.1021/ja00489a035
PDF
Peptide formation in the presence of a metal ion protecting group. Pentaammine cobalt(III)-peptide complexes
Stephan S. Isied and Christa G. Kuehn
pp 6752 - 6754; DOI:
10.1021/ja00489a036
PDF
Binuclear bridging imidazolate complexes of cobalt and ruthenium
Stephan S. Isied and C. G. Kuehn
pp 6754 - 6756; DOI:
10.1021/ja00489a037
PDF
A novel functionalization of prostaglandin skeleton. Addition of thallium triacetate to PGF2.alpha. methyl ester
Vilmos Simonidesz, Zsuzsa Gombos-Visky, Gabor Kovacs, Eszter Baitz-Gacs, and Lajos Radics
pp 6756 - 6757; DOI:
10.1021/ja00489a038
PDF
Biosynthesis of the antitumor antibiotic pactamycin. A methionine-derived ethyl group and a C7N unit
Dwight D. Weller and Kenneth L. Rinehart
pp 6757 - 6760; DOI:
10.1021/ja00489a039
PDF
Decomposition of meso- and dl-3,4-diethyl-3,4-dimethyldiazetine (a 1,2-diaza-1-cyclobutene)
Dabney K. White and Frederick D. Greene
pp 6760 - 6761; DOI:
10.1021/ja00489a040
PDF
The observable cyclodecyl cation. A novel secondary hydrogen-bridged carbocation
R. P. Kirchen, T. S. Sorensen, and K. Wagstaff
pp 6761 - 6763; DOI:
10.1021/ja00489a041
PDF
"Tailored detection" of nuclear magnetic resonance signals: application to the assignment of carbon-13 spectra
Gareth A. Morris and Ray Freeman
pp 6763 - 6764; DOI:
10.1021/ja00489a042
PDF
Angle and torsional strains as tools for enhancing the kinetic stability of .beta.-hydroperoxy ketones
Leo A. Paquette, Richard V. C. Carr, and Francois Bellamy
pp 6764 - 6766; DOI:
10.1021/ja00489a043
PDF
.alpha.-Silyloxy and .alpha.-hydroxy manganese alkyls. Generation via a new five-membered metallocycle
J. A. Gladysz, J. C. Selover, and C. E. Strouse
pp 6766 - 6768; DOI:
10.1021/ja00489a044
PDF
Micelle-enzyme analogy: stereochemical and substrate selectivity
S. I. Goldberg, N. Baba, R. L. Green, R. Pandian, J. Stowers, and R. B. Dunlap
pp 6768 - 6769; DOI:
10.1021/ja00489a045
PDF
Structural changes upon oxygenation of an iron(II)(porphyrinato)(imidazole) complex
Geoffrey B. Jameson, Frank S. Molinaro, James A. Ibers, James P. Collman, John I. Brauman, Eric Rose, and Kenneth S. Suslick
pp 6769 - 6770; DOI:
10.1021/ja00489a046
PDF
Chemical reduction of .eta.5-cyclopentadienyldicarbonylrhodium. Crystal and molecular structure of an anionic trinuclear rhodium cluster with "semi-triple-bridging" carbonyl ligands
William D. Jones, Mary Ann White, and Robert G. Bergman
pp 6770 - 6772; DOI:
10.1021/ja00489a047
PDF
Polyoxoanion supported organometallics: synthesis and characterization of .alpha.[(.eta.5-C5H5)Ti(PW11O39)]4-
R. K. C. Ho and W. G. Klemperer
pp 6772 - 6774; DOI:
10.1021/ja00489a048
PDF
Multiple metal-carbon bonds. 12. Tungsten and molybdenum neopentylidyne and some tungsten neopentylidene complexes
D. N. Clark and R. R. Schrock
pp 6774 - 6776; DOI:
10.1021/ja00489a049
PDF
Relative extinction coefficient measurements for naked silver atom clusters, Ag1,2,3,by photoaggregation techniques
Steven A. Mitchell and Geoffrey A. Ozin
pp 6776 - 6777; DOI:
10.1021/ja00489a050
PDF
Structural identification of the extruded cores of the active centers of iron-sulfur proteins by fluorine-19 nuclear magnetic resonance spectroscopy. Application to milk xanthine oxidase
Donald M. Kurtz, Geoffrey B. Wong, and R. H. Holm
pp 6777 - 6779; DOI:
10.1021/ja00489a051
PDF
Stereochemical effects on anion mass spectra of cyclic diols. Negative chemical ionization, collisional activation, and metastable ion spectra
F. J. Winkler and D. Stahl
pp 6779 - 6780; DOI:
10.1021/ja00489a052
PDF
A synthesis of (.+-.)-3-aminonocardicinic acid (3-ANA)
Harry H. Wasserman and Dennis J. Hlasta
pp 6780 - 6781; DOI:
10.1021/ja00489a053
PDF
Classical configurations associated with nonclassical molecules: three carboranes as examples
R. Nicholas Camp, Dennis S. Marynick, Glenn D. Graham, and William N. Lipscomb
pp 6781 - 6783; DOI:
10.1021/ja00489a054
PDF
Arsaacetylenes, RC.tplbond.As, as ligands in dicobalt hexacarbonyl complexes: novel main group element-transition metal hybrid cluster compounds
Dietmar Seyferth and Joseph S. Merola
pp 6783 - 6784; DOI:
10.1021/ja00489a055
PDF
Structure of antibiotic X-14547A, a carboxylic acid ionophore produced by Streptomyces antibioticus, NRRL 8167
John W. Westley, Ralph H. Evans, Chao-Min Liu, Theron Hermann, and John F. Blount
pp 6784 - 6786; DOI:
10.1021/ja00489a056
PDF
Structure, absolute configuration, and total synthesis of an acid-catalyzed rearrangement product of bicyclomycin
Hans Maag, John F. Blount, David L. Coffen, Thomas V. Steppe, and Frederick Wong
pp 6786 - 6788; DOI:
10.1021/ja00489a057
PDF
Elusive carbenes. Olefinic capture of cyclopropylchlorocarbene and related species
Robert A. Moss and Mary E. Fantina
pp 6788 - 6790; DOI:
10.1021/ja00489a058
PDF
"Water splitting" by titanium exchanged zeolite A
Steven M. Kuznicki and Edward M. Eyring
pp 6790 - 6791; DOI:
10.1021/ja00489a059
PDF
Structure of neosaxitoxin
Yuzuru Shimizu, Chien-Ping Hsu, William E. Fallon, Yasukatsu Oshima, Iwao Miura, and Koji Nakanishi
pp 6791 - 6793; DOI:
10.1021/ja00489a060
PDF
Book Reviews

pp 6793 - 6800; DOI:
10.1021/ja00489a600
PDF

Issue 22


Magnetic circular dichroism of cyclic .pi.-electron systems. 1. Algebraic solution of the perimeter model for the A and B terms of high-symmetry systems with a (4N + 2)-electron [n]annulene perimeter
Josef Michl
pp 6801 - 6811; DOI:
10.1021/ja00490a001
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 2. Algebraic solution of the perimeter model for the B terms of systems with a (4N + 2)-electron [n]annulene perimeter
Josef Michl
pp 6812 - 6818; DOI:
10.1021/ja00490a002
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 3. Classification of cyclic .pi. chromophores with a (4N + 2)-electron [n]annulene perimeter and general rules for substituent effects on the MCD spectra of soft chromophores
Josef Michl
pp 6819 - 6824; DOI:
10.1021/ja00490a003
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 4. Aza analogs of benzene
Alain Castellan and Josef Michl
pp 6824 - 6827; DOI:
10.1021/ja00490a004
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 5. Derivatives of pyridine
Susan L. Wallace, Alain Castellan, Danielle Muller, and Josef Michl
pp 6828 - 6834; DOI:
10.1021/ja00490a005
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 6. Pyridones and related heterocycles
Ivan Jonas and Josef Michl
pp 6834 - 6838; DOI:
10.1021/ja00490a006
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 7. Aza analogs of naphthalene
Milan Vasak, Michael R. Whipple, and Josef Michl
pp 6838 - 6843; DOI:
10.1021/ja00490a007
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 8. Derivatives of naphthalene
Michael R. Whipple, Milan Vasak, and Josef Michl
pp 6844 - 6852; DOI:
10.1021/ja00490a008
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 9. Aminoquinolines and aminoisoquinolines
Mark A. Souto and Josef Michl
pp 6853 - 6857; DOI:
10.1021/ja00490a009
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 10. Quinolones, isoquinolones, and related heterocycles
Dale Otteson and Josef Michl
pp 6857 - 6861; DOI:
10.1021/ja00490a010
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 11. Derivatives and aza analogues of anthracene
Richard P. Steiner and Josef Michl
pp 6861 - 6867; DOI:
10.1021/ja00490a011
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 12. Aza analogs of phenanthrene
Milan Vasak, Michael R. Whipple, and Josef Michl
pp 6867 - 6871; DOI:
10.1021/ja00490a012
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 13. Derivatives of pyrene
Milan Vasak, Michael R. Whipple, A. Berg, and Josef Michl
pp 6872 - 6877; DOI:
10.1021/ja00490a013
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 14. Derivatives of azulene
Wolfgang Gerhartz and Josef Michl
pp 6877 - 6881; DOI:
10.1021/ja00490a014
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 15. Benzazulenes
Dale Otteson, Christian Jutz, and Josef Michl
pp 6882 - 6883; DOI:
10.1021/ja00490a015
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 16. Derivatives of acenaphthylene
John W. Kenney, David A. Herold, J. Michl, and Josef Michl
pp 6884 - 6887; DOI:
10.1021/ja00490a016
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 17. Derivatives of fluoranthene
Genomarta P. Dalgaard and Josef Michl
pp 6887 - 6892; DOI:
10.1021/ja00490a017
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 18. Benzofluoranthenes
Mark A. Souto, Dale Otteson, and Josef Michl
pp 6892 - 6898; DOI:
10.1021/ja00490a018
PDF
Liquid crystals composed of N-acylamino acids. I. Circular dichroism and selective light transmission in cholesteric liquid crystals composed of N-acylamino acids and organic solvents
Kazutami Sakamoto, Ryonosuke Yoshida, Masahiro Hatano, and Taro Tachibana
pp 6898 - 6902; DOI:
10.1021/ja00490a019
PDF
Anisotropic ring-carbon chemical shifts in arene chromium tricarbonyl complexes
M. M. Maricq, J. S. Waugh, J. L. Fletcher, and M. J. McGlinchey
pp 6902 - 6904; DOI:
10.1021/ja00490a020
PDF
Solvent isotope effect on the rate of methoxyl exchange between methyl borate and methanol
William C. Hutton and Thomas I. Crowell
pp 6904 - 6907; DOI:
10.1021/ja00490a021
PDF
The photoelectron spectrum of 1,1-difluoroallene. On .pi. electron donation and withdrawal by fluorine
L. N. Domelsmith, K. N. Houk, C. Piedrahita, and W. J. Dolbier
pp 6908 - 6911; DOI:
10.1021/ja00490a022
PDF
Analysis of the topological features of the conformational hypersurface of n-butane
Michael R. Peterson and Imre G. Csizmadia
pp 6911 - 6916; DOI:
10.1021/ja00490a023
PDF
A theoretical study of hydrogen bonding in malonaldehyde
J. Catalan, M. Yanez, and J. I. Fernandez-Alonso
pp 6917 - 6919; DOI:
10.1021/ja00490a024
PDF
Is antiaromaticity absolute?
Nathan L. Bauld, Terry L. Welsher, James Cessac, and Robert L. Holloway
pp 6920 - 6924; DOI:
10.1021/ja00490a025
PDF
Theoretical ab initio SCF investigation of the photochemical behavior of three-membered rings. 2. Azirine
B. Bigot, A. Sevin, and A. Devaquet
pp 6924 - 6929; DOI:
10.1021/ja00490a026
PDF
Low-lying electronic states of unsaturated carbenes. Comparison with methylene
John W. Kenney, Jack Simons, George D. Purvis, and Rodney J. Bartlett
pp 6930 - 6936; DOI:
10.1021/ja00490a027
PDF
A molecular orbital study of protonation. 5. Equilibrium structures and energies of ions R2COH+
Janet E. Del Bene and Sally Radovick
pp 6936 - 6941; DOI:
10.1021/ja00490a028
PDF
Theoretical study of some ethylene-halogen molecule (chlorine, bromine, iodine) complexes at large and intermediate distances from ab initio calculations
J. Prissette, G. Seger, and E. Kochanski
pp 6941 - 6947; DOI:
10.1021/ja00490a029
PDF
Characterization of the asymmetric nitric oxide dimer O:N:O:N by resonance Raman and infrared spectroscopy
J. R. Ohlsen and J. Laane
pp 6948 - 6955; DOI:
10.1021/ja00490a030
PDF
Laser photoluminescence of matrix-isolated calcium-magnesium (CaMg), strontium-magnesium (SrMg), and strontium-calcium (SrCa) in solid argon at 12 K
John C. Miller and Lester Andrews
pp 6956 - 6960; DOI:
10.1021/ja00490a031
PDF
Excited state proton transfer of ruthenium(II) complexes of 4,7-dihydroxy-1,10-phenanthroline. Increased acidity in the excited state
Paul J. Giordano, C. Randolph Bock, and Mark S. Wrighton
pp 6960 - 6965; DOI:
10.1021/ja00490a032
PDF
Chemistry of zero- and low-valent metal phosphine and phosphite complexes. 4. The iron system
T. V. Harris, J. W. Rathke, and E. L. Muetterties
pp 6966 - 6977; DOI:
10.1021/ja00490a033
PDF
An examination of the reductive-elimination reaction. Chemistry of XYCo[P(OR)3]z+ complexes
E. L. Muetterties and Patricia L. Watson
pp 6978 - 6989; DOI:
10.1021/ja00490a034
PDF
The octahedral hexasilver molecule. Seven crystal structures of variously vacuum-dehydrated fully silver(1+)-exchanged zeolite A
Yang Kim and Karl Seff
pp 6989 - 6997; DOI:
10.1021/ja00490a035
PDF
Crystal structures of cyclopropane complexes of cobalt(II) and manganese(II) in partially exchanged zeolite A
Wyona V. Cruz, Peter C. W. Leung, and Karl Seff
pp 6997 - 7003; DOI:
10.1021/ja00490a036
PDF
Proton, phosphorus-31, and carbon-13 nuclear magnetic resonance nonequivalence of diastereomeric salts of chiral phosphorus thio acids with optically active amines. A method for determining the optical purity and configuration of chiral phosphorus thio acids
Marian Mikolajczyk, Jan Omelanczuk, Miroslawa Leitloff, Jozef Drabowicz, Andrzej Ejchart, and Janusz Jurczak
pp 7003 - 7008; DOI:
10.1021/ja00490a037
PDF
Studies of the spin correlation effect in acyclic azo compounds
Paul S. Engel, David J. Bishop, and Matthew A. Page
pp 7009 - 7017; DOI:
10.1021/ja00490a038
PDF
Single-electron oxidation equilibriums of tetraalkylhydrazines. 2. Tetraalkyl-2-tetrazenes as models for steric effects, and the importance of alkyl group charge delocalization anisotropy
S. F. Nelsen, V. E. Peacock, and C. R. Kessel
pp 7017 - 7023; DOI:
10.1021/ja00490a039
PDF
Transition states for the hydrolysis of 4-nitroacetanilide and 4-nitrothioacetanilide in varying concentrations of sulfuric acid
John T. Edward, Gary D. Derdall, and Sin Cheong Wong
pp 7023 - 7027; DOI:
10.1021/ja00490a040
PDF
The reactivity of oxocarbonium ions. 1. Detection as transient intermediates in the hydrolysis of ketals and ortho esters
Robert A. McClelland and Mahmood Ahmad
pp 7027 - 7031; DOI:
10.1021/ja00490a041
PDF
The reactivity of oxocarbonium ions. 2. Hydrolysis in sulfuric acid solutions and estimates of reactivity in water
Robert A. McClelland and Mahmood Ahmad
pp 7031 - 7036; DOI:
10.1021/ja00490a042
PDF
Kinetic hydrogen isotope effects in the concerted mechanism for the hydrolysis of acetals, ketals, and ortho esters
Robert Eliason and Maurice M. Kreevoy
pp 7037 - 7041; DOI:
10.1021/ja00490a043
PDF
Vinylic cations from solvolysis. 26. Solvolysis of 9-(.alpha.-chlorovinyl)anthracene and selectivity of the derived ion
Zvi Rappoport, Pnina Shulman, and Mordechai Thuval
pp 7041 - 7051; DOI:
10.1021/ja00490a044
PDF
Potential energy profile for gas-phase, unimolecular reactions of ionized acetic acid and its enol. The barrier to a 1,3-hydrogen migration
Helmut Schwarz, Dudley H. Williams, and Chrysostomos Wesdemiotis
pp 7052 - 7055; DOI:
10.1021/ja00490a045
PDF
Lactim-lactam tautomeric equilibriums of 2-hydroxypyridines. 1. Cation binding, dimerization, and interconversion mechanism in aprotic solvents. A spectroscopic and temperature-jump kinetic study
O. Bensaude, M. Chevrier, and J. E. Dubois
pp 7055 - 7060; DOI:
10.1021/ja00490a046
PDF
The first d0 metallooxaziridines. Amination of olefins
Lanny S. Liebeskind, K. Barry Sharpless, Robert D. Wilson, and James A. Ibers
pp 7061 - 7063; DOI:
10.1021/ja00490a047
PDF
Group 6 metallooxaziridines: preparation, characterization, and reaction with cyclohexanone
D. A. Muccigrosso, S. E. Jacobson, P. A. Apgar, and F. Mares
pp 7063 - 7065; DOI:
10.1021/ja00490a048
PDF
Amino-substituted sulfonium salts. Synthesis and stereochemistry
Alan H. Cowley, Donald J. Pagel, and Michael L. Walker
pp 7065 - 7066; DOI:
10.1021/ja00490a049
PDF
Solvolysis of cyclooctatetraenyl trifluoromethanesulfonate
Michael Hanack and Linhard Sproesser
pp 7066 - 7068; DOI:
10.1021/ja00490a050
PDF
Unusual coordination of the .alpha.-dioxime ligand in bis(camphorquinone dioximato)nickel(II)
Man Sheung Ma, Robert J. Angelici, Douglas Powell, and Robert A. Jacobson
pp 7068 - 7069; DOI:
10.1021/ja00490a051
PDF
Preparation of macrolides via the Wittig reaction. A total synthesis of (-)-vermiculine
Kaspar F. Burri, Robert A. Cardone, Wen Yean Chen, and Perry Rosen
pp 7069 - 7071; DOI:
10.1021/ja00490a052
PDF
Functional polymers. 1. Poly(cinchona alkaloid-co-acrylonitrile)s. New polymer catalysts for asymmetric synthesis
Norio Kobayashi and Kiyoko Iwai
pp 7071 - 7072; DOI:
10.1021/ja00490a053
PDF
Persistent cyclopropyl radicals with novel configurations
V. Malatesta, D. Forrest, and K. U. Ingold
pp 7073 - 7074; DOI:
10.1021/ja00490a054
PDF
Reactions of hexamethylsilacyclopropane with carbonyl compounds in the presence of tertiary phosphines. The possible intermediacy of a dimethylsilylenephosphorane
Dietmar Seyferth and Thomas F. O. Lim
pp 7074 - 7075; DOI:
10.1021/ja00490a055
PDF
.gamma.-Methyl substituent effect on vicinal coupling constants involving carbon-13
M. Barfield, J. L. Marshall, E. D. Canada, and M. R. Willcott
pp 7075 - 7077; DOI:
10.1021/ja00490a056
PDF
Sulfuranes. 37. Tricoordinate hypervalent sulfur species. Sulfuranide anions
Patrick H. W. Lau and J. C. Martin
pp 7077 - 7079; DOI:
10.1021/ja00490a057
PDF
Revision of the structure of xylomollin
Masami Nakane, C. Richard Hutchinson, Donna VanEngen, and Jon Clardy
pp 7079 - 7080; DOI:
10.1021/ja00490a058
PDF
Evidence for a preassociation mechanism for acid catalyzed addition of semicarbazide to 4-methoxyphenyl formate
Juan J. Ortiz and E. H. Cordes
pp 7080 - 7082; DOI:
10.1021/ja00490a059
PDF
Rates of degenerate 1,2-hydride and 1,2-methide shifts from the carbon-13 nuclear magnetic resonance spectra of tertiary alkyl cations
Martin Saunders and Mandes R. Kates
pp 7082 - 7083; DOI:
10.1021/ja00490a060
PDF
Catalytic decarbonylation of aldehydes
D. H. Doughty and L. H. Pignolet
pp 7083 - 7085; DOI:
10.1021/ja00490a061
PDF
Concerning the structure and modes of degenerate rearrangement of the nonclassical 1-methylcyclobutyl and related carbocations
George A. Olah, G. K. Surya Prakash, Daniel J. Donovan, and Issa Yavari
pp 7085 - 7086; DOI:
10.1021/ja00490a062
PDF
Substitution reactions which proceed via radical anion intermediates. 19. Direct conversion of nitro compounds to thiols
Nathan Kornblum and Joerg Widmer
pp 7086 - 7088; DOI:
10.1021/ja00490a063
PDF
Vibrational circular dichroism and individual chiral centers. An example from the sugars
Curtis Marcott, Henry A. Havel, John Overend, and Albert Moscowitz
pp 7088 - 7089; DOI:
10.1021/ja00490a064
PDF
Organic photochemistry with 6.7-eV photons: bicyclo[n.1.0]alkanes and tricyclo[3.2.1.02,4]octane
R. Srinivasan and Jose A. Ors
pp 7089 - 7091; DOI:
10.1021/ja00490a065
PDF
Photochemical reactions in organized monolayer assemblies. 11. Ketone photoreactivity as a probe of the microenvironment: photochemistry of the surfactant ketone 16-oxo-16-p-tolylhexadecanoic acid in monolayers, micelles, and solution
Paul R. Worsham, David W. Eaker, and David G. Whitten
pp 7091 - 7093; DOI:
10.1021/ja00490a066
PDF
Geometry of transition states involving allylic hydrogen abstraction elucidated by isotope effect studies
H. Kwart, D. A. Benko, and M. E. Bromberg
pp 7093 - 7094; DOI:
10.1021/ja00490a067
PDF
Transient proton-proton Overhauser effects in horse ferrocytochrome c
Sidney L. Gordon and Kurt Wuethrich
pp 7094 - 7096; DOI:
10.1021/ja00490a068
PDF
Analogs of metallic lattices in rhodium carbonyl cluster chemistry. Synthesis and x-ray structure of the [Rh15(.mu.-CO)14(CO)13]3- and [Rh14(.mu.-CO)16(CO)9]4- anions showing a stepwise hexagonal close-packed/body-centered cubic interconversion
Secondo Martinengo, Gianfranco Ciani, Angelo Sironi, and Paolo Chini
pp 7096 - 7098; DOI:
10.1021/ja00490a069
PDF
Diels-Alder cycloaddition of juglone derivatives: elucidation of factors influencing regiochemical control
Robert K. Boeckman, Terence M. Dolak, and Kenneth O. Culos
pp 7098 - 7100; DOI:
10.1021/ja00490a070
PDF
Lewis acid induced cyclization of vinyl ether-epoxides: a new stereospecific route to carbocyclic ketones and ketolactones
Robert K. Boeckman, Kenneth J. Bruza, and Gerald R. Heinrich
pp 7101 - 7103; DOI:
10.1021/ja00490a071
PDF
Hydroxysulfenylation of olefins. An olefin cleavage with functional group differentiation
Barry M. Trost, Masahito Ochiai, and Patrick G. McDougal
pp 7103 - 7106; DOI:
10.1021/ja00490a072
PDF
X-ray evidence for the metal ion bridged intra- and intermolecular stacking interactions between nucleotide bases and aromatic heterocyclic rings within the ternary complex [Cu(5'-AMP)(bpy)(H2O)]2.(NO3)2.6H2O
Katsuyuki Aoki
pp 7106 - 7108; DOI:
10.1021/ja00490a073
PDF
Formation, trapping, and lifetime of the biradicals generated in the photochemistry of valeraldehyde
M. V. Encinas and J. C. Scaiano
pp 7108 - 7109; DOI:
10.1021/ja00490a074
PDF
Stereochemistry of the indene phototransposition reaction and the mechanistic implications thereof
David Giacherio and Harry Morrison
pp 7109 - 7110; DOI:
10.1021/ja00490a075
PDF
Generation, diffusivity, and reactivity of singlet oxygen in polymer matrices. A convenient and sensitive chemiluminescent technique
Nicholas J. Turro, Ming-Fea Chow, and Michael A. Blaustein
pp 7110 - 7112; DOI:
10.1021/ja00490a076
PDF
Bis(pentamethylcyclopentadienyl)actinide alkyls: facile activation of carbon monoxide, carbon-carbon double bond formation, and the production of unusual oxygen-bonded migratory insertion products
Juan M. Manriquez, Paul J. Fagan, Tobin J. Marks, Cynthia Secaur Day, and Victor W. Day
pp 7112 - 7114; DOI:
10.1021/ja00490a077
PDF
Novel photochemical addition reactions of iminium salts. Electron transfer initiated additions of olefins to 2-phenyl-1-pyrrolinium perchlorate
Patrick S. Mariano, Jerome L. Stavinoha, Gerard Pepe, and Edgar F. Meyer
pp 7114 - 7116; DOI:
10.1021/ja00490a078
PDF
Stereochemistry of free-radical substitution on the peroxide bond
N. A. Porter and J. R. Nixon
pp 7116 - 7117; DOI:
10.1021/ja00490a079
PDF
Chemistry at liquid-liquid interfaces. Evidence for an SN1 reaction occurring at a toluene-water interface
Steven L. Regen and Jacques J. Besse
pp 7117 - 7119; DOI:
10.1021/ja00490a080
PDF
Synthesis and thermal decomposition of homoleptic tert-butyl lanthanide complexes
Andrea L. Wayda and William J. Evans
pp 7119 - 7121; DOI:
10.1021/ja00490a081
PDF
General base catalysis and evidence for a sulfurane intermediate in the iodine oxidation of methionine
Paul R. Young and Li-Shan Hsieh
pp 7121 - 7122; DOI:
10.1021/ja00490a082
PDF
Cyclonerodiol biosynthesis and the stereochemistry of the conversion of farnesyl to nerolidyl pyrophosphate
David E. Cane, Radha Iyengar, and Ming-Shi Shiao
pp 7122 - 7125; DOI:
10.1021/ja00490a083
PDF
Nuclear magnetic resonance characterization of compounds I and II of horseradish peroxidase
Isao Morishima and Satoshi Ogawa
pp 7125 - 7127; DOI:
10.1021/ja00490a084
PDF
Rearrangement of an excited .beta.,.gamma.-unsaturated ketone generated by dioxetane thermolysis. On the T1(.pi.,.pi.*) and T2(n,.pi.*) reactivities
Manfred J. Mirbach, Andreas Henne, and Kurt Schaffner
pp 7127 - 7128; DOI:
10.1021/ja00490a085
PDF
Book Reviews

pp 7129 - 7130; DOI:
10.1021/ja00490a600
PDF

Issue 23


Optical detection of magnetic resonance measurements of the effects of pH on the triplet states of benzimidazole and purine
Peter Svejda, Richard R. Anderson, and August H. Maki
pp 7131 - 7138; DOI:
10.1021/ja00491a001
PDF
Methylmercury as a spin-orbit probe. Effect of complexing on the excited state properties of tryptophan, tryptamine, and benzimidazole
Peter Svejda, August H. Maki, and Richard R. Anderson
pp 7138 - 7145; DOI:
10.1021/ja00491a002
PDF
Picosecond studies of the fluorescence probe molecule 8-anilino-1-naphthalenesulfonic acid
G. W. Robinson, R. J. Robbins, G. R. Fleming, J. M. Morris, A. E. W. Knight, and R. J. S. Morrison
pp 7145 - 7150; DOI:
10.1021/ja00491a003
PDF
Intrinsic isotopic selectivity factors: carbon dioxide TEA laser photolysis of dichlorodifluoromethane
David S. King and John C. Stephenson
pp 7151 - 7155; DOI:
10.1021/ja00491a004
PDF
Carbon-13 magnetic shielding from beam-maser measurements of spin-rotation interaction in acetonitrile
S. G. Kukolich, G. Lind, M. Barfield, L. Faehl, and J. L. Marshall
pp 7155 - 7159; DOI:
10.1021/ja00491a005
PDF
Calculated carbon-13 NMR relaxation parameters for a restricted internal diffusion model. Application to methionine relaxation in dihydrofolate reductase
Robert E. London and John Avitabile
pp 7159 - 7165; DOI:
10.1021/ja00491a006
PDF
Cyclododecane. Force-field calculations and proton NMR spectra of deuterated isotopomers
Frank A. L. Anet and T. N. Rawdah
pp 7166 - 7171; DOI:
10.1021/ja00491a007
PDF
Intramolecular excimer study of rates of conformational transitions. Dependence on molecular structure and the viscosity of the medium
Merrill Goldenberg, Jack Emert, and Herbert Morawetz
pp 7171 - 7177; DOI:
10.1021/ja00491a008
PDF
Conformation analysis. 6. The molecular structure of gaseous tetrabromoformaldazine as determined by electron diffraction
Kolbjoern Hagen, Vladimir Bondybey, and Kenneth Hedberg
pp 7178 - 7180; DOI:
10.1021/ja00491a009
PDF
Mechanisms of gas-phase and liquid-phase ozonolysis
Lawrence B. Harding and William A. Goddard
pp 7180 - 7188; DOI:
10.1021/ja00491a010
PDF
Calorimetric and molecular orbital studies of hydrogen bonding between hydrogen fluoride and cyclic ethers
Mitsunori Tsuda, Hidekazu Touhara, Koichiro Nakanishi, Kazuo Kitaura, and Keiji Morokuma
pp 7189 - 7196; DOI:
10.1021/ja00491a011
PDF
Importance of electron correlation in computing molecular energies and structures of annulenes
H. Baumann
pp 7196 - 7201; DOI:
10.1021/ja00491a012
PDF
Ab initio calculation of some vertical excitation energies of N-methylacetamide
Larry E. Nitzsche and Ernest R. Davidson
pp 7201 - 7204; DOI:
10.1021/ja00491a013
PDF
Quantitative nonempirical analysis of the .pi.-conjugative effects of substituents
Fernando Bernardi, Andrea Bottoni, and Nicolaos D. Epiotis
pp 7205 - 7209; DOI:
10.1021/ja00491a014
PDF
Comment on a symmetry criterion for the necessity of including atomic d orbitals in computational basis sets
William R. Rodwell
pp 7209 - 7213; DOI:
10.1021/ja00491a015
PDF
A simple model of bond geometry and the stereoactivity of lone pairs
H. Bradford Thompson, Madeleine Wells, and Joan E. Weaver
pp 7213 - 7219; DOI:
10.1021/ja00491a016
PDF
Free energy correlation of rate constants for electron transfer quenching of excited transition metal complexes
R. Ballardini, G. Varani, M. T. Indelli, F. Scandola, and V. Balzani
pp 7219 - 7223; DOI:
10.1021/ja00491a017
PDF
Organometallic migration reactions
Heinz Berke and Roald Hoffmann
pp 7224 - 7236; DOI:
10.1021/ja00491a018
PDF
Ion association and electron transfer in reactions between copper and pentaamminepyridineruthenium complexes
Kenneth A. Norton and James K. Hurst
pp 7237 - 7242; DOI:
10.1021/ja00491a019
PDF
Thermodynamic studies on (thio iminato)cobalt(II) oxygen carriers and the effect of chelate ring substituents
Loomis S. Chen, Mark E. Koehler, Beverly C. Pestel, and Sue C. Cummings
pp 7243 - 7248; DOI:
10.1021/ja00491a020
PDF
Mixed valence interactions in di-.mu.-oxo bridged manganese complexes. Electron paramagnetic resonance and magnetic susceptibility studies
Stephen R. Cooper, G. Charles Dismukes, Melvin P. Klein, and Melvin Calvin
pp 7248 - 7252; DOI:
10.1021/ja00491a021
PDF
The dioxygen adducts of several manganese(II) porphyrins. Electron paramagnetic resonance studies
Brian M. Hoffman, Thomas Szymanski, Theodore G. Brown, and Fred Basolo
pp 7253 - 7259; DOI:
10.1021/ja00491a022
PDF
Pulse radiolysis studies of decacarbonyldimanganese(0) and halopentacarbonylmanganese(I). The pentacarbonylmanganese(0) radical
William L. Waltz, Ortfried Hackelberg, Leon M. Dorfman, and Andrew Wojcicki
pp 7259 - 7264; DOI:
10.1021/ja00491a023
PDF
Preparation of chemically derivatized platinum and gold electrode surfaces. Synthesis, characterization, and surface attachment of trichlorosilylferrocene, (1,1'-ferrocenediyl)dichlorosilane, and 1,1'-bis(triethoxysilyl)ferrocene
Mark S. Wrighton, Michael C. Palazzotto, Andrew B. Bocarsly, Jeffrey M. Bolts, Alan B. Fischer, and Louis Nadjo
pp 7264 - 7271; DOI:
10.1021/ja00491a024
PDF
Crystallographic determination of the absolute configuration at iron of a series of chiral iron alkyls. Empirical circular dichroism spectroscopic correlates
Chaw-Kuo Chou, David L. Miles, Robert Bau, and Thomas C. Flood
pp 7271 - 7278; DOI:
10.1021/ja00491a025
PDF
Stereochemistry at iron of the sulfur dioxide insertion reaction of iron alkyls. Crystallographic determination of the absolute configuration at iron of a chiral iron sulfinate
Susan L. Miles, David L. Miles, Robert Bau, and Thomas C. Flood
pp 7278 - 7282; DOI:
10.1021/ja00491a026
PDF
Studies of the ferric forms of cytochrome P-450 and chloroperoxidase by extended x-ray absotption fine structure. Characterization of the iron-nitrogen and iron-sulfur distances
Stephen P. Cramer, John H. Dawson, Keith O. Hodgson, and Lowell P. Hager
pp 7282 - 7290; DOI:
10.1021/ja00491a027
PDF
Electron spin resonance, magnetic, and x-ray crystallographic studies of a binuclear, imidazolate bridged copper(II) complex, [(TMDT)2Cu2(im)(ClO4)2](ClO4)
Chi-Lin O'Young, John C. Dewan, Henry R. Lilenthal, and Stephen J. Lippard
pp 7291 - 7300; DOI:
10.1021/ja00491a028
PDF
Preparation and chemistry of some phosphoranes containing phosphorus-sulfur bonds
Byron C. Burros, Norman J. De'Ath, Donald B. Denney, Dorothy Z. Denney, and Irving J. Kipnis
pp 7300 - 7304; DOI:
10.1021/ja00491a029
PDF
Role of through space 2p-3d overlap in the alkylation of phosphines
William E. McEwen, A. Blair Janes, Jerome W. Knapczyk, Vernon L. Kyllingstad, Wen-I Shiau, Stanley Shore, and Joanne H. Smith
pp 7304 - 7311; DOI:
10.1021/ja00491a030
PDF
Chemical consequences of through space 2p-3d overlap in the alkaline cleavage of benzyltriarylphosphonium chlorides
Glenn L. Keldsen and William E. McEwen
pp 7312 - 7317; DOI:
10.1021/ja00491a031
PDF
A study of superoxide reactivity. Reaction of potassium superoxide with alkyl halides and tosylates
Chuen-Ing Chern, Robert DiCosimo, Reynalda De Jesus, and Joseph San Filippo
pp 7317 - 7327; DOI:
10.1021/ja00491a032
PDF
Gas-phase basicities of N-methyl substituted 1,8-diaminonaphthalenes and related compounds
Yan K. Lau, P. P. S. Saluja, Paul Kebarle, and Roger W. Alder
pp 7328 - 7333; DOI:
10.1021/ja00491a033
PDF
The use of chlorine kinetic isotope effects for evaluating ion pairing in nucleophilic displacements at saturated carbon
Donald G. Graczyk, James W. Taylor, and Carl R. Turnquist
pp 7333 - 7339; DOI:
10.1021/ja00491a034
PDF
A vibronic model for IR absorption by a mixed valence anion radical
Albert H. Schroeder and Stephen Mazur
pp 7339 - 7346; DOI:
10.1021/ja00491a035
PDF
Fragmentations of alkane molecular ions
Peder Wolkoff and John L. Holmes
pp 7346 - 7352; DOI:
10.1021/ja00491a036
PDF
Organic photochemistry. 40. Photochemistry of bichromophoric molecules. Photochemistry and photophysics of 2-methylenebenzonorbornene and related nonconjugated aryl olefins in nonprotic media
Frank Scully, Tom Nylund, Fred Palensky, and Harry Morrison
pp 7352 - 7364; DOI:
10.1021/ja00491a037
PDF
Organic photochemistry. 41. Photochemistry of bichromophoric molecules. Photochemistry and photophysics of 2-methylenebenznorbornene and related molecules in protic media
Tom Nylund and Harry Morrison
pp 7364 - 7374; DOI:
10.1021/ja00491a038
PDF
Characterization and one- and two-electron redox chemistry of 1,5-dicarba-1,5-dideazaisoalloxazines (flavins)
Rebecca L. Chan and Thomas C. Bruice
pp 7375 - 7382; DOI:
10.1021/ja00491a039
PDF
Rates of formation and decomposition of tetrahedral intermediates in the hydrolysis of dimethyl aroylphosphonates. Substituent effects on a model for carboxylate ester hydrolysis
Ronald Kluger and Jik Chin
pp 7382 - 7388; DOI:
10.1021/ja00491a040
PDF
Substrate analog studies of the specificity and catalytic mechanism of D-3-hydroxybutyrate dehydrogenase
Ronald Kluger, Kurt Nakaoka, and Wing-Cheong Tsui
pp 7388 - 7392; DOI:
10.1021/ja00491a041
PDF
Pentacoordinated molecules. 28. Computer simulation of ribonuclease action on uridylyl-(3'-5')-adenosine
Robert R. Holmes, Joan A. Deiters, and Judith C. Gallucci
pp 7393 - 7402; DOI:
10.1021/ja00491a042
PDF
Deuterium NMR as a probe of the stereochemistry of enzyme reactions at prochiral centers. Deaminaton of cadaverine, catalyzed by diamine oxidase
James C. Richards and Ian D. Spenser
pp 7402 - 7404; DOI:
10.1021/ja00491a043
PDF
Energy transfer processes involving distorted excited states
V. Balzani and F. Bolletta
pp 7404 - 7405; DOI:
10.1021/ja00491a044
PDF
Bifunctional activation of carbon dioxide. Synthesis and structure of a reversible carbon dioxide carrier
Giuseppe Fachinetti, Carlo Floriani, and Pier Francesco Zanazzi
pp 7405 - 7407; DOI:
10.1021/ja00491a045
PDF
Interaction of an aliphatic hydrogen atom with a transition metal. The first direct observation of a strong carbon-hydrogen.cntdot.metal interaction derived from a single crystal neutron diffraction study of {Fe[P(OCH3)3]3(.eta.3-C8H13)}+[BF4]-
Jack M. Williams, Richard K. Brown, Arthur J. Schultz, Galen D. Stucky, and Steven D. Ittel
pp 7407 - 7409; DOI:
10.1021/ja00491a046
PDF
Polyandrocarpidines: antimicrobial and cytotoxic agents from a marine tunicate (Polyandrocarpa species) from the Gulf of California
Michael T. Cheng and Kenneth L. Rinehart
pp 7409 - 7411; DOI:
10.1021/ja00491a047
PDF
Lanthanide photochemistry initiated in f-f transitions
Terence Donohue
pp 7411 - 7413; DOI:
10.1021/ja00491a048
PDF
Applications of photoinduced electron-transfer reactions: visible light mediated redox reactions of substrates using transition metal complexes as catalysts
Patricia J. DeLaive, Charles Giannotti, and David G. Whitten
pp 7413 - 7415; DOI:
10.1021/ja00491a049
PDF
Deracemization by enantioselective protonation. A new method for the enantiomeric enrichment of .alpha.-amino acids
Lucette Duhamel and Jean Christophe Plaquevent
pp 7415 - 7416; DOI:
10.1021/ja00491a050
PDF
Metallacyclopentanes as catalysts for the linear and cyclodimerization of olefins
Robert H. Grubbs and Akira Miyashita
pp 7416 - 7418; DOI:
10.1021/ja00491a051
PDF
Carbon-carbon bond cleavage reactions in the decomposition of metallacycles
Robert H. Grubbs and Akira Miyashita
pp 7418 - 7420; DOI:
10.1021/ja00491a052
PDF
Reaction of the water-soluble reagent N-ethyl-N'-(3-dimethylaminopropyl)carbodiimide with nucleophiles: participation of the tautomeric cyclic ammonioamidine as a kinetically important intermediate
Ibrahim T. Ibrahim and Andrew Williams
pp 7420 - 7421; DOI:
10.1021/ja00491a053
PDF
Labeling of amide linkages in active site mapping: Carbonium ion and extended photoaffinity labeling approaches
Emil H. White, H. Mark Perks, and David F. Roswell
pp 7421 - 7423; DOI:
10.1021/ja00491a054
PDF
Synthesis of d-biotin via dehydrobiotin
Janis Vasilevskis, Joseph A. Gualtieri, Stanley D. Hutchings, Ronald C. West, John W. Scott, David R. Parrish, Fred T. Bizzarro, and George F. Field
pp 7423 - 7424; DOI:
10.1021/ja00491a055
PDF
A new synthetic method for medium- and large-membered lactones by intramolecular alkylation of .omega.-haloalkyl phenylthioacetates, and its application to the syntheses of recifeiolide and 9-decanolide using butadiene telomers obtained by palladium catalyzed telomerization
Takashi Takahashi, Shohei Hahiguchi, Kazuyuki Kasuga, and Jiro Tsuji
pp 7424 - 7425; DOI:
10.1021/ja00491a056
PDF
Arene-transition metal complexes. 1. Site exchange and chemical characteristics of .eta.6-C6(CH3)6Ru-.eta.4-C6(CH3)6
Marcetta Y. Darensbourg and E. L. Muetterties
pp 7425 - 7428; DOI:
10.1021/ja00491a057
PDF
Naphthalene-butadiene exciplex. An extended Hueckel calculation
David F. Eaton and David A. Pensak
pp 7428 - 7429; DOI:
10.1021/ja00491a058
PDF
Electrochemical properties of bis(cyclopentadienylcobalt)cyclooctatetraene. Formation of a 34-electron triple-decker compound
Jerry Moraczewski and William E. Geiger
pp 7429 - 7431; DOI:
10.1021/ja00491a059
PDF
Photoreactions in detergent solutions. Enhancement of regioselectivity resulting from the reduced dimensionality of substrates sequestered in a micelle
Nicholas J. Turro and William R. Cherry
pp 7431 - 7432; DOI:
10.1021/ja00491a060
PDF
Magnetic isotope and magnetic field effects on chemical reactions. Sunlight and soap for the efficient separation of carbon-13 and carbon-12
Nicholas J. Turro and Bernhard Kraeutler
pp 7432 - 7434; DOI:
10.1021/ja00491a061
PDF
A phosphoranide anion - direct observation of a tetracoordinated phosphorane species
Itshak Granoth and J. C. Martin
pp 7434 - 7436; DOI:
10.1021/ja00491a062
PDF
Flash vacuum pyrolysis studies. 6. Allene episulfide
Eric Block, Robert E. Penn, Michael D. Ennis, Terry A. Owens, and Shin-Liang Yu
pp 7436 - 7437; DOI:
10.1021/ja00491a063
PDF
Antitumor plants. 8. Lychnopholic acid, a novel trioxygenated caryophyllene derivative from Lychnophora affinis Gardn
Robert F. Raffauf, Mary P. Pastore, Charles J. Kelley, Philip W. Le Quesne, Iwao Miura, Koji Nakanishi, Janet Finer, and Jon Clardy
pp 7437 - 7439; DOI:
10.1021/ja00491a064
PDF
Matrix isolation study of iron-manganese (FeMn) molecules
William Dyson and Pedro A. Montano
pp 7439 - 7441; DOI:
10.1021/ja00491a065
PDF
Aplidiasphingosine, an antimicrobial and antitumor terpenoid from an Aplidium species (marine tunicate)
Guy T. Carter and Kenneth L. Rinehart
pp 7441 - 7442; DOI:
10.1021/ja00491a066
PDF
Book Reviews

pp 7442 - 7444; DOI:
10.1021/ja00491a600
PDF

Issue 24


Fused organic salts. 8. Properties of molten straight-chain isomers of tetra-n-pentylammonium salts
John E. Gordon and G. N. Subba Rao
pp 7445 - 7454; DOI:
10.1021/ja00492a001
PDF
Potential energy profiles for unimolecular reactions of organic ions: C4H9O+
Richard D. Bowen and Dudley H. Williams
pp 7454 - 7459; DOI:
10.1021/ja00492a002
PDF
Acid catalysis in the gas phase: dissociative proton transfer to formic and acetic acid
G. I. Mackay, A. C. Hopkinson, and D. K. Bohme
pp 7460 - 7464; DOI:
10.1021/ja00492a003
PDF
Calculations of proton shieldings in conjugated hydrocarbons
H. Vogler
pp 7464 - 7471; DOI:
10.1021/ja00492a004
PDF
Proton transfer and tautomerism in an excited state of methyl salicylate
J. Goodman and L. E. Brus
pp 7472 - 7474; DOI:
10.1021/ja00492a005
PDF
Indole 3-sulfonium ylides and related sulfonium salts. Carbon and hydrogen nuclear magnetic resonance study
Kyong Hwi Park, George A. Gray, and G. Doyle Daves
pp 7475 - 7478; DOI:
10.1021/ja00492a006
PDF
Elucidation of the detailed structures of the native and denatured ternary complexes of thymidylate synthetase via fluorine-19 NMR
R. Andrew Byrd, William H. Dawson, Paul D. Ellis, and R. Bruce Dunlap
pp 7478 - 7486; DOI:
10.1021/ja00492a007
PDF
A sodium-23 nuclear magnetic resonance study of ionic mobility and contact ion pairing in a perfluorosulfonate ionomer
Richard A. Komoroski and Kenneth A. Mauritz
pp 7487 - 7489; DOI:
10.1021/ja00492a008
PDF
Spin probes in reversed micelles. Electron paramagnetic resonance spectra of 2,2,5,5-tetramethylpyrrolidine-1-oxyl derivatives in benzene in the presence of dodecylammonium propionate aggregates
Yau Yan Lim and Janos H. Fendler
pp 7490 - 7494; DOI:
10.1021/ja00492a009
PDF
Experimental determination of the singlet-triplet splitting in methylene
R. K. Lengel and R. N. Zare
pp 7495 - 7499; DOI:
10.1021/ja00492a010
PDF
Ground states of molecules. 50. MNDO study of hydroboration and borohydride reduction. Implications concerning cyclic conjugation and pericyclic reactions
Michael J. S. Dewar and Michael L. McKee
pp 7499 - 7505; DOI:
10.1021/ja00492a011
PDF
ENDOR of organic triplet- and quartet-state molecules in liquid solutions and in rigid media
B. Kirste, H. Van Willigen, H. Kurreck, K. Moebius, M. Plato, and R. Biehl
pp 7505 - 7513; DOI:
10.1021/ja00492a012
PDF
Perturbation theory, 3-orbital-4-electron and 4-orbital-4-electron bonding, and the inductive effect in tetrahedral compounds
Evgeny Shustorovich
pp 7513 - 7522; DOI:
10.1021/ja00492a013
PDF
Generalized Berlin diagram for polyatomic molecules
T. Koga, H. Nakatsuji, and T. Yonezawa
pp 7522 - 7527; DOI:
10.1021/ja00492a014
PDF
Electrostatic force theory for a molecule and interacting molecules. 7. Ab initio verification of the force concepts based on the flotating wave functions of ammonia, methyl(1+) ion, and ammonia(1+) ion
H. Nakatsuji, S. Kanayama, S. Harada, and T. Yonezawa
pp 7528 - 7534; DOI:
10.1021/ja00492a015
PDF
p.sigma.p.sigma. Interactions. 2. .pi. Face bonding in cyclobutadiene
Kenney B. Lipkowitz
pp 7535 - 7539; DOI:
10.1021/ja00492a016
PDF
Quantum mechanical partitioning of the energies of polypeptides. Conformational study of polyglycine
Steve Scheiner and C. W. Kern
pp 7539 - 7548; DOI:
10.1021/ja00492a017
PDF
The synchronous 1,4-addition of methylene to cis-butadiene
W. W. Schoeller and E. Yurtsever
pp 7548 - 7550; DOI:
10.1021/ja00492a018
PDF
A theoretical study on the paths of photodissociation: ketene .fwdarw. methylene + carbon monoxide
Shinichi Yamabe and Keiji Morokuma
pp 7551 - 7556; DOI:
10.1021/ja00492a019
PDF
Asymmetric catalysis with chiral complexes of rhodium-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane. 6. On the mechanism of reduction of (E,Z)-.alpha.-acylaminocinnamic acids with homogeneous rhodium catalysts
Christian Detellier, Georges Gelbard, and Henri B. Kagan
pp 7556 - 7561; DOI:
10.1021/ja00492a020
PDF
Use of deuterium to investigate E-Z isomerizations during rhodium-catalyzed reduction. Asymmetric induction and mechanistic implications
Karl E. Koenig and William S. Knowles
pp 7561 - 7564; DOI:
10.1021/ja00492a021
PDF
Preparation and reactions of alkyl- and arylpentacarbonyltungsten anions
Charles P. Casey and Stanley W. Polichnowski
pp 7565 - 7568; DOI:
10.1021/ja00492a022
PDF
Reactions of the excited states of substituted polypyridinechromium(III) complexes with oxygen, iron(II) ions, ruthenium(II) and -(III), and osmium(II) and -(III) complexes
Bruce Brunschwig and Norman Sutin
pp 7568 - 7577; DOI:
10.1021/ja00492a023
PDF
The chemistry of 2-naphthyl bis[bis(dimethylphosphino)ethane] hydride complexes of iron, ruthenium, and osmium. 2. Cleavage of sp and sp3 carbon-hydrogen, carbon-oxygen, and carbon-halogen bonds. Coupling of carbon dioxide and acetonitrile
S. D. Ittel, C. A. Tolman, A. D. English, and J. P. Jesson
pp 7577 - 7585; DOI:
10.1021/ja00492a024
PDF
Iron porphyrin phenoxides: models for some hemoglobin mutants
E. W. Ainscough, A. W. Addison, D. Dolphin, and B. R. James
pp 7585 - 7591; DOI:
10.1021/ja00492a025
PDF
Activation volume and transition state character in several proton and hydride transfer reactions
K. R. Brower and David Hughes
pp 7591 - 7596; DOI:
10.1021/ja00492a026
PDF
Effect of aryl substituents, solvent, and steric effects on the efficiency of excited-state carbonyl production from 1,2-dioxetanes
William H. Richardson, James H. Burns, Mary E. Price, Richard Crawford, Mark Foster, Penny Slusser, and James H. Anderegg
pp 7596 - 7600; DOI:
10.1021/ja00492a027
PDF
The ortho functionalization of aromatic amines. Benzylation, formylation, and vinylation of anilines
Paul G. Gassman and H. Roger Drewes
pp 7600 - 7610; DOI:
10.1021/ja00492a028
PDF
Exclusive ortho substitution of phenols via [2,3]-sigmatropic rearrangements
Paul G. Gassman and David R. Amick
pp 7611 - 7619; DOI:
10.1021/ja00492a029
PDF
Secondary deuterium isotope effects for acid-catalyzed hydrolysis of inosine adenosine
R. Romero, R. Stein, H. G. Bull, and E. H. Cordes
pp 7620 - 7624; DOI:
10.1021/ja00492a030
PDF
Hydrolysis enthalpy changes for selected five- and six-membered cyclic esters
E. Izbicka and D. W. Bolen
pp 7625 - 7628; DOI:
10.1021/ja00492a031
PDF
1,9-Dithiophenalenyl system
Robert C. Haddon, Fred Wudl, Martin L. Kaplan, James H. Marshall, Rudolf E. Cais, and Fitzgerald B. Bramwell
pp 7629 - 7633; DOI:
10.1021/ja00492a032
PDF
Ion pairing in excited states of carbanions. 2. Emission of fluorenyl and fluoradenyl alkali salts in aprotic media
T. E. Hogen-Esch and J. Plodinec
pp 7633 - 7640; DOI:
10.1021/ja00492a033
PDF
Asymmetric reductions of carbocations by chiral organosilicon hydrides. The stereochemical nature of the carbocation captured
James L. Fry and Merwyn G. Adlington
pp 7641 - 7644; DOI:
10.1021/ja00492a034
PDF
Reactivity of ethylenic compounds. 42. The multipathway mechanism in styrene bromination: competition between bromonium and carbonium ion intermediates
M. F. Ruasse, A. Argile, and J. E. Dubois
pp 7645 - 7652; DOI:
10.1021/ja00492a035
PDF
Evidence from the absorption and emission spectra of trimethylenemethane derivatives for two molecular species in thermal equilibrium
Nicholas J. Turro, Manfred J. Mirbach, Niels Harrit, Jerome A. Berson, and Matthew S. Platz
pp 7653 - 7658; DOI:
10.1021/ja00492a036
PDF
Pyridinyl radicals, pyridinyl anions, Z values, and disproportionation equilibriums
Mahboob Mohammad, A. Y. Khan, M. Iqbal, R. Iqbal, and M. Razzaq
pp 7658 - 7660; DOI:
10.1021/ja00492a037
PDF
Pyrimidine derivatives and related compounds. 31. A new photochemical transformation of 6-azido-1,3-dimethyluracil to 6-alkylamino-5-amino-1,3-dimethyluracils and its application to one-step synthesis of lumazines and fervenulins
Shigeo Senda, Kosaku Hirota, Tetsuji Asao, and Kazuo Maruhashi
pp 7661 - 7664; DOI:
10.1021/ja00492a038
PDF
Stylocheilamide, an unusual constituent of the sea hare Stylocheilus longicauda
Allan F. Rose, Paul J. Scheuer, James P. Springer, and Jon Clardy
pp 7665 - 7670; DOI:
10.1021/ja00492a039
PDF
Oxidation of dihydronicotinamides by flavopapain
Howard L. Levine and E. T. Kaiser
pp 7670 - 7677; DOI:
10.1021/ja00492a040
PDF
Minor and trace sterols in marine invertebrates. 8. Isolation, structure elucidation, and partial synthesis of two novel sterols - stelliferasterol and isostelliferasterol
Norbert Theobald, R. J. Wells, and Carl Djerassi
pp 7677 - 7684; DOI:
10.1021/ja00492a041
PDF
Des-N-tetramethyltriostin A and bis-L-seryldes-N-tetramethyltriostin A, synthetic analogs of the quinoxaline antibiotics
Thomas L. Ciardelli, Prasun K. Chakravarty, and Richard K. Olsen
pp 7684 - 7690; DOI:
10.1021/ja00492a042
PDF
Synthesis and characterization of prostacyclin, 6-ketoprostaglandin F1.alpha., prostaglandin I1, and prostaglandin I3
Roy A. Johnson, Frank H. Lincoln, Eldon G. Nidy, William P. Schneider, John L. Thompson, and Udo Axen
pp 7690 - 7705; DOI:
10.1021/ja00492a043
PDF
Porphyrins. 38. Redox potentials, charge transfer transitions, and emission of copper, silver, and gold complexes
Artemis Antipas, David Dolphin, Martin Gouterman, and Eugene C. Johnson
pp 7705 - 7709; DOI:
10.1021/ja00492a044
PDF
Kinetic studies on reactions of iron-sulfur proteins. 1. Oxidation of reduced parsley (and spinach) 2-iron ferredoxins with Co(NH3)63+, dl- and d- Co(en)33+, Co(NH3)5Cl2+, Co(NH3)5C2O4+, Co(dmgH)2(C6H5NH2)2+, and Co(edta)-. Evidence for protein-complex association
Fraser A. Armstrong and A. Geoffrey Sykes
pp 7710 - 7715; DOI:
10.1021/ja00492a045
PDF
Enzymic dynamics and molecular orbital study on the roles of arginines in carboxypeptidase A, a sliding mechanism
Setsuko Nakagawa and Hideaki Umeyama
pp 7716 - 7725; DOI:
10.1021/ja00492a046
PDF
Decacarbonyl(methyl)hydrotriosmium: NMR evidence for a carbon.cntdot..cntdot.hydrogen.cntdot..cntdot.osmium interaction
R. Bruce Calvert and John R. Shapley
pp 7726 - 7727; DOI:
10.1021/ja00492a047
PDF
Investigations concerning the apparent contradiction between the microwave structure and the ab initio calculations of glycine
Harrell L. Sellers and Lothar Schafer
pp 7728 - 7729; DOI:
10.1021/ja00492a048
PDF
Carbon-13 nuclear magnetic resonance of cis- and trans-polyacetylenes
M. M. Maricq, J. S. Waugh, A. G. MacDiarmid, H. Shirakawa, and A. J. Heeger
pp 7729 - 7730; DOI:
10.1021/ja00492a049
PDF
Bicyclo[4.2.2]deca-1,5-diene, a bridgehead diene
John R. Wiseman and Jeffrey J. Vanderbilt
pp 7730 - 7731; DOI:
10.1021/ja00492a050
PDF
Antineoplastic agents. 61. Isolation and structure of amoorastatin
Judith Polonsky, Zoia Varon, Bernadette Arnoux, Claudine Pascard, George R. Pettit, and Jean M. Schmidt
pp 7731 - 7733; DOI:
10.1021/ja00492a051
PDF
Remarks on free-energy correlations of rate constants for electron-transfer quenching of electronically excited states
Maria Teresa Indelli and Franco Scandola
pp 7733 - 7734; DOI:
10.1021/ja00492a052
PDF
1,1-Difluoro-2,2,3,3-tetramethyl-1-silirane: synthesis and novel chemistry. Reinterpretation of difluorosilylene reaction mechanisms
Dietmar Seyferth and Don P. Duncan
pp 7734 - 7736; DOI:
10.1021/ja00492a053
PDF
Triple-bonded ethane-like M2L6 transition metal complexes should be eclipsed
Thomas A. Albright and Roald Hoffmann
pp 7736 - 7738; DOI:
10.1021/ja00492a054
PDF
Thermochemistry of some metal-to-metal triple bonds
J. A. Connor, G. Pilcher, H. A. Skinner, M. H. Chisholm, and F. A. Cotton
pp 7738 - 7739; DOI:
10.1021/ja00492a055
PDF
Perturbation molecular orbital treatment of free-radical hydrogen-abstraction reactions
H. Bartels, W. Eichel, K. Riemenschneider, and P. Boldt
pp 7739 - 7740; DOI:
10.1021/ja00492a056
PDF
Theoretical ab initio calculations of deformation densities in some binuclear metal complexes
M. Benard
pp 7740 - 7742; DOI:
10.1021/ja00492a057
PDF
The Hartree-Fock theory of local regions in molecules
H. Stoll, G. Wagenblast, and H. Preuss
pp 7742 - 7743; DOI:
10.1021/ja00492a058
PDF
Kinetics of reactions in solutions under pressure. 51. Shape and inversion of an allenic anion
W. J. Le Noble, D. M. Chiou, and Y. Okaya
pp 7743 - 7744; DOI:
10.1021/ja00492a059
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Temperature dependence of rotational correlation times for an inverse temperature transition. A fundamental characterization
Dan W. Urry, Tina L. Trapane, and M. Abu Khaled
pp 7744 - 7746; DOI:
10.1021/ja00492a060
PDF
An unusual new allene cyclization reaction. Synthesis of dihydrofuran-3(2H)-ones
David Gange and Philip Magnus
pp 7746 - 7747; DOI:
10.1021/ja00492a061
PDF
Palladium catalyzed allylic alkylation of olefins
Louis S. Hegedus, Tamio Hayashi, and W. H. Darlington
pp 7747 - 7748; DOI:
10.1021/ja00492a062
PDF
Bis heteroannulation. 1. Model studies in the synthesis of highly oxygenated sesquiterpenes
Peter A. Jacobi and Todd Craig
pp 7748 - 7750; DOI:
10.1021/ja00492a063
PDF
Carboxypeptidase A catalyzed enolization of a ketonic substrate. A new stereochemical probe for an enzyme-bound nucleophile
Takuji Sugimoto and E. T. Kaiser
pp 7750 - 7751; DOI:
10.1021/ja00492a064
PDF
Synthetic studies of rishitin and related compounds. 7. Synthesis of phytuberin
Akio Murai, Mitsunori Ono, Atsushi Abiko, and Tadashi Masamune
pp 7751 - 7753; DOI:
10.1021/ja00492a065
PDF
The dianion of dimethyl cyclobut-3-ene-1,2-dicarboxylate. Aromaticity vs. Coulombic repulsion
Peter J. Garratt and Robert Zahler
pp 7753 - 7754; DOI:
10.1021/ja00492a066
PDF
A nitrogen-sulfur bonded cation radical [R3N-SR2]+.cntdot.and a dication [R3N-SR2]2+ from 5-methyl-1-thia-5-azacyclooctane
W. Kenneth Musker, Albert S. Hirschon, and Joyce Takahashi Doi
pp 7754 - 7756; DOI:
10.1021/ja00492a067
PDF
Synthesis of nucleoside [18O]pyrophosphorothioates with chiral [18O]phosphorothioate groups of known configuration. Stereochemical orientations of enzymic phosphorylations of chiral [18O]phosphorothioates
John P. Richard, Hsu-Tso Ho, and Perry A. Frey
pp 7756 - 7757; DOI:
10.1021/ja00492a068
PDF
Stereochemical course of thiophosphoryl group transfer catalyzed by adenylate kinase
John P. Richard and Perry A. Frey
pp 7757 - 7758; DOI:
10.1021/ja00492a069
PDF
Ultraviolet chromophores of palytoxins
Richard E. Moore, Frank X. Woolard, M. Younus Sheikh, and Paul J. Scheuer
pp 7758 - 7759; DOI:
10.1021/ja00492a070
PDF
Isolation and characterization of the first mitotic cycle hormone that regulates cell proliferation
David G. Lynn, Koji Nakanishi, Steven L. Patt, John L. Occolowitz, Sophia Almeida, and Lance S. Evans
pp 7759 - 7760; DOI:
10.1021/ja00492a071
PDF
Metal-silicon bonded compounds. 13. Synthesis, proton and carbon-13 NMR spectra, and structure of bis(1,2-dimethoxyethane)-.mu.-hexakis(2-methoxyethanolato)tetramagnesium(II) tris(dimethylphenylsilyl)mercurate(II)
E. Alan Sadurski, William H. Ilsley, Ruthanne D. Thomas, Milton D. Glick, and John P. Oliver
pp 7761 - 7762; DOI:
10.1021/ja00492a072
PDF
Synthesis, characterization, and structure of diaminoborane
Thomas S. Briggs, William D. Gwinn, William L. Jolly, and Lawrence R. Thorne
pp 7762 - 7763; DOI:
10.1021/ja00492a073
PDF
Stable dimethyl, methyl, and unsubstituted vinylidene complexes
Alan Davison and John P. Selegue
pp 7763 - 7765; DOI:
10.1021/ja00492a074
PDF
The separation of polarizability and inductive effects in gas- and solution-phase proton-transfer equilibriums
Robert W. Taft, M. Taagepera, J. L. M. Abbound, J. F. Wolf, D. J. DeFrees, W. J. Hehre, J. E. Bartmess, and R. T. McIver
pp 7765 - 7767; DOI:
10.1021/ja00492a075
PDF
A stereospecific total synthesis of (.+-.)-pentenomycin I, (.+-.)-pentenomycin II, and dehydropentenomycin I exploiting a versatile latent .alpha.-oxovinyl anion equivalent
Stephen J. Branca and Amos B. Smith
pp 7767 - 7768; DOI:
10.1021/ja00492a076
PDF
Electrochemical behavior and standard potential of gold(1-) ion in liquid ammonia
Towfik H. Teherani, William J. Peer, J. J. Lagowski, and Allen J. Bard
pp 7768 - 7770; DOI:
10.1021/ja00492a077
PDF
Chemistry of singlet oxygen. 29. A specific three-phase "Kautsky test" for singlet oxygen
S. Wolf, C. S. Foote, and J. Rebek
pp 7770 - 7771; DOI:
10.1021/ja00492a078
PDF
Very Fast acylation of .beta.-cyclodextrin by bound p-nitrophenyl ferrocinnamate
Michael F. Czarniecki and Ronald Breslow
pp 7771 - 7772; DOI:
10.1021/ja00492a079
PDF
Solvent-incorporated medium to macrocyclic compounds by the photochemical cyclization of N-alkenylphthalimides
Kazuhiro Maruyama and Yasuo Kubo
pp 7772 - 7773; DOI:
10.1021/ja00492a080
PDF
Selectivity features of polystyrene-based triphase catalysts
Steven L. Regen and Alok Nigam
pp 7773 - 7775; DOI:
10.1021/ja00492a081
PDF
Total synthesis of cytochalasin B
Gilbert Stork, Yoshiaki Nakahara, Yuko Nakahara, and W. J. Greenlee
pp 7775 - 7777; DOI:
10.1021/ja00492a082
PDF
Synthetic utilization of the imine moiety. 6. Intramolecular carbon alkylation of oxime anions. Stereospecific generation and rearrangement of nitrosocyclopropanes and nitrosocyclobutanes
D. A. Clark, C. A. Bunnell, and P. L. Fuchs
pp 7777 - 7779; DOI:
10.1021/ja00492a083
PDF
Steric steering with supported palladium catalysts
Barry M. Trost and Ehud Keinan
pp 7779 - 7781; DOI:
10.1021/ja00492a084
PDF
Steroids and related natural products. 96. Synthesis of 3.beta.,16.beta.,23(R),26-Tetrahydroxy-5.beta.-cholestane
George R. Pettit, James J. Einck, and John C. Knight
pp 7781 - 7782; DOI:
10.1021/ja00492a085
PDF
Quantitative assessment of pp-.sigma. overlap in a topologically convex triene. Electronic and crystal structure analysis of C16-hexaquinacene
Gary G. Christoph, Jean L. Muthard, Leo A. Paquette, Michael C. Boehm, and Rolf Gleiter
pp 7782 - 7784; DOI:
10.1021/ja00492a086
PDF
Static and dynamic stereochemistry of dicoordinate phosphorus cations
Alan H. Cowley, Mike C. Cushner, and John S. Szobota
pp 7784 - 7786; DOI:
10.1021/ja00492a087
PDF
Protonation-induced dynamic stereochemistry of hexatungstobis(organoarsonate) anions
S. H. Wasfi, W. Kwak, M. T. Pope, K. M. Barkigia, R. J. Butcher, and C. O. Quicksall
pp 7786 - 7787; DOI:
10.1021/ja00492a088
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Book Reviews

pp 7787 - 7790; DOI:
10.1021/ja00492a600
PDF

Issue 25


Nuclear magnetic resonance and electron spin resonance observation of hindered rotation in sym-tetra-tert-butyldisilane and the corresponding disilanyl radical
David A. Stanislawski, A. C. Buchanan, and Robert West
pp 7791 - 7794; DOI:
10.1021/ja00493a001
PDF
Tetraalkyldisilanes as models for the conformational analysis of tetraalkyldiphosphines
S. G. Baxter, Dennis A. Dougherty, John F. Blount, Kurt Mislow, and J. P. Hummel
pp 7795 - 7799; DOI:
10.1021/ja00493a002
PDF
Substituent effects in the phenylbicyclo[2.2.2]octane ring system by fluorine-19 and carbon-13 NMR. The nature of aryl fluorine-19 NMR polar field effects
William Adcock and Thong-Chak Khor
pp 7799 - 7810; DOI:
10.1021/ja00493a003
PDF
Iterative force-field calculations of cycloundecane, cyclotridecane, and cyclopentadecane
Frank A. L. Anet and T. N. Rawdah
pp 7810 - 7814; DOI:
10.1021/ja00493a004
PDF
Conformations of cis,cis-1,3-cyclooctadiene and its epoxides. Dynamic nuclear magnetic resonance spectroscopy and iterative force-field calculations
Frank A. L. Anet and Issa Yavari
pp 7814 - 7819; DOI:
10.1021/ja00493a005
PDF
Absence of an energetically viable pathway for triplet 1,2 hydrogen shifts. A theoretical study of the vinylidene-acetylene isomerization
Morgan P. Conrad and Henry F. Schaefer
pp 7820 - 7823; DOI:
10.1021/ja00493a006
PDF
Quantum and statistical mechanical studies of liquids. 2. Monte-Carlo simulations of liquid hydrogen fluoride
William L. Jorgensen
pp 7824 - 7831; DOI:
10.1021/ja00493a007
PDF
Ground states of molecules. 51. MNDO (modified neglect of diatomic overlap) calculations of kinetic isotope effects
S. Bruce Brown, Michael J. S. Dewar, George P. Ford, Donna J. Nelson, and Henry S. Rzepa
pp 7832 - 7836; DOI:
10.1021/ja00493a008
PDF
Electronic states of organic molecules. 6. Dipole and quadrupole moments: the sign of the dipole moment for cyclopropene and the microwave spectrum of 3,3-dimethylcyclopropene
Kenneth B. Wiberg, G. Barney Ellison, John J. Wendoloski, William E. Pratt, and Marlin D. Harmony
pp 7837 - 7840; DOI:
10.1021/ja00493a009
PDF
Ab initio calculation on the photochemistry of formaldehyde. The search for a hydroxycarbene intermediate
M. J. H. Kemper, J. M. F. Van Dijk, and H. M. Buck
pp 7841 - 7846; DOI:
10.1021/ja00493a010
PDF
Molecular orbital study of structural changes on oxidation and reduction of S3, S4, S6, and S8
Dennis R. Salahub, Aniko E. Foti, and Vedene H. Smith
pp 7847 - 7859; DOI:
10.1021/ja00493a011
PDF
Ground- and excited-state correlations in bond rupture reactions
E. M. Evleth and E. Kassab
pp 7859 - 7864; DOI:
10.1021/ja00493a012
PDF
Resonance Raman spectroscopy of uranocene: observation of an anomalously polarized electronic band and assignment of energy levels
R. F. Dallinger, P. Stein, and T. G. Spiro
pp 7865 - 7870; DOI:
10.1021/ja00493a013
PDF
Chemically modified electrodes. 13. Monolayer/multilayer coverage, decay kinetics, and solvent and interaction effects for ferrocenes covalently linked to platinum electrodes
Jerome R. Lenhard and Royce W. Murray
pp 7870 - 7875; DOI:
10.1021/ja00493a014
PDF
Geometry change upon electron removal from a tetraalkylhydrazine. X-ray crystallographic structures of 9,9'-bis-9-azabicyclo[3.3.1]nonane and its radical cation hexafluorophosphate
S. F. Nelsen, W. C. Hollinsed, C. R. Kessel, and J. C. Calabrese
pp 7876 - 7882; DOI:
10.1021/ja00493a015
PDF
Specific sequestering agents for the actinides. 2. A ligand field effect in the crystal and molecular structures of tetrakis(catecholato)uranate(IV) and -thorate(IV)
Stephen R. Sofen, Kamal Abu-Dari, Derek P. Freyberg, and Kenneth N. Raymond
pp 7882 - 7887; DOI:
10.1021/ja00493a016
PDF
Electronic structures and spectra of trinuclear carbonyl complexes
David R. Tyler, Robert A. Levenson, and Harry B. Gray
pp 7888 - 7893; DOI:
10.1021/ja00493a017
PDF
Structural and magnetic properties of tris(o-semiquinone) complexes of iron(III) and chromium(III)
Robert M. Buchanan, Stephen L. Kessel, Hartly H. Downs, Cortlandt G. Pierpont, and David N. Hendrickson
pp 7894 - 7900; DOI:
10.1021/ja00493a018
PDF
Reactions of activated quadruply bonded molybdenum dimers. Formation of new rectangular clusters containing the tetrametal analog of cyclobutadiyne
Roger N. McGinnis, Timothy R. Ryan, and R. E. McCarley
pp 7900 - 7902; DOI:
10.1021/ja00493a019
PDF
Synthesis and reactions of (.eta.5-cyclopentadienyl)tricarbonylhydridovanadate. A comparative mechanistic study of its organic halide reduction reactions with those of tri-n-butyltin hydride
Robert J. Kinney, William D. Jones, and Robert G. Bergman
pp 7902 - 7915; DOI:
10.1021/ja00493a020
PDF
Structures of butyl ions formed by electron impact ionization of isomeric butyl halides and alkanes
D. M. Shold and P. Ausloos
pp 7915 - 7919; DOI:
10.1021/ja00493a021
PDF
Electronic effects in the unimolecular decomposition of substituted diphenyldiazomethanes
R. J. Miller and H. Shechter
pp 7920 - 7927; DOI:
10.1021/ja00493a022
PDF
Chemistry of (2- and 3-furyl)methylenes and (2- and 3-thienyl)methylenes
Robert V. Hoffman, Gus. G. Orphanides, and Harold Shechter
pp 7927 - 7933; DOI:
10.1021/ja00493a023
PDF
Carbenic, cationic, metal ion catalyzed, and photolytic decompositions of ethyl (2-furyl)diazoacetate
Robert V. Hoffman and Harold Shechter
pp 7934 - 7940; DOI:
10.1021/ja00493a024
PDF
Photolysis of tert-butyl hydroperoxide in alcohols. A carbon-13 CIDNP study
W. B. Moniz, S. A. Sojka, C. F. Poranski, and D. K. Birkle
pp 7940 - 7945; DOI:
10.1021/ja00493a025
PDF
Structural effects in solvolytic reactions. 28. Solvolysis of 1-aryl-1-cyclopropyl 3,5-dinitrobenzoates containing strongly electron-supplying aryl groups. Evidence for two distinct reaction processes involving assisted (K.DELTA.) and unassisted (Kc) mechanisms
Herbert C. Brown, C. Gundu Rao, and M. Ravindranathan
pp 7946 - 7953; DOI:
10.1021/ja00493a026
PDF
Radical production from the interaction of closed-shell molecules. 9. Reaction of ozone with tert-butyl hydroperoxide
Michael E. Kurz and William A. Pryor
pp 7953 - 7959; DOI:
10.1021/ja00493a027
PDF
Superoxide chemistry. Reactions of superoxide with alkyl halides and alkyl sulfonate esters
Roy A. Johnson, Eldon G. Nidy, and Margaret V. Merritt
pp 7960 - 7966; DOI:
10.1021/ja00493a028
PDF
Properties of small-ring free radicals. 2. Thermal decomposition of alicyclic percarboxylates
Richard A. Wolf, Michael J. Migliori, Patrick H. Fuery, Paul R. Gagnier, Isidore C. Sabeta, and Richard J. Trocino
pp 7967 - 7976; DOI:
10.1021/ja00493a029
PDF
Epimerization and isomerization in C20-diterpenoid alkaloids. Crystal and molecular structures of atisinium chloride, dihydroatisine, isoatisine, and veatchine
S. William Pelletier, Wilson H. De Camp, and Naresh V. Mody
pp 7976 - 7987; DOI:
10.1021/ja00493a030
PDF
Sirohydrochlorin. Prosthetic group of sulfite and nitrite reductases and its role in the biosynthesis of vitamin B12
A. Ian Scott, Anthony J. Irwin, Lewis M. Siegel, and J. N. Shoolery
pp 7987 - 7994; DOI:
10.1021/ja00493a031
PDF
Structure of 9,9'-bitriptycyl
M. H. P. Ardebili, D. A. Dougherty, K. Mislow, L. H. Schwartz, and J. G. White
pp 7994 - 7997; DOI:
10.1021/ja00493a032
PDF
Reaction of crosslinked chloromethyl polystyrene with 1,4-butanedithiol: site-site interactions and their control
M. Jean Farrall and Jean M. J. Frechet
pp 7998 - 7999; DOI:
10.1021/ja00493a033
PDF
Complete syn selectivity in the alkylation of lithiated ketimines
Robert R. Fraser, Jacques Banville, and Kasturi L. Dhawan
pp 7999 - 8001; DOI:
10.1021/ja00493a034
PDF
Structure and triboluminescence of polymorphs of hexaphenylcarbodiphosphorane
Gordon E. Hardy, Jeffrey I. Zink, W. C. Kaska, and J. C. Baldwin
pp 8001 - 8002; DOI:
10.1021/ja00493a035
PDF
Monomeric molybdenum(V) oxo complexes with tetradentate aminoethanethiols
J. T. Spence, M. Minelli, P. Kroneck, M. I. Scullane, and N. D. Chasteen
pp 8002 - 8004; DOI:
10.1021/ja00493a036
PDF
Decysteaminylthienamycin
D. H. Shih, J. Hannah, and B. G. Christensen
pp 8004 - 8006; DOI:
10.1021/ja00493a037
PDF
Total synthesis of thienamycin analogs. 1. Synthesis of the thienamycin nucleus and dl-decysteaminylthienamycin
L. D. Cama and B. G. Christensen
pp 8006 - 8007; DOI:
10.1021/ja00493a038
PDF
Nitrogen fixation via photoenhanced reduction on p-gallium phosphide electrodes
C. R. Dickson and A. J. Nozik
pp 8007 - 8009; DOI:
10.1021/ja00493a039
PDF
Planar 3A2' - orthogonal 1B1 energy separation for trimethylenemethane
Diane M. Hood, Henry F. Schaefer, and Russell M. Pitzer
pp 8009 - 8010; DOI:
10.1021/ja00493a040
PDF
Optical rotatory dispersion studies. 125. Independent evidence for preference of axial deuterium vs. axial hydrogen through variable-temperature circular dichroism spectra of (4S)-2,2-dimethyl-4-deuteriocyclohexanone and (3S)-3-deuterio-4,4-dimethylcyclohexanone
Shy-Fuh Lee, Guenter Barth, and Carl Djerassi
pp 8010 - 8012; DOI:
10.1021/ja00493a041
PDF
Evidence for "naphtharadialene" (1,2,3,4,5,6,7,8-octakis(methylene)-.DELTA.9-octalin)
Harold Hart, Mark Jeffares, Avraham Teuerstein, and Donald L. Ward
pp 8012 - 8013; DOI:
10.1021/ja00493a042
PDF
A radical-chain mechanism for some sulfur dioxide "insertion" reactions in organocobaloximes
Alan E. Crease and Michael D. Johnson
pp 8013 - 8014; DOI:
10.1021/ja00493a043
PDF
Inhibition of 5-phosphomevalonate kinase by an isosteric analog of 5-phosphomevalonate
George Popjak, Thomas S. Parker, Vivander Sarin, Burton E. Tropp, and Robert Engel
pp 8014 - 8016; DOI:
10.1021/ja00493a044
PDF
Low-temperature carbon-13 nuclear magnetic resonance spectroscopic investigation of C4H7+. Evidence for an equilibrium involving the nonclassical bicyclobutonium ion and the bisected cyclopropylcarbinyl cation
John S. Staral, Issa Yavari, John D. Roberts, G. K. Surya Prakash, Daniel J. Donovan, and George A. Olah
pp 8016 - 8018; DOI:
10.1021/ja00493a045
PDF
Observation by carbon-13 nuclear magnetic resonance spectroscopy of hydride shifts in C4H7+ derived from cyclopropylcarbinol-1-13C in antimony pentafluoride-sulfuryl chloride fluoride-sulfuryl fluoride solution
John S. Staral and John D. Roberts
pp 8018 - 8020; DOI:
10.1021/ja00493a046
PDF
Homolytic substitution at saturated carbon: mass spectrometry and free-radical chemistry
Mark M. Green, R. J. Giguere, and James R. P. Nicholson
pp 8020 - 8021; DOI:
10.1021/ja00493a047
PDF
Alkali metal enolates and cryptands - a novel type of strong base
Jean Louis Pierre, Raymond Le Goaller, and Henri Handel
pp 8021 - 8022; DOI:
10.1021/ja00493a048
PDF
Absolute stereochemistries of 3-epicaryoptin, caryoptin, and clerodin as determined by chiroptical methods
Nobuyuki Harada and Hisashi Uda
pp 8022 - 8024; DOI:
10.1021/ja00493a049
PDF
Dimerization of carbene to ethylene
L. M. Cheung, K. R. Sundberg, and K. Ruedenberg
pp 8024 - 8025; DOI:
10.1021/ja00493a050
PDF
Exciton collection from an antenna system into accessible traps
Hiroyasu Tachikawa and Larry R. Faulkner
pp 8025 - 8026; DOI:
10.1021/ja00493a051
PDF
Synthesis and reactivity of compounds with cyclobutane ring(s). 11. [2 + 2] Cycloadditions of tetraalkoxyethylenes with ketenes: a general route to 2-substituted 1-hydroxycyclobut-1-ene-3,4-diones
Daniel Bellus
pp 8026 - 8028; DOI:
10.1021/ja00493a052
PDF
Hypovalent radicals. 3. Chemical reductions of certain diazo compounds to carbene anion radicals - formation of fluorenylidene disodium, a carbene dianion
Richard N. McDonald and Kuo-Wei Lin
pp 8028 - 8030; DOI:
10.1021/ja00493a053
PDF
Total synthesis of (-)-axisonitrile-3. An application of the reductive ring opening of vinylcyclopropanes
Drury Caine and Howard Deutsch
pp 8030 - 8031; DOI:
10.1021/ja00493a054
PDF
Stereospecific total synthesis of gibberellic acid. A key tricyclic intermediate
E. J. Corey, Rick L. Danheiser, Srinivasan Chandrasekaran, Patrice Siret, Gary E. Keck, and Jean Louis Gras
pp 8031 - 8034; DOI:
10.1021/ja00493a055
PDF
Stereospecific total synthesis of gibberellic acid
E. J. Corey, Rick L. Danheiser, Srinivasan Chandrasekaran, Gary E. Keck, B. Gopalan, Samuel D. Larsen, Patrice Siret, and Jean Louis Gras
pp 8034 - 8036; DOI:
10.1021/ja00493a056
PDF
A highly efficient total synthesis of (.+-.)-lycopodine
Clayton H. Heathcock, Edward Kleinman, and Edward S. Binkley
pp 8036 - 8037; DOI:
10.1021/ja00493a057
PDF
Poly(I) helix formation. Dependence on size-specific complexing to alkali metal ions
H. Todd Miles and Joe Frazier
pp 8037 - 8038; DOI:
10.1021/ja00493a058
PDF
Low-temperature natural-abundance carbon-13 NMR spectroscopy of matrix-isolated species. The anisotropy of the shielding tensor in ethylene
K. W. Zilm, R. T. Conlin, D. M. Grant, and J. Michl
pp 8038 - 8039; DOI:
10.1021/ja00493a059
PDF
Book Reviews

pp 8040 - 8040; DOI:
10.1021/ja00493a600
PDF

Issue 26


Nitrogen-15 nuclear magnetic resonance spectroscopy. The state of histidine in the catalytic triad of .alpha.-lytic protease. Implications for the charge-relay mechanism of peptide-bond cleavage by serine proteases
William W. Bachovchin and John D. Roberts
pp 8041 - 8047; DOI:
10.1021/ja00494a001
PDF
EPR and NMR combined analysis of the metal-ATP interaction
Riccardo Basosi, Neri Niccolai, Enzo Tiezzi, and Gianni Valensin
pp 8047 - 8050; DOI:
10.1021/ja00494a002
PDF
Covalently attached organic monolayers on semiconductor surfaces
Ivan Haller
pp 8050 - 8055; DOI:
10.1021/ja00494a003
PDF
Theory and application of photoelectron spectroscopy. 70. Photoelectron spectra of 1,2-diphenylcyclopropene, 2,3-diphenylcyclopropenone, 2,3-diphenylcyclopropenethione, 2,3-diphenylthiirene 1-oxide, and cis-stilbene. An experimental verification of conjugative and inductive interactions
Claus Mueller, Armin Schweig, and Hans Vermeer
pp 8056 - 8060; DOI:
10.1021/ja00494a004
PDF
"Increased valence" when the octet rule is obeyed. A reply to a challenge
Richard D. Harcourt
pp 8060 - 8062; DOI:
10.1021/ja00494a005
PDF
Ab initio studies on the electronic structure of ONF (nitrosyl fluoride) and NOF (nitrogen hypofluorite)
L. J. Lawlor, K. Vasudevan, and F. Grein
pp 8062 - 8068; DOI:
10.1021/ja00494a006
PDF
Paramagnetic organometallic compounds of the early transition metals stabilized by chelating benzyl and phenyl ligands
Leo E. Manzer
pp 8068 - 8073; DOI:
10.1021/ja00494a007
PDF
Synthesis, microwave spectrum, and structure of ArBF3, BF3CO, and N2BF3
K. C. Janda, L. S. Bernstein, J. M. Steed, S. E. Novick, and W. Klemperer
pp 8074 - 8079; DOI:
10.1021/ja00494a008
PDF
High-spin and low-spin .alpha.-picolylamine iron(II) complexes. Effect of ligand reversal on spin state
Anthony M. Greenaway and Ekk Sinn
pp 8080 - 8084; DOI:
10.1021/ja00494a009
PDF
NMR studies of low-spin ferric complexes of natural porphyrin derivatives. 1. Effect of peripheral substituents on the .pi. electronic asymmetry in biscyano complexes
Gerd N. La Mar, David B. Viscio, Kevin M. Smith, W. S. Caughey, and Michael L. Smith
pp 8085 - 8092; DOI:
10.1021/ja00494a010
PDF
NMR studies of low-spin ferric complexes of natural porphyrin derivatives. 2. Determination of the dimer structure of the biscyano complex using intermolecular paramagnetic dipolar relaxations
David B. Viscio and Gerd N. La Mar
pp 8092 - 8096; DOI:
10.1021/ja00494a011
PDF
NMR studies of low-spin ferric complexes of natural porphyrin derivatives. 3. Thermodynamics of dimerization and the influence of substituents on dimer structure and stability
David B. Viscio and Gerd N. La Mar
pp 8096 - 8100; DOI:
10.1021/ja00494a012
PDF
Empirical relations between disulfide bond lengths, (nitrogen or carbon)-carbon-sulfur-sulfur torsion angles, and substituents in aromatic disulfides. Crystal and molecular structure of 3,3'-dihydroxydi-2-pyridyl disulfide
Lois S. Higashi, Munime Lundeen, and Karl Seff
pp 8101 - 8106; DOI:
10.1021/ja00494a013
PDF
C-5 substituted pyrimidine nucleosides. 2. Synthesis via olefin coupling to organopalladium intermediates derived from uridine and 2'-deoxyuridine
Donald E. Bergstrom and Mark K. Ogawa
pp 8106 - 8112; DOI:
10.1021/ja00494a014
PDF
The three-phase test: intermediates in phosphate transfer reactions
Julius Rebek, Francisco Gavina, and Carmen Navarro
pp 8113 - 8117; DOI:
10.1021/ja00494a015
PDF
Intermediates in nucleophilic aromatic substitution. 19. Multiple structure-reactivity relationships in the acid-catalyzed breakdown of Meisenheimer complexes
Claude F. Bernasconi and Joseph R. Gandler
pp 8117 - 8124; DOI:
10.1021/ja00494a016
PDF
Tetraoxysulfuranes from phenols. Synthesis and the dehydration of alcohols
G. E. Wilson and Benjamin A. Belkind
pp 8124 - 8130; DOI:
10.1021/ja00494a017
PDF
Solvation as the cause for slower rates of cyanide and thiol anion catalyzed proton abstraction from carbon compared to oxy anions of the same basicity
Eric R. Pohl and D. J. Hupe
pp 8130 - 8133; DOI:
10.1021/ja00494a018
PDF
Solvolysis of cyclopentyl p-bromobenzenesulfonate in aqueous hexafluoroisopropyl alcohol. Deuterium rate effects, stereochemistry of substitution and elimination, and reaction mechanism
R. C. Seib, V. J. Shiner, V. Sendijarevic, and K. Humski
pp 8133 - 8137; DOI:
10.1021/ja00494a019
PDF
Contrasting responses in aqueous trifluoroethanol and aqueous ethanol as a probe for nucleophilic solvent assistance in solvolysis
Douglas J. Raber, William C. Neal, Michael D. Dukes, J. Milton Harris, and Dwight L. Mount
pp 8137 - 8146; DOI:
10.1021/ja00494a020
PDF
Application of the ethanol-trifluoroethanol method to solvolyses for which nucleophilic involvement is questioned
J. Milton Harris, Dwight L. Mount, Maurice R. Smith, William C. Neal, Michael D. Dukes, and Douglas J. Raber
pp 8147 - 8156; DOI:
10.1021/ja00494a021
PDF
Photoreactions of charged benzophenone with amphiphiles in micelles and multicomponent aggregates as conformational probes
Ronald Breslow, Senji Kitabatake, and Jonathan Rothbard
pp 8156 - 8160; DOI:
10.1021/ja00494a022
PDF
Microwave spectrum, molecular geometry, ring bending potential function, and electric dipole moment of bicyclo[3.1.0]hexan-3-one
J. W. Bevan, A. C. Legon, S. O. Ljunggren, and P. J. Mjoberg
pp 8161 - 8165; DOI:
10.1021/ja00494a023
PDF
Conformations of some bicyclic monoterpenes based on bicyclo[3.1.0]hexane from their low-resolution microwave spectra
Z. Kisiel and A. C. Legon
pp 8166 - 8169; DOI:
10.1021/ja00494a024
PDF
Studies relating to the alleged structure of cannivonine and synthetically derived (.+-.)-dihydrocannivonine
David A. Evans, Alan M. Golob, Neil S. Mandel, and Gretchen S. Mandel
pp 8170 - 8174; DOI:
10.1021/ja00494a025
PDF
Dynamic stereochemistry of hexaarylbenzenes
Devens Gust and Alan Patton
pp 8175 - 8181; DOI:
10.1021/ja00494a026
PDF
Origins of stereoselectivity in asymmetric syntheses using chiral oxazolines
M. A. Hoobler, David E. Bergbreiter, and Martin Newcomb
pp 8182 - 8185; DOI:
10.1021/ja00494a027
PDF
Stereochemistry of metalation and alkylation of chiral oxazolines. A carbon-13 nuclear magnetic resonance study of lithio oxazolines
A. I. Meyers, Evan S. Snyder, and Joseph J. H. Ackerman
pp 8186 - 8189; DOI:
10.1021/ja00494a028
PDF
Host-guest complexation. 13. High chiral recognition of amino esters by dilocular hosts containing extended steric barriers
Stephen C. Peacock, Linda A. Domeier, Fred C. A. Gaeta, Roger C. Helgeson, Joseph M. Timko, and Donald J. Cram
pp 8190 - 8202; DOI:
10.1021/ja00494a029
PDF
Cyclopeptide alkaloids. Synthesis of the ring system and its ion affinity
J. Clark Lagarias, Richard A. Houghten, and Henry Rapoport
pp 8202 - 8209; DOI:
10.1021/ja00494a030
PDF
Studies on transfer ribonucleic acids and related compounds. 23. Synthesis of a heptanucleotide corresponding to a eukaryotic initiator tRNA loop sequence
E. Ohtsuka, S. Tanaka, and M. Ikehara
pp 8210 - 8213; DOI:
10.1021/ja00494a031
PDF
The penems, a new class of .beta.-lactam antibiotics: 6-acylaminopenem-3-carboxylic acids
I. Ernest, J. Gosteli, C. W. Greengrass, W. Holick, H. R. Pfaendler, and R. B. Woodward
pp 8214 - 8222; DOI:
10.1021/ja00494a032
PDF
Analysis of the factors determining the EPR spectra of spin probes that partition between aqueous and lipid phases
Carl F. Polnaszek, Shirley Schreier, Keith W. Butler, and Ian C. P. Smith
pp 8223 - 8232; DOI:
10.1021/ja00494a033
PDF
Effects of donor molecules on the palladium-catalyzed cyclocotrimerization of acetylenes with olefins. Preparation of dimeric tetrakis(methoxycarbonyl)palladiacyclopentadiene(base) complexes and structure with base = 2,6-lutidine
Leo D. Brown, Kenji Itoh, Hiroharu Suzuki, Kenji Hirai, and James A. Ibers
pp 8232 - 8238; DOI:
10.1021/ja00494a034
PDF
Base-catalyzed proton transfer from an intramolecularly hydrogen-bonded naphthylammonium ion in 70% dimethyl sulfoxide-water (v/v)
Frank Hibbert and Heather J. Robbins
pp 8239 - 8244; DOI:
10.1021/ja00494a035
PDF
Aromatic sulfonation. 67. Sulfonation of the 1,6-methano[10]annulene system. Evidence for ipso attack with the 2,7-dimethyl derivative
Koop Lammertsma and Hans Cerfontain
pp 8244 - 8246; DOI:
10.1021/ja00494a036
PDF
Photochemical transformations of small ring carbonyl compounds. 101. Migratory aptitude studies in the photochemical rearrangement of 2(5H)-furanones
Albert Padwa, Todd Brookhart, David Dehm, and Gene Wubbels
pp 8247 - 8259; DOI:
10.1021/ja00494a037
PDF
Stereochemistry of noncovalent interactions in organic and metal cationic complexes
Andrew C. Coxon, Dale A. Laidler, Roger B. Pettman, and J. Fraser Stoddart
pp 8260 - 8262; DOI:
10.1021/ja00494a038
PDF
Comment on the communication "Photoionization by green light in micellar solution"
Gregory E. Hall
pp 8262 - 8264; DOI:
10.1021/ja00494a039
PDF
Proton, deuterium, and tritium nuclear magnetic resonance of intramolecular hydrogen bonds. Isotope effects and the shape of the potential energy function
Lawrence J. Altman, Pilip Laungani, Gudmundur Gunnarsson, Hakan Wennerstrom, and Sture Forsen
pp 8264 - 8266; DOI:
10.1021/ja00494a040
PDF
Characterization and molecular structure of [(PPh3)RhC2B9H11]2, a phosphinorhodacarborane dimer containing rhodium-hydrogen-boron bridges
R. T. Baker, R. E. King, C. Knobler, C. A. O'Con, and M. F. Hawthorne
pp 8266 - 8267; DOI:
10.1021/ja00494a041
PDF
Synthesis and crystal structure analysis of a rhodiacyclopentenedione complex containing a coordinated water ligand
P. Douglas Frisch and G. P. Khare
pp 8267 - 8269; DOI:
10.1021/ja00494a042
PDF
The importance of intramolecular hydrogen bonding on the reactivity of tetrahydro diol epoxides
John M. Janusz, Allyn R. Becker, and Thomas C. Bruice
pp 8269 - 8271; DOI:
10.1021/ja00494a043
PDF
Carbon acidity. 59. First and second ion-pair acidity constants for 9,10-dihydroanthracene with cesium cyclohexylamide
Andrew Streitweiser, Carl M. Berke, and Karyl Robbers
pp 8271 - 8272; DOI:
10.1021/ja00494a044
PDF
Total synthesis of prostaglandin F2.alpha. by chirality transfer from D-glucose
Gilbert Stork, Takashi Takahashi, Isao Kawamoto, and Toshio Suzuki
pp 8272 - 8273; DOI:
10.1021/ja00494a045
PDF
Additions and Corrections - Chemistry and Molecular Structure of a Product Formed through Enamine-Ketimine Tautomerism in a Pd-C(CH3)==NR Fragment
H. C. Clark, C. R. C. Milne, and N. C. Payne
pp 8274 - 8274; DOI:
10.1021/ja00494a600
PDF
Additions and Corrections - Selenium-77 Nuclear Magnetic Resonance Studies. 1. Chemical Shifts, Coupling Constants, and Relaxation Times for Se-dl-Cystine, Se-dl-Methionine, and Several Se-Containing Transition Metal Complexes.
W.H. Pan, and John P. Fackler, Jr.
pp 8274 - 8274; DOI:
10.1021/ja00494a601
PDF
Additions and Corrections - Outer-Sphere Intervalence Transfer
Jeff C. Curtis, and Thomas J. Meyer
pp 8274 - 8274; DOI:
10.1021/ja00494a602
PDF
Additions and Corrections - Nucleophilic Substitution at Phosphorus. The Effect of Ion Association on the Stereochemistry and Rate of Substitution at Phosphorus in a Six-Membered Ring Phosphate
Mike Bauman, and William S. Wadsworth, Jr.
pp 8274 - 8274; DOI:
10.1021/ja00494a603
PDF
Additions and Corrections - Photochemical Transformations. 22. Photo-Wagner-Meerwein Rearrangements and Photoreactions of Some Halogen Derivatives in Dibenzobicyclonatriene Systems.
Stanley J. Cristol, Dean P. Stull, and Rory D. Daussin
pp 8274 - 8274; DOI:
10.1021/ja00494a604
PDF
Additions and Corrections - Structure-Reactivity Coefficients for General Acid Catalysis of Semicarbazone Formation
Lance H. Funderburk, and William P. Jencks
pp 8274 - 8274; DOI:
10.1021/ja00494a605
PDF
Additions and Corrections - Magnetic Circular Dichroism of Cyclic π-Electron Systems. 2. Algebraic Solution of the Perimeter Model for the B Terms of Systems with a (4N + 2)-Electron [n]Annulene Perimeter
Josef Michl
pp 8274 - 8274; DOI:
10.1021/ja00494a606
PDF